TL;DR: In this article, a joint analysis of the distributions of some biogeochemical variables and their relation to the hydrodynamics of Gibraltar Strait is presented, with emphasis on the two physical processes that are proposed as key factors for the coupling: interface position and oscillations, and mixing processes along the Strait.
TL;DR: In this article, the ability of microorganisms and higher plants to transform polycyclic aromatic hydrocarbons and their importance in the remediation of polluted soils is examined, and emerging areas of research intended to improve the available treatment processes are discussed.
TL;DR: The U.S. EPA's Integrated Risk Information System (IRIS) program has initiated a health assessment for polycyclic aromatic hydrocarbon (PAH) mixtures as mentioned in this paper.
TL;DR: Findings of this study establish the relationship between bioavailability and the acute toxic effects of B a P observed in the laboratory at these high doses.
TL;DR: In this paper, the best passive samplers among eleven plants diffused in the Mediterranean basin for the determination of polycyclic aromatic hydrocarbons in the atmosphere in substitution to the particulate matter sampling were selected.
TL;DR: The lowering of the legal concentration of sulfur in fuels (in the European Union from 150 ppm at present to 50 ppm in 2004) not only affects the concentration but also the pattern of the polycycli...
TL;DR: The environmental impact of polycyclic aromatic compounds (PACs) in asphalt (bitumen) materials is related to their availability for environmental transport and biouptake, rather than their total concentrations as discussed by the authors.
TL;DR: In this article, the contamination by 16 polycyclic aromatic hydrocarbons (PAHs) in surface soils, sampled at a 0-5 cm depth in the urban areas of Tallinn, Helsinki, Vilnius, Chicago, London is reported.
TL;DR: In this article, two different oligomeric calix[4]arene-crowns (2b and 3b ) were synthesized via the condensation reaction of p- tert -butylcalix(4) with 1,5-dibromopentane.
TL;DR: Analysis of the growth and substrate depletion kinetics showed a classical pattern and it was demonstrated that B a P mineralization by the non-white rot fungus F. solani occurred rapidly at early stages of fermentation (15 hr) during the germination process.
TL;DR: In order to determine the respective contribution of cutaneous and respiratory exposure to urinary PyOH excretion, some experimental follow-ups were carried out during cathode relining in the aluminum industry, leading to qualitative (excretion profiles) and quantitative assessments (excreted PyOH/inhaled pyrene).
TL;DR: In this paper, the exposure profiles indicate an important lag between the excretion of the two metabolites: the maximum of 3-OHB a P urinary excretion is observed 10 to 17 hours after the 1-OHPy maximum, with a much closer correlation ( r = 0.81) than that obtained with both metabolites in real time ( r < 0.21).
TL;DR: In this paper, the formation of particles during the reaction of naphthalene with OH radicals in a smog chamber was followed by means of a scanning particle-sizing system and aerosol spectrometer probe.
TL;DR: In this paper, a comparison between Soxhlet, ultrasonic, and microwave assisted extraction (MAE) of polycyclic aromatic hydrocarbons (PAHs) from diesel particulate matter was made.
TL;DR: Interaction with other chemicals may dramatically affect the toxicological effects of some polycyclic aromatic carcinogens, and the effect of ethanol may be relevant for some human exposures to poly cyclic aromatic compounds.
TL;DR: For the first time, 13 polycyclic aromatic hydrocarbons (PAHs) have been identified in samples of surface sediments at 17 stations on the Vigo estuary (northwest Spain) and its adjacent shelf.
TL;DR: In this article, a multivariate decomposition method (principal component analysis) has been applied together with univariate methods to assess the early fate of petrogenic compounds in the marine environment following the Baltic Carrier oil spill.
TL;DR: In this paper, surface sediments from six sampling sites in the Cotonou lagoon were used to assess the urban runoff contribution of polycyclic aromatic hydrocarbons accumulation in this ecosystem.
TL;DR: In this article, diesel exhaust particulate matter (DEP) extracts were collected from three commercial diesel engine vehicles and DEP extracts (DEPEs) were prepared from each, and the estrogenic and antiestrogenic activities of the DEPE samples were examined using an estrogen response element (ERE)-driven luciferase reporter gene assay in MCF-7 human breast cancer cells.
TL;DR: The ability of Sphingomonas paucimobilis strain EPA 505 (a soil bacterium capable of utilizing fluoranthene as the sole source of carbon and energy for growth) to metabolize 3-methyl-methylfluoranthene, 7-methlybenz[a ]anthracene, 5-methylchrysene, and their corresponding unsubstituted parent hydrocarbons was investigated.
TL;DR: In this paper, the biotransformation of 16 polycyclic aromatic hydrocarbons (PAHs) in mixture was investigated in reactors in the presence of purified laccases of the fungus Pycnoporus cinnabarinus, ABTS as a redox mediator, 25% acetonitrile, and Tween 20.
TL;DR: The first natural matrix Standard Reference Material (SRM) for the determination of polycyclic aromatic compounds (PACs), SRM 1580 Organics in Shale Oil, was developed by the National Institute of Standards and Technology (NIST).
TL;DR: In this article, photolysis products of 1-hydroxypyrene (1-HP) were identified by liquid chromatography coupled with mass spectrometry (LC/MS/MS).
TL;DR: In this paper, the spectral-luminescence (Shpol'skii) method was used to assess the contamination of a very special lake, Lake Baikal in Siberia and two big lakes, Ladoga and Onega in the European part of Russia, by polycyclic aromatic hydrocarbons (PAHs).
TL;DR: Partitioning behavior of PAHs including NAP, FLO, PHE, and PYR was investigated in this paper, where a plot of experimental K-HA against log K-OW gives a good linear relationship.
TL;DR: The formation of a benzo[ c ]fluorene-derived DNA adduct in rat lung following coal tar exposure is consistent with previous studies performed with mice.
TL;DR: In this article, the Suzuki coupling reaction was used to synthesize important metabolites of 7,12-dimethylbenz[a ]anthracene (DMBA) and benzo[c ]chrysene (B[ c ]C).
TL;DR: In this article, sample preparation techniques using solid phase extraction (SPE) and solid phase microextraction (SPME) are compared for the analysis of monohydroxy polycyclic aromatic hydrocarbons (OHPAH) in human urine.
TL;DR: Treatment of P450 1B1 knockout mice and DNA binding studies with fibroblasts isolated from these animals provided further evidence for the central role of P550 1A1-catalyzed formation of ( m )- anti -DB[ a,l ]PDE-DNA adducts in DB[ a-l ]P-induced carcinogenesis.
TL;DR: In this paper, the authors used microbore columns to accelerate the analysis of polycyclic aromatic compounds (PAHs) with an increase in chromatographic resolution, which can reduce the number of theoretical plates per meter by about 45% and 60% respectively.