Journal Article10.1021/CR010444T
Asymmetric catalysis and amplification with chiral lanthanide complexes.
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About: This article is published in Chemical Reviews. The article was published on 17 May 2002. The article focuses on the topics: Enantioselective synthesis & Lanthanide.
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Citations
Asymmetric Counteranion-Directed Catalysis: Concept, Definition, and Applications
Manuel Mahlau,Benjamin List +1 more
TL;DR: This Review closes this gap by providing a clear definition of ACDC and by examining both clear cases as well as more ambiguous examples to illustrate the differences and overlaps with other catalysis concepts.
761
Chiral sulfoxides: advances in asymmetric synthesis and problems with the accurate determination of the stereochemical outcome.
Jianlin Han,Vadim A. Soloshonok,Vadim A. Soloshonok,Karel D. Klika,Józef Drabowicz,Alicja Wzorek,Alicja Wzorek +6 more
TL;DR: This work concerns a critical discussion of the problem of the accurate determination of the stereochemical outcome of a reaction due to the self-disproportionation of enantiomers (SDE) phenomenon, particularly as it relates to chiral sulfoxides.
219
Selective lanthanide sorption and mechanism using novel hybrid Lewis base (N-methyl-N-phenyl-1,10-phenanthroline-2-carboxamide) ligand modified adsorbent
Md. Rabiul Awual,Tohru Kobayashi,Yuji Miyazaki,Ryuhei Motokawa,Hideaki Shiwaku,Shinichi Suzuki,Yoshihiro Okamoto,Tsuyoshi Yaita +7 more
TL;DR: The results suggested that HyLBA has a good prospect of promising applications for separation/sorption of lanthanide ions from effluents.
217
References
Chiral organolanthanide complexes for enantioselective olefin hydrogenation
Vincent P. Conticello,Laurent Brard,Michael A. Giardello,Yasushi Tsuji,Michal Sabat,Charlotte L. Stern,Tobin J. Marks +6 more
TL;DR: In this paper, a chelating ligand system designed to preserve Cp{prime}{sub 2}Ln stereoelectronic properties is presented, which provides a rigid, chiral template for lateral/transverse substrate enantioface discrimination.
142
Catalytic asymmetric nitroaldol reaction: An efficient synthesis of (S) propranolol using the lanthanum binaphthol complex
TL;DR: Propranolol, a more potent optical isomer of the widely used β-blocker, was conveniently synthesized in a higly enantioselective manner by the lanthanum-(R )-(+)-binaphthol complex catalyzed asymmetric nitroaldol reaction as discussed by the authors.
135
Enantioselective synthesis of α-hydroxy phosphonates using the LaLi3tris(binaphthoxide) catalyst (LLB), prepared by an improved method
TL;DR: In this article, the LaLi 3 tris(binaphthoxide) catalyst (LLB) was used for the hydrophosphonylation of various aldehydes to give desired α-hydroxyphosphonates in up to 95% ee (88% yield).
129
The enantioselective addition of dialkylphosphites to aldehydes: Catalysis by a lanthanum binaphthoxide complex
TL;DR: The enantioselective addition of dialkylphosphites to aldehydes was catalyzed by a lanthanum (R)-binaphthoxide complex to give (S)-hydroxy phosphonates in good yield and modest enanti-lectivity as mentioned in this paper.
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