Journal Article10.1016/J.ENSM.2016.10.007
A perspective on nickel-rich layered oxide cathodes for lithium-ion batteries
548
TL;DR: In this paper, the authors highlight the evolution of nickel-rich layered oxides from LiNiO2 to LiNi 1−x−yCoxMnyO2 (1−x −y>0.5) in view of cationic substitutions, state-of-the-art understanding of the capacity fading mechanisms that is related to a complex surface chemistry of the particles, and various modification strategies to enhance the surface stability.
read more
About: This article is published in Energy Storage Materials. The article was published on 01 Jan 2017.
read more
Chat with Paper
AI Agents for this Paper
Find similar papers on Google Scholar, PubMed and Arxiv
Write a critical review of this paper
Analyze citations of this paper to find unaddressed research gaps
Citations
High-voltage positive electrode materials for lithium-ion batteries
TL;DR: This review gives an account of the various emerging high-voltage positive electrode materials that have the potential to satisfy the requirements of lithium-ion batteries either in the short or long term, including nickel-rich layered oxides, lithium- rich layeredOxides, high- voltage spinel oxide compounds, and high- voltage polyanionic compounds.
1.1K
Automotive Li-Ion Batteries: Current Status and Future Perspectives
Yuanli Ding,Zachary P. Cano,Aiping Yu,Jun Lu,Zhongwei Chen +4 more
- 03 Apr 2019
TL;DR: In this article, the authors set the extensive market penetration of lithium-ion battery-powered EVs as an ultimate objective and then discussed recent advances and challenges of electric automobiles, mainly focusing on critical element resources, present and future EV markets, and the cost and performance of Li-ion batteries.
1K
Prospect and Reality of Ni-Rich Cathode for Commercialization
TL;DR: In this paper, important stability issues and in-depth understanding of the nickel-rich cathode materials on the basis of the industrial electrode fabrication condition for the commercialization of the NRC-compliant cathode material are reviewed.
810
Current Status and Future Prospects of Metal–Sulfur Batteries
TL;DR: The current state of the research indicates that lithium-sulfur cells are now at the point of transitioning from laboratory-scale devices to a more practical energy-storage application, and over 450 research articles are summarized to analyze the research progress and explore the electrochemical characteristics, cell-assembly parameters, cell -testing conditions, and materials design.
529
Bulk fatigue induced by surface reconstruction in layered Ni-rich cathodes for Li-ion batteries
Chao Xu,Katharina Märker,Juhan Lee,Amoghavarsha Mahadevegowda,Philip J. Reeves,Sarah J. Day,Matthias F. Groh,Matthias F. Groh,Steffen P. Emge,Caterina Ducati,B. Layla Mehdi,Chiu C. Tang,Clare P. Grey +12 more
TL;DR: A structure-driven degradation mechanism for NMC811, in which a proportion of the material exhibits a lowered accessible state of charge at the end of charging after repetitive cycling and becomes fatigued, is reported and provides fundamental insights into strategies to help mitigate this degradation process.
507
References
Synthesis, structural and electrochemical properties of LiNi0.79Co0.1Mn0.1Cr0.01O2 via fast co-precipitation
TL;DR: In this article, a novel layered material of LiNi0.79Co0.1Mn0.01O2 is synthesized by fast co-precipitation method.
71
Structural and Chemical Characterization of Layered Li1-xNi1-yMnyO2-δ (y = 0.25 and 0.5, and 0 ≤ (1 − x) ≤ 1) Oxides
TL;DR: In this article, LiNi1-yMnyO2 (y = 0.25 and 0.5) oxides with the oxidizer NO2BF4 in acetonitrile medium have been characterized by X-ray diffraction, redox titrations, and infrared spectroscopy.
70
Nano-structural changes in Li-ion battery cathodes during cycling revealed by FIB-SEM serial sectioning tomography
TL;DR: In this paper, the authors used focused ion beam-scanning electron microscopy (FIB-SEM) serial sectioning to reconstruct the evolution of the three-dimensional structure of Li-ion battery electrodes during extended cycling.
68
Self-Terminated Artificial SEI Layer for Nickel-Rich Layered Cathode Material via Mixed Gas Chemical Vapor Deposition
TL;DR: In this article, a facile chemical vapor deposition process involving mixed gases of CO2 and CH4 was proposed to yield thin and conformal artificial solid-electrolyte-interphase (SEI) layer consisting of alkyl lithium carbonate (LiCO3R) and Li2CO3 on nickel-rich active cathode powder.
64
Improving thermal and electrochemical performances of LiCoO2 cathode at high cut-off charge potentials by MF3 (M=Ce, Al) coating
Abdelmaula Aboulaich,Khalid Ouzaouit,Hakim Faqir,Abderrahman Kaddami,Intissar Benzakour,Ismail Akalay +5 more
TL;DR: In this article, the surface coating of LiCoO 2 cathode particles with an average layer thickness about 12nm and 40nm for AlF 3 and CeF 3, respectively, was synthesized via co-precipitation method followed by a solid state reaction at 400°C.
62