Applications of Supramolecular Anion Recognition
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About: This article is published in Chemical Reviews. The article was published on 21 May 2015. and is currently open access. The article focuses on the topics: Supramolecular chemistry.
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Citations
Coumarin-Based Small-Molecule Fluorescent Chemosensors.
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TL;DR: This comprehensive and critical review of coumarin-based small-molecule fluorescent chemosensors during the period of 2012-2018 may facilitate the development of more powerful fluorescent chemOSensors for broad and exciting applications in the future.
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Applying low-molecular weight supramolecular gelators in an environmental setting – self-assembled gels as smart materials for pollutant removal
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Supramolecular chemotherapy based on host–guest molecular recognition: a novel strategy in the battle against cancer with a bright future
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σ-Hole Bond vs π-Hole Bond: A Comparison Based on Halogen Bond.
TL;DR: The σ-hole and π-hole are the regions with positive surface electrostatic potential on the molecule entity; the former specifically refers to the positive region of a molecular entity along extension of the Y-Ge/P/Se/X covalent ρ-bond.
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References
Ceramide forms channels in mitochondrial outer membranes at physiologically relevant concentrations.
TL;DR: The concentration of ceramide at which significant channel formation occurs is consistent with the level of mitochondrial ceramide that occurs during the induction phase of apoptosis (4 pmol ceramide/nanomole phospholipid).
New method for retrospective detection of exposure to organophosphorus anticholinesterases : Application to alleged sarin victims of Japanese terrorists
TL;DR: The new procedure is applied to serum samples from victims of the Tokyo subway attack by the AUM Shinriyko sect and from an earlier incident at Matsumoto, finding that these victims had been exposed to an organophosphate with the structure PriO(CH3)P(O)X, presumably with X = F (sarin).
Biologically active binaphthol-scaffolded imidazolium salts
TL;DR: The most potent compound displayed micromolar minimal inhibitory concentrations against Gram-positive Bacillus thuringiensis and Listeria seeligeri.
Synthetic Prodigiosenes and the Influence of C-Ring Substitution on DNA Cleavage, Transmembrane Chloride Transport and Basicity.
Soumya Rastogi,Estelle Marchal,Imam Uddin,Brandon R. Groves,Julie Colpitts,Sherri A. McFarland,Jeffery T. Davis,Alison Thompson +7 more
TL;DR: Although the presence of an ester conjugated to the prodigiosene C-ring seems to decrease both pKa and chloride transport efficiency compared to the natural product, these analogues still exhibit a high rate of chloride transport.
Discotic columnar mesophases derived from ‘rod-like’ π-conjugated anion-responsive acyclic oligopyrroles
Hiromitsu Maeda,Hiromitsu Maeda,Yoshitaka Terashima,Yohei Haketa,Atsushi Asano,Yoshihito Honsho,Shu Seki,Shu Seki,Masahiro Shimizu,Hidetomo Mukai,Kazuchika Ohta +10 more
TL;DR: Rod-like pi-conjugated anion-responsive acyclic oligopyrroles have been reported to form stacked disk-like components that result in the formation of discotic columnar mesophases as thermotropic liquid crystals.