TL;DR: In this paper, the state-of-the-art of In2O3 in terms of semiconductor applications is summarized, with the focus on the charge carrier transport properties of the material.
Abstract: The present review takes a semiconductor physics perspective to summarize the state-of-the art of In2O3 in relation to applications. After discussing conventional and novel applications, the crystal structure, synthesis of single-crystalline material, band-structure and optical transparency are briefly introduced before focussing on the charge carrier transport properties. The issues of unintentional n-type conductivity and its likely causes, the surface electron accumulation, and the lack of p-type conductivity will be presented. Intentional doping will be demonstrated to control the electron concentration and resistivity over a wide range, but is also subject to compensation. The control of the surface accumulation in relation to Schottky and ohmic contacts will be demonstrated. In the context of scattering mechanisms, the electron mobility and its limits will be discussed. Finally, the Seebeck coefficient and its significance will be shown, and ferromagnetic doping of In2O3 will be critically discussed. With this overview most if not all ingredients for the use of In2O3 as semiconductor material in novel or improved conventional devices will be given.
TL;DR: In this paper, a review of high fluence irradiation studies reporting on non-linear incorporation of implanted species, enhanced sputtering yields, morphological changes induced by the high thermal impact, as well as strongly enhanced dynamic annealing for such confined nanostructures is presented.
Abstract: Nanostructured materials are today subject to intense research, as their mesoscopic properties will enable a variety of new applications in the future. They can be grown with specific properties under equilibrium conditions by a variety of different top-down and bottom-up synthesis techniques. Subsequent modification, including doping or alloying using the highly non-equilibrium process of ion irradiation, significantly expands the potpourri of functionality of what is today an important material class. Important and newly discovered effects must be considered compared to ion irradiation of bulk or thin film counterparts, as the ion range becomes comparable to the size of the nanotructure. Here, we will review recent high fluence irradiation studies reporting on non-linear incorporation of implanted species, enhanced sputtering yields, morphological changes induced by the high thermal impact, as well as strongly enhanced dynamic annealing for such confined nanostructures. Our review will also include the concurrent and recent progress in developing new simulation tools in order to describe and quantify those newly observed effects.
TL;DR: In this paper, the authors outline some important properties of copper(I) thiocyanate and examine its use in the fabrication of potentially low-cost optoelectronic devices.
Abstract: Recent advances in large-area optoelectronics research have demonstrated the tremendous potential of copper(I) thiocyanate (CuSCN) as a universal hole-transport interlayer material for numerous applications, including transparent thin-film transistors, high-efficiency organic and hybrid organic-inorganic photovoltaic cells, and organic light-emitting diodes. CuSCN combines intrinsic hole-transport (p-type) characteristics with a large bandgap (>3.5 eV) which facilitates optical transparency across the visible to near infrared part of the electromagnetic spectrum. Furthermore, CuSCN is readily available from commercial sources while it is inexpensive and can be processed at low-temperatures using solution-based techniques. This unique combination of desirable characteristics makes CuSCN a promising material for application in emerging large-area optoelectronics. In this review article, we outline some important properties of CuSCN and examine its use in the fabrication of potentially low-cost optoelectronic devices. The merits of using CuSCN in numerous emerging applications as an alternative to conventional hole-transport materials are also discussed.
TL;DR: In this article, the thermal conductivity of Mg-doped electrical insulating and undoped semiconducting was measured by applying the electrical 3ω-method on Czochralski-grown bulk crystals, which have a thickness of and.
Abstract: For - only little information exists concerning the thermal properties, especially the thermal conductivity λ. Here, the thermal conductivity is measured by applying the electrical 3ω-method on Czochralski-grown - bulk crystals, which have a thickness of and . At room temperature (RT), the thermal conductivity along the [100]-direction in Mg-doped electrical insulating and undoped semiconducting - is confirmed as for both crystals. The thermal conductivity increases for decreasing temperature down from 25 K to . The phonon contribution of λ dominates over the electron contribution below RT. The observed function is in accord with phonon–phonon–Umklapp scattering and the Debye model for the specific heat at which is about 0.1 times the Debye temperature . Here, a detailed discussion of the phonon–phonon–Umklapp scattering for is carried out. The influence of point defect scattering is considered for .
TL;DR: In this article, the performance of a planar perovskite solar cell with cuprous oxide (Cu2O) hole transporting layers (HTLs) was investigated using a solar cell simulation program, wxAMPS.
Abstract: Solution-processed p-type metal oxide materials have shown great promise in improving the stability of perovskite-based solar cells and offering the feasibility for a low cost printing fabrication process. Herein, we performed a device modeling study on planar perovskite solar cells with cuprous oxide (Cu2O) hole transporting layers (HTLs) by using a solar cell simulation program, wxAMPS. The performance of a Cu2O/perovskite solar cell was correlated to the material properties of the Cu2O HTL, such as thickness, carrier mobility, mid-gap defect, and doping concentrations. The effect of interfacial defect densities on the solar cell performance was also investigated. Our simulation indicates that, with an optimized Cu2O HTL, high performance perovskite solar cells with efficiencies above 13% could be achieved, which shows the potential of using Cu2O as an alternative HTL over other inorganic materials, such as NiOx and MoOx. This study provides theoretical guidance for developing perovskite solar cells with inorganic hole transporting materials via a printing process.
TL;DR: In this article, structural and optical properties of a (InxGa)2O3 thin film having a monotonic lateral variation of the indium content x were investigated.
Abstract: We report on structural and optical properties of a (InxGa)2O3 thin film having a monotonic lateral variation of the indium content x (). The growth condition for each In content is similar allowing precise determination of the dependence of material properties on x. For low In content () the thin film has monoclinic crystal structure; for highest In contents () the cubic bixbyite phase is predominant. For intermediate alloying we observe additionally the rhombohedral InGaO3(II) crystallographic phase. The optical band-gap decreases systematically with increasing indium content and has a linear dependency on x for parts of the sample having the monoclinic phase, only. Further, properties of Pt Schottky diodes are reported for monoclinic (InxGa)2O3 and photo response measurements for
TL;DR: In this paper, a study has been performed to understand the gradual reset in Al2O3 resistive random access memory (RRAM) devices, where a significantly higher number of vacancies are created in the dielectric during the set event.
Abstract: In this work, a study has been performed to understand the gradual reset in Al2O3 resistive random-access memory (RRAM). Concentration of vacancies created during the forming or set operation is found to play a major role in the reset mechanism. The reset was observed to be gradual when a significantly higher number of vacancies are created in the dielectric during the set event. The vacancy concentration inside the dielectric was increased using a multi-step forming method which resulted in a diffusion-dominated gradual filament dissolution during the reset in Al2O3 RRAM. The gradual dissolution of the filament allows one to control the conductance of the dielectric during the reset. RRAM devices with gradual reset show excellent endurance and retention for multi-bit storage. Finally, the conductance modulation characteristics realizing synaptic learning are also confirmed in the RRAM.
TL;DR: The small variation range of memristance and the nonfloating operation that limit conventional memristor emulators are improved significantly and the circuit is designed to be built with off-the-shelf electronics devices.
Abstract: In this paper, we propose a memristor emulator that embraces most of features of a real memristor. The important features that a memristor emulator should include are a sufficiently wide range of memristance, bimodal operability of pulse and continuous signal inputs, a long period of nonvolatility, floating operation, operability with other devices, and the ability to be implemented with off-the-shelf devices. The proposed memristor emulator circuit contains all of these features. Specifically, the small variation range of memristance and the nonfloating operation that limit conventional memristor emulators are improved significantly. It is designed to be built with off-the-shelf electronics devices.
TL;DR: In this paper, the authors predict the material parameters that are necessary to achieve high efficiencies in a GaInP/GaAs/GAAsBi/Ge quad-junction cell.
Abstract: Multi-junction solar cells achieve high efficiency by stacking sub-cells of different bandgaps (typically GaInP/GaAs/Ge) resulting in efficiencies in excess of 40%. The efficiency can be improved by introducing a 1 eV absorber into the stack, either replacing Ge in a triple-junction configuration or on top of Ge in a quad-junction configuration. GaAs0.94Bi0.06 yields a direct-gap at 1 eV with only 0.7% strain on GaAs and the feasibility of the material has been demonstrated from GaAsBi photodetector devices. The relatively high absorption coefficient of GaAsBi suggests sufficient current can be generated to match the sub-cell photocurrent from the other sub-cells of a standard multi-junction solar cell. However, minority carrier transport and background doping levels place constraints on both p/n and p-i-n diode configurations. In the possible case of short minority carrier diffusion lengths we recommend the use of a p-i-n diode, and predict the material parameters that are necessary to achieve high efficiencies in a GaInP/GaAs/GaAsBi/Ge quad-junction cell.
TL;DR: In this article, a new environmental friendly solution combustion synthesis route, using ethanol as solvent, for the preparation of indium/gallium free amorphous zinc-tin oxide (ZTO) thin film transistors (TFTs) including AlOx gate dielectric was reported.
Abstract: Solution based deposition has been recently considered as a viable option for low-cost flexible electronics. In this context research efforts have been increasingly centred on the development of suitable solution-processed materials for oxide based transistors. Nevertheless, the majority of synthetic routes reported require the use of toxic organic solvents. In this work we report on a new environmental friendly solution combustion synthesis route, using ethanol as solvent, for the preparation of indium/gallium free amorphous zinc-tin oxide (ZTO) thin film transistors (TFTs) including AlOx gate dielectric. The decomposition of ZTO and AlOx precursor solutions, electrical characterization and stability of solution processed ZTO/AlOx TFTs under gate-bias stress, in both air and vacuum atmosphere, were investigated. The devices demonstrated low hysteresis (ΔV = 0.23 V), close to zero turn on voltage, low threshold voltage (VT = 0.36 V) and a saturation mobility of 0.8 cm2 V−1 s−1 at low operation voltages. Ethanol based ZTO/AlOx TFTs are a promising alternative for applications in disposable, low cost and environmental friendly electronics.
TL;DR: In this paper, a numerical study of the characteristics of p-GaN/n-ZnO light-emitting diodes (LEDs) with p-NiO and nZnSe interlayers, and on LED design optimization which includes bandgap engineering, thickness and doping of constituent layers.
Abstract: We report on a numerical study of the characteristics of p-GaN/n-ZnO light-emitting diodes (LEDs) with p-NiO and n-ZnSe interlayers, and on LED design optimization which includes bandgap engineering, thickness and doping of constituent layers The current-voltage dependences of investigated LEDs show a threshold voltage of 31 V, 54 V and 56 V for LED devices without and with the presence of p-NiO and n-ZnSe interlayers, respectively It is found that p-NiO, n-ZnSe and n-ZnO interlayers act as an electron blocking layer, active media layer, and electron transport layer, respectively It is established that the insertion of both p-NiO and n-ZnSe interlayers leads to the enhancement of charge carrier-confinement in the active region and to the significant increase of internal quantum efficiency (IQE) of the LED device up to 82%, which is comparable with IQE values in order to obtain better AlGaN- and InGaN-based LEDs It is found that the efficiency of LED devices at 100 A cm−2 is equal to 0024, 009 and 164% of external quantum efficiency (EQE), 13 × 10−4, 16 × 10−4, and 64 lm W−1 of PE, and 13 × 10−4, 29 × 10−4, and 12 cd A−1 of CE for p-GaN/n-ZnO, p-GaN/p-NiO/n-ZnO, and p-GaN/p-NiO/n-ZnSe/n-ZnO LED devices, respectively
TL;DR: In this article, the simultaneous influences of an intense laser field and static electric field on one-electron states and intraband optical absorption coefficient are investigated in two-dimensional GaAs/GaAl0.3 As quantum ring.
Abstract: The simultaneous influences of an intense laser field and static electric field on one-electron states and intraband optical absorption coefficient are investigated in two-dimensional GaAs/GaAl0.3 As quantum ring. An analytical expression of the effective confining potential in the presence of the external fields is obtained. The one-electron energy levels and wave functions are calculated using the effective mass approximation and an exact diagonalization technique. We show that changes in the incident light polarization lead to blue- or redshifts in the intraband optical absorption spectrum. Moreover, we found that blueshift and redshift are induced by the simultaneous influences of an intense laser and lateral electric fields. The obtained theoretical results indicate a novel opportunity to tune the performance of quantum rings and to control their specific properties by means of intense laser and homogeneous electric fields.
TL;DR: In this article, the effect of In on the growth dynamics of β-Ga2O3 was studied and it was observed that In was essential to obtain very high crystal quality. And the concentration of structural defects, such as stacking faults and twins, decreased dramatically and step-flow growth mode was achieved.
Abstract: (Ga1−xInx)2O3 epitaxial layers have been grown on (100) β-Ga2O3 substrates by metal organic vapour phase epitaxy (MOVPE). The process parameters were tuned in order to obtain an In-poor (Ga1−xInx)2O3 alloy, limiting the In incorporation below 3%. In this way it was possible to study the effect of In on the growth dynamics of Ga2O3. By varying the flow of the carrier gas (Ar) through the In precursor (trimethylindium) in a wide range, it was observed that for Ar/TMIn flows higher than a minimum threshold value, In was essential to obtain layers with very high crystal quality. The concentration of structural defects, such as stacking faults and twins, decreased dramatically and step-flow growth mode was achieved. These results have been explained by the tendency of In to float on the growing Ga2O3 surface, delivering an effective surfactant effect.
TL;DR: In this paper, the Bethe-Salpeter framework was used to compute dielectric functions of transparent conducting oxides and compared to spectra computed without excitonic effects.
Abstract: Transparent conducting oxides keep attracting strong scientific interest not only due to their promising potential for 'transparent electronics' applications but also due to their intriguing optical absorption characteristics. Materials such as In2O3 and Ga2O3 have complicated unit cells and, consequently, are interesting systems for studying the physics of excitons and anisotropy of optical absorption. Since currently no experimental data is available, for instance, for their dielectric functions across a large photon-energy range, we employ modern first-principles computational approaches based on many-body perturbation theory to provide theoretical-spectroscopy results. Using the Bethe–Salpeter framework, we compute dielectric functions and we compare to spectra computed without excitonic effects. We find that the electron–hole interaction strongly modifies the spectra and we discuss the anisotropy of optical absorption that we find for Ga2O3 in relation to existing theoretical and experimental data.
TL;DR: In this paper, the authors demonstrate that the biocompatible and biodegradable natural silk fibroin (SF) films embedded with silver nanowires (AgNWs) mesh could be employed as conductive transparent substrates to fabricate flexible organic light emitting diodes (OLEDs).
Abstract: Flexible and biodegradable electronics are currently under extensive investigation for biocompatible and environmentally-friendly applications. Synthetic plastic foils are widely used as substrates for flexible electronics. But typical plastic substrates such as polyethylene naphthalate (PEN) could not be degraded in a natural bio-environment. A great demand still exists for a next-generation biocompatible and biodegradable substrate for future application. For example, electronic devices can be potentially integrated into the human body. In this work, we demonstrate that the biocompatible and biodegradable natural silk fibroin (SF) films embedded with silver nanowires (AgNWs) mesh could be employed as conductive transparent substrates to fabricate flexible organic light emitting diodes (OLEDs). Compared with commercial PEN substrates coated with indium tin oxide, the AgNWs/SF composite substrates exhibit a similar sheet resistance of 12 Ω sq−1, a lower surface roughness, as well as a broader light transmission range. Flexible OLEDs based on AgNWs/SF substrates achieve a current efficiency of 19 cd A−1, demonstrating the potential of the flexible AgNWs/SF films as conductive and transparent substrates for next-generation biodegradable devices.
TL;DR: In this article, a combined growth approach involving both molecular-beam epitaxy and metal-organic vapor phase epitaxy has been developed to fabricate GaAsBi/GaAs-based quantum well (QW) laser structures with a Bi composition up to 8%.
Abstract: A combined growth approach involving both molecular-beam epitaxy and metal-organic vapor phase epitaxy has been developed to fabricate GaAsBi/GaAs-based quantum well (QW) laser structures with a Bi composition up to 8%. Lasing operation has been demonstrated at room temperature at 1.06 μm in laser diodes containing 3QWs that in turn contain approximately 6% Bi. A 5QW device demonstrated lasing at 1.09 μm at 80 K. Using temperature- and pressure-dependent measurements of stimulated emission as well as pure spontaneous emission measurements, we show that the threshold current of the devices is limited by non-radiative defect-related recombination and an inhomogeneous carrier distribution. This is suspected to be due to inhomogeneity of the QW width as well as non-uniform Bi composition in the active region.
TL;DR: In this paper, the performance of P3HT/PC70BM solar cells with different weight percentages of CuO nanoparticles was investigated and shown to increase the photo absorption of the active layer, this increased the power conversion efficiency of the solar cells by 24%.
Abstract: Copper oxide (CuO) is a p-type semiconductor with a band gap energy of 1.5 eV, this is close to the ideal energy gap of 1.4 eV required for solar cells to allow good solar spectral absorption. The inherent electrical characteristics of CuO nanoparticles make them attractive candidates for improving the performance of polymer solar cells when incorporated into the active polymer layer. The UV-visible absorption spectra and external quantum efficiency of P3HT/PC70BM solar cells containing different weight percentages of CuO nanoparticles showed a clear enhancement in the photo absorption of the active layer, this increased the power conversion efficiency of the solar cells by 24% in comparison to the reference cell. The short circuit current of the reference cell was found to be 5.234 mA cm �2 and it seemed to increase to 6.484 mA cm �2 in cells containing 0.6 mg of CuO NPs; in addition, the fill factor increased from 61.15% to 68.0%, showing an enhancement of 11.2%. These observations suggest that the optimum concentration of CuO nanoparticles was 0.6 mg in the active layer. These significant findings can be applied to design high-efficiency polymer solar cells containing inorganic nanoparticles.
TL;DR: In this paper, the authors compared two MOS based UHV 4H-SiC power switching devices; 15 kV 4h-siC MOSFETs and 15 kv 4hSiC n-IGBTs, and showed a specific on-resistance of 204 mΩ cm2 at 25 °C, which increased to 570 m Ω cm 2 at 150 °C. They also showed that the use of a carrier storage layer (CSL) can significantly improve the conduction performance of the 15kV 4 h-Si
Abstract: Ultra high voltage (UHV, >15 kV) 4H-silicon carbide (SiC) power devices have the potential to significantly improve the system performance, reliability, and cost of energy conversion systems by providing reduced part count, simplified circuit topology, and reduced switching losses. In this paper, we compare the two MOS based UHV 4H-SiC power switching devices; 15 kV 4H-SiC MOSFETs and 15 kV 4H-SiC n-IGBTs. The 15 kV 4H-SiC MOSFET shows a specific on-resistance of 204 mΩ cm2 at 25 °C, which increased to 570 mΩ cm2 at 150 °C. The 15 kV 4H-SiC MOSFET provides low, temperature-independent, switching losses which makes the device more attractive for applications that require higher switching frequencies. The 15 kV 4H-SiC n-IGBT shows a significantly lower forward voltage drop (VF), along with reasonable switching performance, which make it a very attractive device for high voltage applications with lower switching frequency requirements. An electrothermal analysis showed that the 15 kV 4H-SiC n-IGBT outperforms the 15 kV 4H-SiC MOSFET for applications with switching frequencies of less than 5 kHz. It was also shown that the use of a carrier storage layer (CSL) can significantly improve the conduction performance of the 15 kV 4H-SiC n-IGBTs.
TL;DR: In this article, the energy position of the charge neutrality level (CNL) in the III-VI semiconductors has been estimated for the first time, and the optimized lattice parameters have been obtained using vdW-DF2-C09 exchange-correlation functional.
Abstract: Density functional theory calculations have been applied to study the structural and electronic properties of layered -GaSe, γ-InSe, β-GaS and GaTe compounds. The optimized lattice parameters have been obtained using vdW-DF2-C09 exchange-correlation functional, which is able to describe dispersion forces and produces interlayer distances in close agreement with experiments. Based on the calculated electronic band structures, the energy position of the charge neutrality level (CNL) in the III–VI semiconductors has been estimated for the first time. The room-temperature values of CNL are found to be 0.80 eV, 1.02 eV, 0.72 eV and 0.77 eV for -GaSe, β-GaS, GaTe and γ-InSe, respectively. The persistent p-type conductivity of the intentionally undoped -GaSe, β-GaS and GaTe and n-type conductivity of γ-InSe crystals are discussed and explained using the concept of CNL. We also estimated the barrier heights for a number of metal/semiconductor and semiconductor/semiconductor interfaces assuming partial Fermi level pinning at the CNL. A reasonable agreement between our calculations and the available experimental data has been obtained.
TL;DR: In this paper, a hybrid source for emission at 540 nm consisting of a 450 nm GaN micro-sized LED (micro-LED) with a micron-thick ZnCdSe/ZncdMgSe multi-quantum-well color-converting membrane is reported.
Abstract: The rapid emergence of gallium-nitride (GaN) light-emitting diodes (LEDs) for solid-state lighting has created a timely opportunity for optical communications using visible light. One important challenge to address this opportunity is to extend the wavelength coverage of GaN LEDs without compromising their modulation properties. Here, a hybrid source for emission at 540 nm consisting of a 450 nm GaN micro-sized LED (micro-LED) with a micron-thick ZnCdSe/ZnCdMgSe multi-quantum-well color-converting membrane is reported. The membrane is liquid-capillary-bonded directly onto the sapphire window of the micro-LED for full hybridization. At an injection current of 100 mA, the color-converted power was found to be 37 μW. At this same current, the −3 dB optical modulation bandwidth of the bare GaN and hybrid micro-LEDs were 79 and 51 MHz, respectively. The intrinsic bandwidth of the color-converting membrane was found to be power-density independent over the range of the micro-LED operation at 145 MHz, which corresponds to a mean carrier lifetime of 1.9 ns.
TL;DR: The formation of new ternary NiGeSn and quaternary NiSiGeSn alloys has been investigated to fabricate metallic contacts on high Sn content, potentially direct bandgap group IV semiconductors as discussed by the authors.
Abstract: The formation of new ternary NiGeSn and quaternary NiSiGeSn alloys has been investigated to fabricate metallic contacts on high Sn content, potentially direct bandgap group IV semiconductors. (Si)GeSn layers were pseudomorphically grown on Ge buffered Si(001) by reduced pressure chemical vapor deposition. Ni, i.e. the metal of choice for source/drain metallization in Si nanoelectronics, is employed for the stano-(silicon)-germanidation of highly strained (Si)GeSn alloys. We show that NiGeSn on GeSn layers change phase from well-oriented Ni5(GeSn)3 to poly-crystalline Ni1(GeSn)1 at very low annealing temperatures. A large range of GeSn compositions with Sn concentrations up to 12 at.%, and SiGeSn ternaries with large Si and Sn compositions from 18%/3% to 4%/11% are investigated. In addition, the sheet resistance, of importance for electronic or optoelectronic device contacts, is quantified. The incorporation of Si extends the thermal stability of the resulting low resistive quaternary phase compared to their NiGeSn counterparts.
TL;DR: In this article, photoreflectance (PR), photoluminescence (PL) and time-resolved PL were applied to study the optical properties, particularly the localized and delocalized states and carrier dynamics, in GaAs1−xBix/GaAs quantum wells.
Abstract: Photoreflectance (PR), photoluminescence (PL) and time-resolved PL were applied to study the optical properties, particularly the localized and delocalized states and carrier dynamics, in GaAs1−xBix/GaAs quantum wells. With increasing Bi concentration the ground state transition (i.e., the transition between the first heavy hole and the first electron subband) red shifts due to Bi-related reduction of the GaAs1−xBix energy gap. Additionally, the transition related to the excited states in the quantum wells is clearly observed for the sample with high Bi concentration of 5.6%, confirming these quantum wells are type I. The PL measurements show the S-shape behavior and indicate the strong localization effect below 150 K for all measured samples, while the PL emission above 150 K is related to delocalized states. The localized character of emission at low temperatures is confirmed by time-resolved PL studies. At 10 K the decay time has strong spectral dispersion (i.e. the decay time increases from ~10 ns to ~400 ns going from the high to low energy side of the PL peak). This dispersion disappears above 190 K. At room temperature the decay time is in the order of a few ns.
TL;DR: In this paper, a review of typical materials that are being used in OFETs are discussed, and demonstrations of unidirectional coating methods are surveyed, and typical materials are discussed.
Abstract: Solution-processed organic field-effect transistors (OFETs) are essential for developing organic electronics. The encouraging development in solution-processed OFETs has attracted research interest because of their potential in low-cost devices with performance comparable to polycrystalline-silicon-based transistors. In recent years, unidirectional coating technology, featuring thin-film coating along only one direction and involving specific materials as well as solution-assisted fabrication methods, has attracted intensive interest. Transistors with organic semiconductor layers, which are deposited via unidirectional coating methods, have achieved high performance. In particular, carrier mobility has been greatly enhanced to values much higher than 10 cm2 V−1 s−1. Such significant improvement is mainly attributed to better control in morphology and molecular packing arrangement of organic thin film. In this review, typical materials that are being used in OFETs are discussed, and demonstrations of unidirectional coating methods are surveyed.
TL;DR: In this article, the authors investigated the temperature effects on the performance of the AlGaN/GaN high electron mobility transistor (HEMT) with a 150 nm and 250 nm gate length on a SiC substrate over a temperature range of −40 to 150 °C.
Abstract: This paper investigated the temperature effects on the performance of the AlGaN/GaN high electron mobility transistor (HEMT) with a 150 nm and 250 nm gate length on a SiC substrate over a temperature range of −40 to 150 °C including experimental characterization, modelling and analysis by on-wafer measurements up to 50 GHz. All the DC and small signal parameter variations with ambient temperature on the same set of devices have been reported for the first time. The temperature coefficient of all the DC and small signal parameters as well as f t and f max were reported. Some of the extracted equivalent circuit parameters with the theoretical data of the evolution of electrical parameters and the relevant physical equations involved have been compared using the same biasing condition for further accuracy. The theoretical results are shown to be consistent with the extracted data. Some results are also experimentally verified with previous works cited in the paper. The results provide some valuable insights for the underlying physics of the device parameters affected by temperature.
TL;DR: In this article, the improved purity of the AlN layers grown at low temperature was correlated to a dramatic increase in the sheet density of the two-dimensional electron gas (2DEG) at the alN/GaN heterointerface.
Abstract: When grown at a high temperature (820 °C) by ammonia-based molecular beam epitaxy (NH3-MBE), the AlN layers of metal-polar AlGaN/AlN/GaN heterostructures had a high GaN mole fraction (~0.15), as identified by atom probe tomography in a previous study (Mazumder et al 2013 Appl. Phys. Lett. 102 111603). In the study presented here, growth at low temperature (<740 °C) by NH3-MBE yielded metal-polar AlN layers that were essentially pure at the alloy level. The improved purity of the AlN layers grown at low temperature was correlated to a dramatic increase in the sheet density of the two-dimensional electron gas (2DEG) at the AlN/GaN heterointerface. Through application of an In surfactant, metal-polar AlN(3.5 nm)/GaN and AlGaN/AlN(2.5 nm)/GaN heterostructures grown at low temperature yielded low 2DEG sheet resistances of 177 and 285 Ω/, respectively.
TL;DR: In this paper, a GaN HEMT with a polarization-graded AlGaN buffer is performed by two-dimensional analysis of drift-diffusion simulations, and the bulk trap-induced current collapse of the proposed structure is effectively restrained in contrast to that of conventional HEMTs with either GaN or AlGaNs buffer.
Abstract: A GaN HEMT with a polarization-graded AlGaN buffer is performed by two-dimensional analysis of drift-diffusion simulations. The bulk trap-induced current collapse of the proposed structure is effectively restrained in contrast to that of conventional HEMTs with a GaN or AlGaN buffer, resulting from the fact that the high and flat back-barrier altitude in the proposed structure prevents the two-dimensional electron gas (2DEG) from spilling over from the channel, with the reduction of hot carriers injecting into the buffer followed by trapping in deep acceptor-like levels. Simultaneously, the off-state breakdown voltage is remarkably enhanced, due to the strong electric breakdown field of the polarization-graded AlGaN buffer and the restraint of the buffer leakage current. In addition, the relationship between the off-state breakdown voltage and the thickness of the polarization-graded AlGaN buffer is analyzed.
TL;DR: In this article, the potential of the vacuum route is benchmarked against solution approaches and found to be highly competitive, and the main issues that need to be resolved in order to fully develop the vacuum-evaporation route to R2R circuit production are highlighted.
Abstract: Surprisingly little consideration is apparently being given to vacuum-evaporation as the route for the roll-to-roll (R2R) production of large-area organic electronic circuits. While considerable progress has been made by combining silicon lithographic approaches with solution processing, it is not obvious that these will be compatible with a low-cost, high-speed R2R process. Most efforts at achieving this ambition are directed at conventional solution printing approaches such as inkjet and gravure. This is surprising considering that vacuum-evaporation of organic semiconductors (OSCs) is already used commercially in the production of organic light emitting diode displays. Beginning from a discussion of the materials and geometrical parameters determining transistor performance and drawing on results from numerous publications, this review makes a case for vacuum-evaporation as an enabler of R2R organic circuit production. The potential of the vacuum route is benchmarked against solution approaches and found to be highly competitive. For example, evaporated small molecules tend to have higher mobility than printed OSCs. High resolution metal patterning on plastic films is already a low-cost commercial process for high-volume packaging applications. Similarly, solvent-free flash-evaporation and polymerization of thin films on plastic substrates is also a high-volume commercial process and has been shown capable of producing robust gate dielectrics. Reports of basic logic circuit elements produced in a vacuum R2R environment are reviewed and shown to be superior to all-solution printing approaches. Finally, the main issues that need to be resolved in order to fully develop the vacuum route to R2R circuit production are highlighted.
TL;DR: In this article, the performance of In-Ga-Zn-O (IGZO) thin-film transistors with Al2O3 gate insulator was investigated.
Abstract: We studied how the performance of In–Ga–Zn–O (IGZO) thin film transistors (TFTs) with Al2O3 gate insulator was affected by post-fabrication annealing temperature and annealing time. At a fixed annealing time of 2 min, the IGZO TFT exhibited the best transfer and output characteristics in the case of 300 °C in N2 atmosphere, which is attributed to the achievement of appropriate carrier concentration and Hall mobility in the IGZO film. Further, it was found that both of the carrier concentration and Hall mobility in the IGZO film increased with the increment of annealing temperature. For the annealing temperature of 300 °C, the performance of the IGZO TFT was further improved by extending annealing time to 5 min, i.e., the field effect mobility, sub-threshold swing and on/off current ratio were 11.6 cm2/(V · s), 0.42 V dec−1 and 106, respectively. The underlying mechanism was discussed.
TL;DR: In this paper, the effect of growth conditions on the electronic properties of GaAs1−xBix grown on GaAs by molecular beam epitaxy has been investigated by means of temperature dependent photoluminescence (PL).
Abstract: The effect of growth conditions on the electronic properties of GaAs1−xBix grown on GaAs by molecular beam epitaxy has been investigated by means of temperature dependent photoluminescence (PL). When the substrate temperature during growth was reduced from 400 °C to 300 °C and all other growth conditions were fixed, the Bi concentration in the deposited films increased from 1% to 5% and the PL intensity decreased by more than a factor of 1000. Two samples were grown at different temperatures (330 °C and 375 °C) with approximately the same Bi concentration (~2%) at a stoichiometric As:Ga flux ratio. The temperature dependence of the PL shows that the sample grown at high temperature has less PL emission from sub-bandgap states and a stronger temperature dependence of the bandgap. We conclude that GaAs1−xBix samples grown at higher temperatures have a lower density of shallow and deep electronic states in the bandgap.
TL;DR: In this paper, the formation of recess etched Au-free ohmic contacts to an InAlN/Al N/GaN heterostructure was investigated, where a Ta/Al/Ta metal stack was used to produce contacts with contact resistance (R-c) as low as 0.14 Omega mm.
Abstract: The formation of recess etched Au-free ohmic contacts to an InAlN/AlN/GaN heterostructure is investigated. A Ta/Al/Ta metal stack is used to produce contacts with contact resistance (R-c) as low as 0.14 Omega mm. It is found that R-c decreases with increasing recess depth until the InAlN barrier is completely removed. For even deeper recesses R-c remains low but requires annealing at higher temperatures for contact formation. The lowest R-c is found for contacts where the recess etch has stopped just above the 2D electron gas channel. At this depth the contacts are also found to be less sensitive to other process parameters, such as anneal duration and temperature. An optimum bottom Ta layer thickness of 5-10 nm is found. Two reliability experiments preliminary confirm the stability of the recessed contacts.