Journal Article10.1016/j.jcat.2023.02.018
A general catalyst for Buchwald-Hartwig amination to prepare secondary five-membered heteroaryl amines with breaking the base barrier
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TL;DR: In this paper , the authors proposed a protocol for the preparation of secondary five-membered heteroaryl amines via the palladium-catalyzed CN cross-coupling reaction.
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About: This article is published in Journal of Catalysis. The article was published on 01 Jun 2023. The article focuses on the topics: Chemistry & Palladium.
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Citations
Direct synthesis of anilines using copper immobilized on triazine-aminopyridine -modified MIL-101(Cr) MOF
Sara Heidari,Sedigheh Alavinia,Ramin Ghorbani‐Vaghei +2 more
TL;DR: Direct synthesis of anilines using copper immobilized on triazine-aminopyridine-modified MIL-101(Cr) MOF enables the synthesis of diverse anilines under mild conditions.
References
Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.
TL;DR: Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts and this review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand.
Recent Applications of Palladium-Catalyzed Coupling Reactions in the Pharmaceutical, Agrochemical, and Fine Chemical Industries
TL;DR: In this review different examples from 2001-2008 are highlighted, which have been performed at least on a kilogram scale in the chemical and pharmaceutical industries.
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Well-defined N-heterocyclic carbenes-palladium(II) precatalysts for cross-coupling reactions.
Nicolas Marion,Steven P. Nolan +1 more
TL;DR: Four main classes of NHC-containing palladium(II) complexes will be presented: palladium dimers with bridging halogens, palladacycles, palladium acetates and acetylacetonates, and finally pi-allyl complexes.
1K
A Simple Catalytic Method for the Conversion of Aryl Bromides to Arylamines
TL;DR: In this paper, a facile and general catalytic method for the conversion of aryl bromides to arylamines was developed, which works well for inter- and intramolecular processes.
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Carbon–heteroatom bond formation catalysed by organometallic complexes
TL;DR: New elementary reactions that occur at metal–heteroatom bonds and the identification of factors that control these reactions have led to new synthetic processes that are in daily use and have formed a foundation for the development of processes likely to be central to synthetic chemistry in the future.