Journal Article10.1016/S0010-2180(97)00282-4
A Comprehensive Modeling Study of n-Heptane Oxidation
TL;DR: In this article, a detailed chemical kinetic mechanism has been developed and used to study the oxidation of n-heptane in flow reactors, shock tubes, and rapid compression machines, where the initial pressure ranged from 1-42 atm, the temperature from 550-1700 K, the equivalence ratio from 0.3-1.5, and nitrogen-argon dilution from 70-99%.
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About: This article is published in Combustion and Flame. The article was published on 01 Jul 1998. The article focuses on the topics: Reaction rate & Reaction rate constant.
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Citations
Development of a Phenomenological Soot Model Coupled with a Skeletal PAH Mechanism for Practical Engine Simulation
TL;DR: In this article, a new chemical mechanism with 12 species and 26 reactions for formation of polycyclic aromatic hydrocarbons (PAHs) was developed and integrated into a skeletal mechanism for oxidation of primary reference fuel (PRF).
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Flame Propagation and Extinction Characteristics of Neat Surrogate Fuel Components
Kamal Kumar,Chih-Jen Sung +1 more
TL;DR: In this paper, an experimental and computational investigation into the flame propagation and extinction characteristics of neat hydrocarbon components relevant to real transportation fuels is conducted, and the atmospheric pressure laminar flame speeds for the neat fuels, over a range of equivalence ratios, are measured and compared at varying preheat temperatures.
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Skeletal mechanism generation with CSP and validation for premixed n-heptane flames
Jens Prager,Habib N. Najm,Mauro Valorani,Dimitris A. Goussis +3 more
- 01 Jan 2009
TL;DR: In this article, an automated procedure has been developed to generate simplified skeletal reaction mechanisms for the combustion of n-heptane/air mixtures at equivalence ratios between 0.5 and 2.0 and different pressures.
51
A comparative study of the oxidation characteristics of two gasoline fuels and an n-heptane/iso-octane surrogate mixture
TL;DR: In this paper, the authors measured species time-histories and ignition delay times of two FACE (Fuels for Advanced Combustion Engines) gasolines and one PRF (Primary Reference Fuel) blend.
51
Low-temperature speciation and chemical kinetic studies of n-heptane
TL;DR: In this paper, the authors presented new ignition and speciation data taken at high pressure (9-atm), low temperatures (660-710 K), and a dilution of inert gases-to-molecular oxygen of 564 (mole basis) using gas chromatography.
51
References
Evaluated Kinetic Data for Combustion Modelling
Donald L. Baulch,Carlos J. Cobos,Richard A. Cox,C. Esser,P. Frank,Th. Just,J. A. Kerr,Michael J. Pilling,Jürgen Troe,Raymond W. Walker,J. Warnatz +10 more
TL;DR: In this paper, the authors present a compilation of critically evaluated kinetic data on elementary homogeneous gas phase chemical reactions for use in modelling combustion processes Data sheets are presented for some 196 reactions each data sheet sets out relevant thermodynamic data, rate coefficient measurements, an assessment of the reliability of the data, references and recommended rate parameters Tables summarizing the preferred rate data are also given
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Chemical Kinetic Data Base for Combustion Chemistry. Part I. Methane and Related Compounds
W. Tsang,R. F. Hampson +1 more
TL;DR: In this paper, the authors evaluated data on the kinetics and thermodynamic properties of species that are of importance in methanepyrolysis and combustion, including H, H2, O, O2, OH, HO2, CH2O, CH4, C2H6, HCHO, CO2, CO, HCO, CH3, CH5, CH6, CH7, CH8, CH9, CH10, CH11, CH12, CH13, CH14, CH15, CH16, CH17, CH
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Chemical Kinetic Data Base for Combustion Chemistry. Part 3: Propane
TL;DR: In this paper, the authors evaluated and estimated data on the kinetics of reactions involving propane, isopropyl radical, n−propyl radical and various small inorganic and organic species.
604
Shock-tube investigation of self-ignition of n-heptane - Air mixtures under engine relevant conditions
H. Ciezki,G. Adomeit +1 more
TL;DR: In this paper, n-heptane-air mixtures have been investigated in a high-pressure shock tube without use of the customary heat bath dilution to determine self-ignition characteristics under conditions relevant to piston engines combustion.
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