TL;DR: In vitro experiments demonstrate that the prepared CDSNPs based dual-PS UC-PDT system exhibits excellent biocompatibility with normal cells and exceptional synergistic photodynamic efficacy against tumor cells upon near-infrared excitation.
Abstract:
Upconversion photodynamic therapy (UC-PDT), which integrates upconversion nanoparticles (UCNPs) with photosensitizers (PSs), presents a promising advancement in the field of phototherapy. However, despite the extensive studies focused on the design and synthesis of UCNPs, there is a paucity of systematic research on the mechanisms underlying the synergistic upconversion photodynamic effects. Here we have synthesized upconversion core@dotted-shell nanoparticles (CDSNPs) and covalently tethered them with two distinct PSs, thereby constructing a dual-PS UC-PDT system with high synergistic photodynamic performance. To unravel the mechanism underlying the synergism, we employed a combination of quantum mechanical calculations and ultrafast time-resolved spectroscopy techniques. The results indicate that rare earth oxides play a pivotal role in enhancing the intersystem crossing processes of PSs through modulating their excited electronic states. Additionally, Förster resonance energy transfer between two distinct PSs contributes to the amplification of triplet state populations, thus further enhancing the photodynamic effect. In vitro experiments demonstrate that the prepared CDSNPs based dual-PS system exhibits excellent biocompatibility with normal cells and exceptional synergistic photodynamic efficacy against tumor cells upon near-infrared excitation. This research contributes theoretical insights into the design and application of multi-photosensitizer UC-PDT systems, laying the groundwork for more efficient preclinical implementations in the future.
TL;DR: Achieving asymmetry parameter-insensitive resonant modes through relative shift–induced quasi-bound states in the continuum. High-Q resonances stemming from symmetry-protected bound states in the continuum are insensitive to variations in asymmetry parameters. This work introduces the concept of relative shift–induced quasi-bound states, which remain insensitive to variations in asymmetry parameters and have flexibly tunable Q-factors.
Abstract: Abstract High-Q resonances in metasurfaces, stemming from symmetry-protected bound states in the continuum (BICs), have proven to be effective for achieving high-performance optical devices. However, the properties associated with symmetry-protected BICs are inherently limited, as even a slight variation in the asymmetry parameter leads to a noticeable shift in the resonance location. Herein, we introduce the concept of relative shift–induced quasi-BICs (QBICs) within dimerized silicon (Si) meta-lattices (DSMs), which can be excited when a nonzero relative shift occurs, a result of in-plane inversion symmetry breaking and Brillouin zone folding within the structure. These QBICs have resonance locations that remain insensitive to variations in asymmetrical parameters. Additionally, their Q-factors can be flexibly tuned, benefiting from the inverse square dependence on asymmetrical parameters. In experiment, six DSMs with different relative shifts are fabricated and the asymmetry parameter-insensitive resonant modes under two orthogonal polarization states are experimentally observed in the optical communication waveband. Our results offer unique opportunities for constructing high-Q resonators with enhanced performances, which can be applied in various optical fields.
TL;DR: Ultra-broadband and wide-angle nonreciprocal thermal emitter based on Weyl semimetal metamaterials achieves nonreciprocal thermal radiation in a wide range of wavelengths and angles.
Abstract: Abstract Nonreciprocal thermal radiation can violate Kirchhoff’s law and exhibit different emissivity at symmetric polar angles relative to the normal direction. Realizing a mid-infrared broadband nonreciprocal thermal emitter with a wide emission angle range is a fundamental yet challenging task, particularly without the need for an external magnetic field. Here, we propose a nonreciprocal thermal emitter operating in the mid-infrared that achieves a significantly nonreciprocal thermal radiation in a wavelength range from 12 μm to 20 μm, spanning a wide angular range from 16° to 88°. This is achieved by utilizing a multilayered Weyl semimetal (WSM)/dielectric structure, which takes the advantage of the strong nonreciprocity of WSMs with different Fermi levels and epsilon-near-zero-induced Brewster modes. The results provide a wider angular range in the broad mid-infrared band compared to previous attempts. The robustness of the nonreciprocal radiation is confirmed through wavelength-averaged emissivity across the azimuth angle φ range from 0° to 360°. Some possible materials and nanostructures as dielectric layers are discussed, showcasing the flexibility and reliability of the design. This work holds promising potential applications such as enhanced radiative cooling, thermal emitters for medical sensing and infrared heating, energy conversion, etc.
TL;DR: Controlling thermal emission with metasurfaces enables flexible tuning of thermal emission properties and has opened new avenues for compact and integrated infrared applications.
Abstract:
Thermal emission caused by the thermal motion of the charged particles is commonly broadband, un-polarized, and incoherent, like a melting pot of electromagnetic waves, which makes it unsuitable for infrared applications in many cases requiring specific thermal emission properties. Metasurfaces, characterized by two-dimensional subwavelength artificial nanostructures, have been extensively investigated for their flexibility in tuning optical properties, which provide an ideal platform for shaping thermal emission. Recently, remarkable progress was achieved not only in tuning thermal emission in multiple degrees of freedom, such as wavelength, polarization, radiation angle, coherence, and so on but also in applications of compact and integrated optical devices. Here, we review the recent advances in the regulation of thermal emission through metasurfaces and corresponding infrared applications, such as infrared sensing, radiative cooling, and thermophotovoltaic devices.
TL;DR: Thermally tunable VO2 metasurfaces enable switchable holography and digital encryption. High-quality holographic images are generated by manipulating the insulator-to-metal phase transition in VO2 nanofins.
Abstract: Abstract Metasurface holography has aroused immense interest in producing holographic images with high quality, higher-order diffraction-free, and large viewing angles by using a planar artificial sheet consisting of subwavelength nanostructures. Despite remarkable progress, dynamically tunable metasurface holography in the visible band has rarely been reported due to limited available tuning methods. In this work, we propose and numerically demonstrate a thermally tunable vanadium dioxide (VO2) nanofin based binary-phase metasurface, which generates holographic information in the visible varying with temperature. The insulator-to-metal phase transition in VO2 nanofins allows two independent binary-phase holograms generated by machine learning to be encoded in the respective phases of VO2 and switched under thermal regulation. By elaborately designing the dimensions and compensated phase of VO2 nanofins, high-quality images are reconstructed at corresponding temperatures under appropriate chiral illumination. In contrast, much poorer images are produced under inappropriate chiral illumination. We further demonstrate the advantage of applying the VO2 phase-compensated metasurface in high-security digital encryption, where two desired character combinations are read out with appropriate excitations and temperatures, whereas one identical fraudulent message is received with inappropriate excitations. Our design approach offers a new and efficient method to realize tunable metasurfaces, which is promisingly adopted in dynamic display, information encryption, optical anti-counterfeiting, etc.
TL;DR: Lithium niobate thin film electro-optic modulator exhibits high modulation amplitude and simple fabrication process.
Abstract:
The linear electro-optic effect offers a valuable means to control light properties via an external electric field. Lithium niobate (LN), with its high electro-optic coefficients and broad optical transparency ranges, stands out as a prominent material for efficient electro-optic modulators. The recent advent of lithium niobate-on-insulator (LNOI) wafers has sparked renewed interest in LN for compact photonic devices. In this study, we present an electro-optic modulator utilizing a thin LN film sandwiched between top and bottom gold (Au) film electrodes, forming a Fabry–Pérot (F–P) resonator. This resonator exhibits spectral resonance shifts under an applied electric field, enabling efficient modulation of reflected light strength. The modulator achieved a 2.3 % modulation amplitude under ±10 V alternating voltage. Our approach not only presents a simpler fabrication process but also offers larger modulation amplitudes compared to previously reported metasurface based LN electro-optic modulators. Our results open up new opportunities for compact electro-optic modulators with applications in beam steering devices, dynamic holograms, and spatial light modulators, and more.
TL;DR: Tightly focused optical skyrmions and merons are generated by electric-field vectors with prescribed characteristics. The topology types and the normal direction of the topology projection plane can be tailored at will.
Abstract: Abstract Optical skyrmions, which are topological quasi-particles with nontrivial electromagnetic textures, have garnered escalating research interest recently for their potential in diverse applications. In this paper, we present a method for generating tightly focused optical skyrmion and meron topologies formed by electric-field vectors under 4π-focusing system, where both the topology types (including Néel-, Bloch-, intermediate- and anti-skyrmion/meron) and the normal direction of the two-dimensional topology projection plane can be tailored at will. By utilizing time-reversal techniques, we analytically derive the radiation pattern of a multiple concentric-ring array of dipoles (MCAD) to obtain the required illumination fields on the pupil planes of the two high numerical aperture lenses. The Deby vector diffraction integral theory is employed to calculate the corresponding tightly focused field, and their topology characteristics are quantitatively evaluated by the electric-field vector distribution. The results demonstrate that arbitrary electric-field based skyrmion and meron can be conveniently generated by adjusting the oscillation direction of each dipole in the MCAD and the normal direction of the dipole array. The generated optical topologies with fully controllable degrees of freedom provide potential applications in optical information processing, transmission, and storage.
TL;DR: The resonance theory of vibrational polariton chemistry at the normal incidence explains the resonance effect of the vibrational strong coupling (VSC) modified reaction rate constant at the normal incidence of a Fabry–Pérot (FP) cavity based on a mechanistic hypothesis that cavity modes promote the transition from the ground state to the vibrational excited state of the reactant.
Abstract: Abstract We present a theory that explains the resonance effect of the vibrational strong coupling (VSC) modified reaction rate constant at the normal incidence of a Fabry–Pérot (FP) cavity. This analytic theory is based on a mechanistic hypothesis that cavity modes promote the transition from the ground state to the vibrational excited state of the reactant, which is the rate-limiting step of the reaction. This mechanism for a single molecule coupled to a single-mode cavity has been confirmed by numerically exact simulations in our recent work in [J. Chem. Phys. 159, 084104 (2023)]. Using Fermi’s golden rule (FGR), we formulate this rate constant for many molecules coupled to many cavity modes inside a FP microcavity. The theory provides a possible explanation for the resonance condition of the observed VSC effect and a plausible explanation of why only at the normal incident angle there is the resonance effect, whereas, for an oblique incidence, there is no apparent VSC effect for the rate constant even though both cases generate Rabi splitting and forming polariton states. On the other hand, the current theory cannot explain the collective effect when a large number of molecules are collectively coupled to the cavity, and future work is required to build a complete microscopic theory to explain all observed phenomena in VSC.
TL;DR: High-Q Fano resonances metasurfaces excited by asymmetric dielectric rods for refractive index sensing enables dual-channel detection with high sensitivity and high Q-factor.
Abstract:
The metasurface refractive index sensor has a high degree of tunability and flexibility, providing excellent performance for high precision refractive index sensing applications. The metasurface absorber with metallic structure has been hindered in further sensor applications due to the inherent Ohmic loss of the metallic material. In this study, a dual nanorod metasurface structure based on semiconductor Si was designed, introducing a symmetry-breaking structure to excite dual ultra-narrow q-BIC resonance peaks with Fano line shapes. Both peaks are located in the near-infrared region, and multipole analysis shows that this strong field enhancement effect is induced by a magnetic dipole. Experimental results demonstrate the potential of this sensor to provide dual-channel detection while achieving high sensitivity and high Q-factor. We believe that this device exhibits outstanding performance and high practicality, providing a reference for the development and application of biological and environmental sensors.
TL;DR: AI-powered advanced metasurface research explores the intersection of AI and metasurfaces, leveraging AI's computational power to design, analyze, and optimize metasurfaces for various applications.
Abstract: Abstract In recent years, metasurface, as a representative of micro- and nano-optics, have demonstrated a powerful ability to manipulate light, which can modulate a variety of physical parameters, such as wavelength, phase, and amplitude, to achieve various functions and substantially improve the performance of conventional optical components and systems. Artificial Intelligence (AI) is an emerging strong and effective computational tool that has been rapidly integrated into the study of physical sciences over the decades and has played an important role in the study of metasurface. This review starts with a brief introduction to the basics and then describes cases where AI and metasurface research have converged: from AI-assisted design of metasurface elements up to advanced optical systems based on metasurface. We demonstrate the advanced computational power of AI, as well as its ability to extract and analyze a wide range of optical information, and analyze the limitations of the available research resources. Finally conclude by presenting the challenges posed by the convergence of disciplines.
TL;DR: Deep-subwavelength multilayered meta-coatings enable visible-infrared compatible camouflage with high angle tolerance and large-area fabrication feasibility.
Abstract:
Camouflage is a common technique in nature, enabling organisms to protect themselves from predators. The development of novel camouflage technologies, not only in fundamental science, but also in the fields of military and civilian applications, is of great significance. In this study, we propose a new type of deep-subwavelength four-layered meta-coating consisting of Si, Bi, Si, and Cr from top to bottom with total thickness of only ∼355 nm for visible-infrared compatible camouflage. The visible color and the infrared emission properties of the meta-coating can be independently adjusted. Colorful meta-coating for visible camouflage can be obtained by changing the thickness of top Si layer, while the selective high emissivity in non-atmospheric window for infrared camouflage remains. Due to the deep-subwavelength properties, the meta-coating shows high angle tolerance in both visible and infrared regions. The compatible camouflage capability of our proposed meta-coating in the visible-infrared region is validated under different environments. The deep-subwavelength, angular insensitivity, visible-infrared compatibility and large-area fabrication feasibility promise the meta-coating an effective solution for camouflage in various applications such as military weapons and anti-counterfeiting.
TL;DR: Optical computing metasurfaces offer high-speed, low-energy, and highly parallel computing capabilities. However, challenges such as device integration and portability remain. Recent research advances in metasurfaces provide new platforms for optical computing applications.
Abstract:
Integrated photonic devices and artificial intelligence have presented a significant opportunity for the advancement of optical computing in practical applications. Optical computing technology is a unique computing system based on optical devices and computing functions, which significantly differs from the traditional electronic computing technology. On the other hand, optical computing technology offers the advantages such as fast speed, low energy consumption, and high parallelism. Yet there are still challenges such as device integration and portability. In the burgeoning development of micro–nano optics technology, especially the deeply ingrained concept of metasurface technique, it provides an advanced platform for optical computing applications, including edge detection, image or motion recognition, logic computation, and on-chip optical computing. With the aim of providing a comprehensive introduction and perspective for optical computing metasurface applications, we review the recent research advances of optical computing, from nanostructure and computing methods to practical applications. In this work, we review the challenges and analysis of optical computing metasurfaces in engineering field and look forward to the future development trends of optical computing.
TL;DR: Transparent energy-saving windows based on broadband directional thermal emission enhance space-cooling performance through angular selective emission and high visible transmittance.
Abstract: Abstract Passive radiative cooling has emerged as a sustainable energy-saving solution, characterized by its energy-free operation and absence of carbon emissions. Conventional radiative coolers are designed with a skyward orientation, allowing for efficient heat dissipation to the cold heat sink. However, this design feature presents challenges when installed on vertical surfaces, as nearby objects obstruct heat release by blocking the cooler’s skyward view. Here, we introduce a directional radiative cooling glass (DRCG) designed to facilitate efficient heat dissipation through angular selective emission. The DRCG is constructed as a multilayer structure incorporating epsilon-near-zero materials, specifically Si3N4 and Al2O3, layered on an indium-tin-oxide thermal reflector. This innovative design restricts thermal emission to specific angular ranges, known as the Berreman mode. Additionally, the transparent layers enable a visible transmittance exceeding 84 %. Theoretical simulations validate the enhanced cooling performance of the DRCG, exhibiting a temperature reduction of over 1.5 °C compared with conventional glass in hot urban environments characterized by a nearby object temperature exceeding 60 °C and a sky view factor of 0.25. Furthermore, outdoor experiments demonstrate that employing the DRCG as a window enhances space-cooling performance by ∼1.5 °C. These findings underscore the potential of transparent energy-saving windows in mitigating the urban heat island effect.
Guseon Kang, Younggeun Lee, Jaeyoon Kim, Dong Jun Yang1, Han Ku Nam2, Shinhyung Kim, Soojeong Baek2, Hyo-sang Yoon, Joohyung Lee, Teun-Teun Kim, Young-Jin Kim•
TL;DR: Frequency comb measurements are essential for evaluating the performance of 6G terahertz nano/microphotonics and metamaterials.
Abstract:
Next-generation 6G communication holds the potential to revolutionize data transfer, enabling the realization of eXtended Reality (XR) with enhanced sensory experiences. To achieve this, advanced components such as high-performance intensity/phase modulators, waveguides, multiplexers, splitters, combiners, and filters operating in terahertz (THz) regime, specifically within the frequency range of 0.1–1 THz, are essential. However, existing microwave equipment and vector network analyzers designed for this frequency range suffer from limitations in resolution, stability, and accuracy when evaluating the intensity and phase responses of critical 6G THz devices. In this comprehensive review, we delve into the critical device requirements and emerging trends in next-generation 6G communication, essential performance evaluation parameters, comparisons between microwave and nano/microphotonic devices for testing, and the application of high-resolution THz sensors in 6G Internet-of-Things (IoT) scenarios. Notably, a frequency comb in the photonic regime emerges as the prime candidate for achieving precision evaluations of 6G networks and devices. Consequently, this review highlights the latest research in frequency comb measurements in the 6G THz frequency regime, with a particular emphasis on nano/microphotonic devices and metamaterials. The integration of frequency comb measurements into 6G and THz photonic devices and networks promises to accelerate the realization of high-density next-generation 6G communication.
TL;DR: Large-scale photonic inverse design faces significant computational challenges due to the need for full-wave Maxwell solutions. Various electromagnetic solvers and optimization techniques are reviewed to address these challenges, highlighting the need for advancements in optimization methods, solver selection, and the integration of neural networks.
Abstract:
Recent advancements in inverse design approaches, exemplified by their large-scale optimization of all geometrical degrees of freedom, have provided a significant paradigm shift in photonic design. However, these innovative strategies still require full-wave Maxwell solutions to compute the gradients concerning the desired figure of merit, imposing, prohibitive computational demands on conventional computing platforms. This review analyzes the computational challenges associated with the design of large-scale photonic structures. It delves into the adequacy of various electromagnetic solvers for large-scale designs, from conventional to neural network-based solvers, and discusses their suitability and limitations. Furthermore, this review evaluates the research on optimization techniques, analyzes their advantages and disadvantages in large-scale applications, and sheds light on cutting-edge studies that combine neural networks with inverse design for large-scale applications. Through this comprehensive examination, this review aims to provide insights into navigating the landscape of large-scale design and advocate for strategic advancements in optimization methods, solver selection, and the integration of neural networks to overcome computational barriers, thereby guiding future advancements in large-scale photonic design.
TL;DR: A metasurface color router facilitates RGB-NIR sensing for an image sensor application by splitting the spectrum and redirecting light to targeted pixel surfaces.
Abstract:
CMOS image sensor (CIS) plays a crucial role in diverse optical applications by facilitating the capture of images in the visible and near-infrared spectra. The enhancement of image resolution in CIS by an increase in pixel density is becoming more significant and realizable with the recent progress of nanofabrication. However, as pixel size decreases towards the diffraction limit, there is an inevitable trade-off between the scale-down of pixel size and the enhancement of optical sensitivity. Recently, to overcome this, an entirely new concept of spectral sensing using a nanophotonic-based color router has been proposed. In this work, we present a metasurface-based spectral router to effectively split the spectrum from visible to near-infrared and redirect through the four optical channels to the targeted pixel surfaces. We optimize the metasurface that simultaneously controls the phases of the transmitted light of targeted spectra, i.e. red (R), green (G), blue (B), and near-infrared (NIR), which is the largest number of channels reported based on a single layered metasurface and has an optical efficiency that surpasses the efficiency of conventional color filter systems.
TL;DR: Highly fault-tolerant and scalable adaptive radiative cooler based on Fabry–Perot resonant cavity achieves high modulation rate and significant cooling performance difference.
Abstract:
Conventional static radiative coolers have an unadjustable cooling capacity, which often results in overcooling in low temperature environment. Therefore, there is a great need for an adaptive dynamic radiative cooler. However, such adaptive coolers usually require complex preparation processes. This paper proposes an adaptive radiative cooler based on a Fabry–Perot resonant cavity. By optimizing the structural parameters of the radiative cooler, this adaptive radiative cooler achieves a modulation rate of 0.909 in the atmospheric window band. The net radiative cooling performance difference between low and high temperatures is nearly eight times. Meanwhile, the device is easily prepared, has a high tolerance, and can effectively prevent W–VO2 oxidation. This study provides new insights into adaptive radiative cooling with potential for large-scale applications.
TL;DR: Aberration-corrected hybrid metalens for longwave infrared thermal imaging achieve wide-angle, low-distortion imaging with high modulation transfer function and efficiency.
Abstract: Abstract Wide-angle metalenses in the longwave infrared have shown great advantages over the traditional refractive doublets or triplets, due to light weight, CMOS compatibility, and low cost. However, previous endeavors have been plagued by challenges including a narrow waveband, large F-number, distortion, and spherical aberration. To address these problems, this study introduces two dispersive metasurfaces, placed near the front focal plane and upon the rear plane of a plano-convex lens, to correct optical aberrations. Utilizing this methodology, we propose and experimentally demonstrate an aberration-corrected hybrid metalens for thermal imaging in the 8–12 μm waveband, featuring an FOV of 24°, F-number of 1.2, and diameter of 12.2 mm. The developed hybrid metalens rigorously evaluated, exhibits Modulation Transfer Function (MTF) values exceeding 0.2 at 20 Lp/mm across the full FOV, and features an average transmission of 48.7 %, a relative focusing efficiencies of up to 42.1 %, polarization insensitivity and broadband imaging capacity. These results emphasize the potential applications of our system in diverse fields, such as camera lenses, autonomous driving, healthcare, and environmental monitoring.
TL;DR: Collimated flat-top beam shaper metasurface doublet based on the complex-amplitude constraint Gerchberg–Saxton algorithm generates flat-top beams with high homogeneity and low wavefront error.
Abstract: Abstract Collimated flat-top beam shapers primarily consisting of freeform lenses have a wide range of applications and pose challenges in terms of processing and integration when the diameter is less than millimeters. Metasurfaces represent a promising solution to planarize optics, can mimic any surface curvature without additional fabrication difficulty, and are suitable for flat-top optics. The conventional metasurface design approach relies on imparting the required phase using meta-atoms and encounters challenges in amplitude modulation due to near-field coupling and varying transmittances among meta-atoms with different phases, making the design of flat-top beam shapers difficult. In this paper, we propose a complex-amplitude constraint Gerchberg–Saxton algorithm for designing a collimated flat-top beam shaper metasurface doublet, which avoids the influence of strong near-field coupling on the amplitude distribution and simultaneously considers the amplitude-phase characteristics of the meta-atoms. A collimated flat-top beam with exceptional homogeneity U p of approximately 0.01, a wavefront error less than 0.1λ, and a transmittance higher than 86 % is experimentally obtained, comparable to commercial products based on freeform lenses. A collimated flat-top beam shaper metasurface doublet for generating flat-top beam is introduced, promoting efficient integration with laser systems.
TL;DR: Enhanced inverse Faraday effect and time-dependent thermo-transmission in gold nanodisks demonstrate large IFE signals due to dipolar plasmonic resonance and spectral resemblance with thermo-transmission signals.
Abstract:
Nonmagnetic media can be magnetized by light via processes referred to as an inverse Faraday effect (IFE). With nonmagnetic metal nanostructures, the IFE is dominated by the presence of light-induced solenoidal surface currents or plasmons with orbital angular momenta, whose properties depend on both the light and nanostructure geometry. Here, through a systematic study of gold nanodisks with different sizes, we demonstrate order-of-magnitude enhancement of the IFE compared to a bare gold film. Large IFE signals occur when light excites the dipolar plasmonic resonance of the gold nanodisk. We observe that the spectral response of the IFE signal mirrors the spectral response of time-dependent thermo-transmission signals. Our careful quantitative experimental measurements and analysis offer insight into the magnitude of IFE in plasmonic structures for compact, low-power, magneto-optic applications.
TL;DR: Photoelectric tunable-step terahertz detectors based on a dipole antenna demonstrate high-speed detection of terahertz radiation with a strong photoresponse. The optimal antenna parameters and speed performance are investigated.
Abstract:
Field effect transistors have shown promising performance as terahertz (THz) detectors over the past few decades. Recently, a quantum phenomenon, the in-plane photoelectric effect, was discovered as a novel detection mechanism in gated two-dimensional electron gases (2DEGs), and devices based on this effect, photoelectric tunable-step (PETS) THz detectors, have been proposed as sensitive THz detectors. Here, we demonstrate a PETS THz detector based on GaAs/AlGaAs heterojunction using a dipole antenna. We investigate the dependence of the in-plane photoelectric effect on parameters including the dimensions and the operating temperature of the device. Two figures of merit within the 2DEG, the maximum electric field and the radiation-induced ac-potential difference, are simulated to determine the optimal design of the PETS detector antenna. We identify the optimal antenna gap size, metal thickness, and 2DEG depth, and demonstrate the first PETS detector with a symmetric dipole antenna, which shows high-speed detection of 1.9 THz radiation with a strong photoresponse. Our findings deepen the understanding of the in-plane photoelectric effect and provide a universal guidance for the design of future PETS THz detectors.
TL;DR: Grating-lobe-free OPA with 2-D circular sparse array aperture and high-efficiency phase calibration achieves low side lobe and high beam resolution.
Abstract: Abstract An optical phased array (OPA) with 2-D circular sparse array aperture has been proposed and demonstrated in the silicon integrated photonic platform. The sparse distribution of the antenna array can realize no grating lobes in 2-D full field of view (FOV). To achieve fast and accurate phase calibration for OPA, an improved rotating element electric field vector algorithm based on golden section search method (GSS-REV) has also been proposed and verified. The 32-element antenna sparse distribution of the proposed OPA is designed and fabricated. A far-field beam steering measurement across 20° × 20° range features the side lobe suppression ratio (SLSR) of larger than 4.81 dB and a full width at half-maximum (FWHM) of approximately 0.63° × 0.59°. The resolvable points are derived to be ∼1076. The OPA chip has also been demonstrated on range measurement with frequency-modulated continuous-wave (FMCW) system.
TL;DR: Programmable, colored thermal camouflage based on In3SbTe2 platform achieves complete decoupled control of visible color and infrared emissivity.
Abstract: Abstract Camouflage is an important technology in various scenarios. Usually, this involves the visible compatibility of the background, which however is facile under infrared thermal radiation detection. The simultaneous visible and thermal camouflage are challenging because it requires full and decoupled manipulations of visible reflection and infrared emissivity using one single device, let alone to its adaptivity to complex environments. Here, we report a programmable, colored thermal camouflage at 3–5 μm and 8–14 μm based on mode coupling in phase-change In3SbTe2 materials. A series of industry-friendly colored multilayer thermal emitters are designed consisting of an anti-reflectance layer for structure coloration above a coupled nanocavity for IR modulation, which easily realizes the complete decoupled control of visible color and infrared emissivity. Our solution features independent structural visible colors in the full visible range and continuously programmable dual-band emissivity modulation with up to 90 % absolute tuning range. Our work facilitates near optimal camouflage and anti-counterfeiting solution for visible-infrared multi-band compatibility of complex environments under different temperatures and colored appearances.
TL;DR: Plasmonic-based electrochromic materials and devices review highlights the importance of plasmonic materials in achieving stable and color-tunable electrochromism.
Abstract: Abstract The development of electrochromic (EC) materials has paved the way for a wide range of devices, such as smart windows, color displays, optical filters, wearable camouflages, among others. However, the advancement of electrochromism faces a significant hurdle due to its poor stability and limited color options. This lack of stability is primarily attributed to the substantial alteration in the dielectric properties of EC materials during cycling. Consequently, the design of advanced plasmonic materials is a key strategy to achieve a stable EC device. In this review, we provide an overview of the current state-of-the-art designs of plasmonic-based EC materials and devices. We discuss their working principles, techniques for structure/morphology engineering, doping methods, and crystal phase design. Furthermore, we explore the integration of plasmonic materials with other EC materials to create advanced EC devices. Finally, we outline the challenges that need to be addressed and present an outlook on the development of high-performance EC devices.
TL;DR: High-resolution non-line-of-sight imaging based on liquid crystal planar optical elements successfully designed a large field-of-view high-resolution system for a wide scanning area and high-quality image reconstruction. The system utilizes liquid crystal planar optical elements for high efficiency, lightweight, low cost, and ease of processing.
Abstract: Abstract Non-line-of-sight (NLOS) imaging aims at recovering hidden objects located beyond the traditional line of sight, with potential applications in areas such as security monitoring, search and rescue, and autonomous driving. Conventionally, NLOS imaging requires raster scanning of laser pulses and collecting the reflected photons from a relay wall. High-time-resolution detectors obtain the flight time of photons undergoing multiple scattering for image reconstruction. Expanding the scanning area while maintaining the sampling rate is an effective method to enhance the resolution of NLOS imaging, where an angle magnification system is commonly adopted. Compared to traditional optical components, planar optical elements such as liquid crystal, offer the advantages of high efficiency, lightweight, low cost, and ease of processing. By introducing liquid crystal with angle magnification capabilities into the NLOS imaging system, we successfully designed a large field-of-view high-resolution system for a wide scanning area and high-quality image reconstruction. Furthermore, in order to reduce the long data acquisition time, a sparse scanning method capitalizing on the correlation between measurement data to reduce the number of sampling points is thus proposed. Both the simulation and experiment results demonstrate a >20 % reduction in data acquisition time while maintaining the exact resolution.
TL;DR: Spintronic terahertz emitters with integrated metallic terahertz cavities enhance THz emission and control polarization state.
Abstract: Abstract Spintronic terahertz emitters (STEs), based on optical excitation of nanometer thick ferromagnetic/heavy metal (FM/HM) heterojunctions, have become important sources for the generation of terahertz (THz) pulses. However, the efficiency of the optical-to-THz conversion remains limited. Although optical techniques have been developed to enhance the optical absorption, no investigations have studied the application of THz cavities. Here, to enhance the THz efficiency of STEs in a selected THz spectral range, FM/HM structures are realized on ultra-thin sapphire layers with metallic mirrors to create λ/4 THz resonant cavities. THz emission time domain spectroscopy of these STE/sapphire/mirror heterostructures, with sapphire thicknesses ranging from 110 µm to 25 µm, shows enhancement of the emitted THz field that fits the λ/4 cavity resonance with up to a doubling of the field in the spectrum, and in agreement with temporal simulations of the emitted THz pulse. By taking advantage of birefringent materials, we further show the potential of control of the polarization state of the emitted THz pulse. This work shows the potential of enhancing and engineering THz emission from STEs using THz cavities that can be controlled over a broad spectral range, which can be easily combined with optical cavities.
TL;DR: High-Q second-harmonic generation of quasi-bound states in lithium niobate thin film enhanced by Bloch surface waves in a composite grating waveguide structure.
Abstract:
Nonlinear optics has generated a wide range of applications in the fields of optical communications, biomedicine, and materials science, with nonlinear conversion efficiency serving as a vital metric for its progress. However, the weak nonlinear response of materials, high optical loss, and inhomogeneous distribution of the light field hamper the improvement of the conversion efficiency. We present a composite grating waveguide structure integrated into a Bragg reflector platform. This design achieves high Q in the spectral range by exploiting the unique properties exhibited by the bound states in the Bloch surface wave-enhanced continuum, and efficient second-harmonic generation by close-field amplification with the optical field tightly localized in a nonlinear material. By manipulating the symmetry of the grating, a precise tune over the near field within a designated wavelength range can be achieved. Specifically, we select a photonic crystal configuration supporting surface waves, employing TE polarization conditions and an asymmetry factor of −0.1 between the composite gratings. This configuration resonates at a fundamental wavelength of 783.5 nm, exhibiting an impressive Q-factor of 106. Notably, at an incident light intensity of 1.33 GW/cm2, we achieve a normalized electric field strength of up to 940 at the fundamental frequency and a second-harmonic conversion efficiency of up to 6 × 10−3, significantly amplifying the second-harmonic response. The proposed configuration in this investigation has the potential to be integrated into the field of nonlinear optics for sensing frequency conversion applications.
TL;DR: A method to extract the excess electron temperature in terahertz quantum cascade lasers from laser characteristics is proposed and validated. This method is simple and can be easily implemented, allowing for the achievement of high temperature performance in terahertz quantum cascade lasers.
Abstract: Abstract We propose a method to extract the upper laser level’s (ULL’s) excess electronic temperature from the analysis of the maximum light output power (Pmax) and current dynamic range ΔJd = (Jmax − Jth) of terahertz quantum cascade lasers (THz QCLs). We validated this method, both through simulation and experiment, by applying it on THz QCLs supporting a clean three-level system. Detailed knowledge of electronic excess temperatures is of utmost importance in order to achieve high temperature performance of THz QCLs. Our method is simple and can be easily implemented, meaning an extraction of the excess electron temperature can be achieved without intensive experimental effort. This knowledge should pave the way toward improvement of the temperature performance of THz QCLs beyond the state-of-the-art.
TL;DR: Observation of tunable accidental bound state in the continuum in silicon nanodisk array TLDR: The A-BIC can be tuned by varying the nanodisk size or the lattice period, and the angular position can be tuned even to 0°.
Abstract:
We experimentally demonstrate the tuning of accidental bound states in the continuum (A-BICs) in silicon nanodisk arrays. The A-BIC emerges of the destructive interference of multipoles, which are the dominating out-of-plane electric dipole and in-plane magnetic dipole, and weak electric quadrupole and magnetic quadrupole. We further show that the spectral and angular position of the A-BIC can be conveniently tuned by varying the nanodisk size or the lattice period. Remarkably, the angular position can be tuned even to 0°, suggesting an interesting transition of the A-BIC from an off-Γ-BIC to an at-Γ-BIC. Our work provides a new strategy for light trapping with high quality factors, and the obtained tunable A-BICs can find potential applications in low-threshold lasing, enhanced nonlinear optics, and optical sensing.
TL;DR: Modeling with graded interfaces accurately reproduces the electro-optical characteristics of record-high power and efficiency mid-infrared quantum cascade lasers. The model is employed to design an 8.1 µm-emitting QCL with suppressed carrier leakage, reaching a maximum front-facet wall-plug efficiency value of 22.2%.
Abstract: Abstract By employing a graded-interfaces model based on a generalized formalism for interface-roughness (IFR) scattering that was modified for mid-infrared emitting quantum cascade lasers (QCLs), we have accurately reproduced the electro-optical characteristics of published record-performance 4.9 µm- and 8.3 µm-emitting QCLs. The IFR-scattering parameters at various interfaces were obtained from measured values and trends found via atom-probe tomography analysis of one of our 4.6 μm-emitting QCL structures with variable barrier heights. Those values and trends, when used for designing a graded-interface, 4.6 μm-emitting QCL, led to experimental device characteristics in very good agreement with calculated ones. We find that the published record-high performance values are mainly due to both injection from a prior-stage low-energy (active-region) state directly into the upper-laser (ul) level, thus at low field-strength values, as well as to strong photon-induced carrier transport. However, the normalized leakage-current density J leak /J is found to be quite high: 26–28 % and 23.3 %, respectively, mainly because of IFR-triggered shunt-type leakage through high-energy active-region states, in the presence of high average electron temperatures in the ul laser level and an energy state adjacent to it: 1060 K and 466 K for 4.9 µm- and 8.3 µm-emitting QCLs, respectively. Then, modeling with graded interfaces becomes a tool for designing devices of performances superior to the best reported to date, thus closing in on fundamental limits. The model is employed to design a graded-interface 8.1 µm-emitting QCL with suppressed carrier leakage via conduction-band engineering, which reaches a maximum front-facet wall-plug efficiency value of 22.2 %, significantly higher than the current record (17 %); thus, a value close to the fundamental front-facet, upper limit (i.e., 25 %) for ∼8 µm-emitting QCLs.