Journal Article10.1006/JCIS.1996.0242
A surface structural approach to ion adsorption : The charge distribution (CD) model
1K
TL;DR: In this paper, an ion adsorption model for metal hydroxides has been developed which deals with the observation that in the case of inner sphere complex formation only part of the surface complex is incorporated into the surface by a ligand exchange reaction while the other part is located in the Stern layer.
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About: This article is published in Journal of Colloid and Interface Science. The article was published on 10 May 1996. The article focuses on the topics: Surface charge & Inner sphere complex.
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Citations
Competitive sorption of copper and lead at the oxide-water interface: Implications for surface site density
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TL;DR: In this paper, the competitive sorption of Cu and Pb to colloidal hematite was investigated as a function of pH and total metal concentration, and the results demonstrate that surface site density is a key parameter if surface complexation models are exposed to more complex, multicomponent environments.
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Fertilization and pH effects on processes and mechanisms controlling dissolved inorganic phosphorus in soils
TL;DR: In this article, a set of mechanistic adsorption models (1-pK TPM, ion exchange and Nica-Donnan) were used to determine the effect of repeated massive application of inorganic P fertilizer on the processes and mechanisms controlling the concentration of dissolved inorganic phosphorus (DIP) in soils.
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Kinetics of Cation and Oxyanion Adsorption and Desorption on Ferrihydrite: Roles of Ferrihydrite Binding Sites and a Unified Model.
TL;DR: This study provided a unified modeling method for the kinetics of ion adsorption/desorption on ferrihydrite and quantitatively elucidated how the equilibrium properties of the cation and oxyanion binding to various ferriHydrite sites and the formation of various surface complexes controlled the adsor adaptation and desorption kinetics at different reaction conditions and time scales.
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Influence of surface conductivity on the apparent zeta potential of amorphous silica nanoparticles.
Philippe Leroy,Nicolas Devau,André Revil,Mohamed Bizi +3 more
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TL;DR: The very good agreement of calculated and measured electrophoretic mobilities confirms that the true zeta potential corresponds to the electrical potential at the outer Helmholtz plane (OHP), and the shear plane might be located close to the OHP.
Regular ArticleInorganic Ligand Effects on Pb(II) Sorption to Goethite (α-FeOOH): I. Carbonate
TL;DR: Characterizing the structures of Pb(II) sorption complexes formed on goethite (alpha-FeOOH) in the presence of carbonate using in situ Pb L(III)-EXAFS and ATR-FTIR spectroscopies suggests the existence of ternary surface complexes in which carbonate groups bond to Pb as monodentate ligands.
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