Journal Article10.1016/S0010-2180(97)00282-4
A Comprehensive Modeling Study of n-Heptane Oxidation
TL;DR: In this article, a detailed chemical kinetic mechanism has been developed and used to study the oxidation of n-heptane in flow reactors, shock tubes, and rapid compression machines, where the initial pressure ranged from 1-42 atm, the temperature from 550-1700 K, the equivalence ratio from 0.3-1.5, and nitrogen-argon dilution from 70-99%.
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About: This article is published in Combustion and Flame. The article was published on 01 Jul 1998. The article focuses on the topics: Reaction rate & Reaction rate constant.
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Citations
Automatic generation of a detailed mechanism for the oxidation of n-decane
TL;DR: In this article, a detailed kinetic mechanism for the oxidation and combustion of n-decane and n-heptane has been written by means of an automatic mechanism generator (REACTION) developed in our laboratory.
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High-dimensional, unsupervised cell clustering for computationally efficient engine simulations with detailed combustion chemistry
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Numerical study on auto-ignition characteristics of hydrogen-enriched methane under engine-relevant conditions
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High temperature shock tube experiments and kinetic modeling study of diisopropyl ketone ignition and pyrolysis
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Autoignition of a Lean Propane-Air Mixture at High Pressures
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References
Evaluated Kinetic Data for Combustion Modelling
Donald L. Baulch,Carlos J. Cobos,Richard A. Cox,C. Esser,P. Frank,Th. Just,J. A. Kerr,Michael J. Pilling,Jürgen Troe,Raymond W. Walker,J. Warnatz +10 more
TL;DR: In this paper, the authors present a compilation of critically evaluated kinetic data on elementary homogeneous gas phase chemical reactions for use in modelling combustion processes Data sheets are presented for some 196 reactions each data sheet sets out relevant thermodynamic data, rate coefficient measurements, an assessment of the reliability of the data, references and recommended rate parameters Tables summarizing the preferred rate data are also given
2.1K
Chemical Kinetic Data Base for Combustion Chemistry. Part I. Methane and Related Compounds
W. Tsang,R. F. Hampson +1 more
TL;DR: In this paper, the authors evaluated data on the kinetics and thermodynamic properties of species that are of importance in methanepyrolysis and combustion, including H, H2, O, O2, OH, HO2, CH2O, CH4, C2H6, HCHO, CO2, CO, HCO, CH3, CH5, CH6, CH7, CH8, CH9, CH10, CH11, CH12, CH13, CH14, CH15, CH16, CH17, CH
1.9K
Chemical Kinetic Data Base for Combustion Chemistry. Part 3: Propane
TL;DR: In this paper, the authors evaluated and estimated data on the kinetics of reactions involving propane, isopropyl radical, n−propyl radical and various small inorganic and organic species.
604
Shock-tube investigation of self-ignition of n-heptane - Air mixtures under engine relevant conditions
H. Ciezki,G. Adomeit +1 more
TL;DR: In this paper, n-heptane-air mixtures have been investigated in a high-pressure shock tube without use of the customary heat bath dilution to determine self-ignition characteristics under conditions relevant to piston engines combustion.
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