Journal Article10.1039/C4TA02066A
AgPd nanoparticles supported on MIL-101 as high performance catalysts for catalytic dehydrogenation of formic acid
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TL;DR: In this article, Bimetallic AgPd nanoparticles were successfully immobilized into the metal-organic frameworks (MIL-101), and tested for their catalytic dehydrogenation of formic acid.
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Abstract: Bimetallic AgPd nanoparticles were successfully immobilized into the metal–organic frameworks (MIL-101), and tested for their catalytic dehydrogenation of formic acid. These catalysts were composition dependent for the catalytic activity. Among all the AgPd@MIL-101 catalysts tested, the Ag20Pd80@MIL-101 catalyst exhibits the highest catalytic activity for the conversion of formic acid to high-quality hydrogen at 80 °C with a TOF value of 848 h−1, which is among the highest values reported at 80 °C.
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Citations
Titanium Dioxide Reinforced Metal–Organic Framework Pd Catalysts: Activity and Reusability Enhancement in Alcohol Dehydrogenation Reactions and Improved Photocatalytic Performance
TL;DR: In this article, the authors reported on the controlled incorporation of nanoscale palladium and titanium dioxide inside MIL•101 (Cr) and demonstrated the improved reusability of the resulting Pd/TiO2@MIL•101 composite materials.
Anchoring PdAu nanoclusters inside aminated metal-organic framework for fast dehydrogenation of formic acid
Yiyu Ding,Peng Liu,Xiaoyun Huang,Caili Hu,Zubiao Wen,Zhang-Hui Lu +5 more
- Fuel
TL;DR: Researchers developed a highly efficient catalyst, PdAu/NH2-MIL-101, for fast dehydrogenation of formic acid, achieving 100% H2 selectivity and a turnover frequency of 2921.0 h−1 at 323 K, outperforming most MOF-based catalysts.
AgPd nanoparticles supported on reduced graphene oxide: A high catalytic activity catalyst for the transfer hydrogenation of nitroarenes
Xiaotong Liu,Chenhuan Wang,Saisai Cheng,Ningzhao Shang,Shutao Gao,Cheng Feng,Chun Wang,Yuqing Qiao,Zhi Wang +8 more
TL;DR: In this paper, the Co3(BO3)2 and AgPd nanoparticles were co-deposited on the surface of reduced graphene oxide, then the Co 3(BO 3)2 was sacrificed by acid etching.
Facile synthesis of amine-functionalized SBA-15-supported bimetallic Au–Pd nanoparticles as an efficient catalyst for hydrogen generation from formic acid
TL;DR: In this article, a series of amine functionalized SBA-15-supported bimetallic Au-Pd nanoparticles (AuPd/SBA15-Amine) as catalysts are successfully synthesized by surface functionalization and co-reduction and characterized by inductively coupled plasma-atomic emission spectroscopy, XRD, XPS, and TEM.
PdAu bimetallic nanoparticles anchored on amine-modified mesoporous ZrSBA-15 for dehydrogenation of formic acid under ambient conditions
Zhenzhen Wang,Xiufeng Hao,Dianwen Hu,Lin Li,Xiao-Jing Song,Wenxiang Zhang,Mingjun Jia +6 more
- 07 Jun 2017
TL;DR: The PdAu bimetallic nanoparticles anchored on amine-modified mesoporous ZrSBA-15 exhibit high catalytic activity for dehydrogenation of formic acid under ambient conditions. The catalytic activity is influenced by the amine modification and Pd/Au ratio. The optimized catalyst achieves high efficiency at low temperatures.
References
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Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
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Hydrogen-storage materials for mobile applications
TL;DR: Recent developments in the search for innovative materials with high hydrogen-storage capacity are presented.
A chromium terephthalate-based solid with unusually large pore volumes and surface area.
Gérard Férey,Gérard Férey,Caroline Mellot-Draznieks,Christian Serre,Franck Millange,Julien Dutour,Suzy Surblé,Irene Margiolaki +7 more
TL;DR: This crystal structure for porous chromium terephthalate, MIL-101, with large poresizes and surface area has potential as a nanomold for monodisperse nanomaterials, as illustrated here by the incorporation of Keggin polyanions within the cages.
Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries
TL;DR: In this article, the authors show that 2 and 5 times higher energy densities are required to meet the performance goals of a future generation of plug-in hybrid-electric vehicles (PHEVs) with a 40-80 mile all-electric range, and all-EVs with a 300-400 mile range, respectively.
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