Journal Article10.1016/S0010-2180(97)00282-4
A Comprehensive Modeling Study of n-Heptane Oxidation
TL;DR: In this article, a detailed chemical kinetic mechanism has been developed and used to study the oxidation of n-heptane in flow reactors, shock tubes, and rapid compression machines, where the initial pressure ranged from 1-42 atm, the temperature from 550-1700 K, the equivalence ratio from 0.3-1.5, and nitrogen-argon dilution from 70-99%.
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About: This article is published in Combustion and Flame. The article was published on 01 Jul 1998. The article focuses on the topics: Reaction rate & Reaction rate constant.
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Citations
On the assumption of using n-heptane as a “surrogate fuel” for the description of the cool flame oxidation of diesel oil
Dionysios I. Kolaitis,Maria A. Founti +1 more
- 01 Jan 2009
TL;DR: In this article, seven n-heptane oxidation chemical kinetic mechanisms of varied complexity are compared aiming to assess their performance in simulating the cool flame oxidative behavior of diesel oil, as well as to investigate the validity of the utilization of n -heptanes as a surrogate fuel for diesel oil.
37
Symbolic Incorporation of External Procedures into Process Modeling Environments
TL;DR: In this article, the authors describe a symbolic approach for incorporating external procedures into an equation-oriented modeling environment. But they do not discuss the use of external procedures within these software packages.
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The role of cool-flame chemistry in quasi-steady combustion and extinction of n-heptane droplets
TL;DR: In this paper, a 770-step reduced chemicalkinetic mechanism and a new 62-step skeletal chemical-kinetic (SKK) mechanism are employed to calculate the droplet burning rates, flame structures, and extinction diameters for this cool-flame regime.
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Exploration of chemical composition effects on the autoignition of two commercial diesels: Rapid compression machine experiments and model simulation
TL;DR: In this article, the authors explored the composition effects on autoignition by comparing the auto-ignition characteristics of two commercial diesels (China Stage-V and Stage-VI) and found that the difference in the total IDTs of the two diesels varies with the temperature range.
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References
Evaluated Kinetic Data for Combustion Modelling
Donald L. Baulch,Carlos J. Cobos,Richard A. Cox,C. Esser,P. Frank,Th. Just,J. A. Kerr,Michael J. Pilling,Jürgen Troe,Raymond W. Walker,J. Warnatz +10 more
TL;DR: In this paper, the authors present a compilation of critically evaluated kinetic data on elementary homogeneous gas phase chemical reactions for use in modelling combustion processes Data sheets are presented for some 196 reactions each data sheet sets out relevant thermodynamic data, rate coefficient measurements, an assessment of the reliability of the data, references and recommended rate parameters Tables summarizing the preferred rate data are also given
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Chemical Kinetic Data Base for Combustion Chemistry. Part I. Methane and Related Compounds
W. Tsang,R. F. Hampson +1 more
TL;DR: In this paper, the authors evaluated data on the kinetics and thermodynamic properties of species that are of importance in methanepyrolysis and combustion, including H, H2, O, O2, OH, HO2, CH2O, CH4, C2H6, HCHO, CO2, CO, HCO, CH3, CH5, CH6, CH7, CH8, CH9, CH10, CH11, CH12, CH13, CH14, CH15, CH16, CH17, CH
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Chemical Kinetic Data Base for Combustion Chemistry. Part 3: Propane
TL;DR: In this paper, the authors evaluated and estimated data on the kinetics of reactions involving propane, isopropyl radical, n−propyl radical and various small inorganic and organic species.
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Shock-tube investigation of self-ignition of n-heptane - Air mixtures under engine relevant conditions
H. Ciezki,G. Adomeit +1 more
TL;DR: In this paper, n-heptane-air mixtures have been investigated in a high-pressure shock tube without use of the customary heat bath dilution to determine self-ignition characteristics under conditions relevant to piston engines combustion.
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