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  4. 2014
Showing papers in "Chemical Communications in 2014"
Journal Article•10.1039/C4CC00751D•
Synthetic applications of eosin Y in photoredox catalysis

[...]

Durga Prasad Hari1, Burkhard König1•
University of Regensburg1
30 May 2014-Chemical Communications
TL;DR: The key photophysical properties of the dye are summarized and the recent synthetic applications in photoredox catalysis are summarized.

909 citations

Journal Article•10.1039/C4CC01625D•
Three-dimensional NiFe layered double hydroxide film for high-efficiency oxygen evolution reaction.

[...]

Zhiyi Lu1, Wenwen Xu1, Wei Zhu1, Qiu Yang1, Xiaodong Lei1, Junfeng Liu1, Yaping Li1, Xiaoming Sun1, Xue Duan1 •
Beijing University of Chemical Technology1
22 May 2014-Chemical Communications
TL;DR: It is demonstrated that a three-dimensional architecture of NiFe layered double hydroxide (NiFe-LDH) significantly reduced the onset potential, yielded high current density at small overpotentials, and showed outstanding stability in electrochemical oxygen evolution reaction.

837 citations

Journal Article•10.1039/C4CC05752J•
Production of few-layer phosphorene by liquid exfoliation of black phosphorus

[...]

Jack R. Brent1, Nicky Savjani1, Edward A. Lewis1, Sarah J. Haigh1, David J. Lewis1, Paul O'Brien1 •
University of Manchester1
07 Oct 2014-Chemical Communications
TL;DR: The liquid exfoliation of black phosphorus in N-methyl-2-pyrrolidone to form few-layer phosphorene nanosheets is reported.

771 citations

Journal Article•10.1039/C4CC01646G•
One-step synthesis of nanocrystalline transition metal oxides on thin sheets of disordered graphitic carbon by oxidation of MXenes.

[...]

Michael Naguib1, Olha Mashtalir1, Maria R. Lukatskaya1, Boris Dyatkin1, Chuanfang (John) Zhang1, Volker Presser2, Yury Gogotsi1, Michel W. Barsoum1 •
Drexel University1, Saarland University2
17 Jun 2014-Chemical Communications
TL;DR: It is shown that heating 2D Ti3C2 in air results in TiO2 nanocrystals enmeshed in thin sheets of disordered graphitic carbon structures that can handle extremely high cycling rates when tested as anodes in lithium ion batteries.

724 citations

Journal Article•10.1039/C4CC02553A•
Two-dimensional layered composite photocatalysts.

[...]

Jingxiang Low1, Shaowen Cao1, Jiaguo Yu2, Jiaguo Yu1, Swelm Wageh2 •
Wuhan University of Technology1, King Abdulaziz University2
19 Aug 2014-Chemical Communications
TL;DR: This feature article summarizes the recent developments of 2D layered composite photocatalysts for photoc atalytic applications, such as photocatallytic hydrogen production, bacterial disinfection, and pollutant degradation.

604 citations

Journal Article•10.1039/C4CC03366C•
Synthesis and characterization of two-dimensional Nb4C3 (MXene)

[...]

Michael Ghidiu1, Michael Naguib1, Chenyang Shi2, Olha Mashtalir1, L. M. Pan3, B. Zhang3, Jian Yang1, Jian Yang3, Yury Gogotsi1, Simon J. L. Billinge2, Simon J. L. Billinge4, Michael Barsoum1 •
Drexel University1, Columbia University2, Nanjing Tech University3, Brookhaven National Laboratory4
24 Jul 2014-Chemical Communications
TL;DR: The structure of this, only second MXene with formula M4X3, was investigated with pair distribution function analysis, and the resistivity of a cold-pressed disc was 0.0046 Ω m, rendering this MXene one of the most conductive to date.

572 citations

Journal Article•10.1039/C4CC03109A•
Nanostructured electrochromic smart windows: traditional materials and NIR-selective plasmonic nanocrystals

[...]

Evan L. Runnerstrom1, Anna Llordes1, Sebastien D. Lounis2, Sebastien D. Lounis1, Delia J. Milliron3, Delia J. Milliron1 •
Lawrence Berkeley National Laboratory1, University of California, Berkeley2, University of Texas at Austin3
14 Aug 2014-Chemical Communications
TL;DR: In an effort to demonstrate a new type of electro Chromic device that goes beyond the capabilities of commonly used electrochromic materials, researchers have turned to plasmonic transparent conductive oxide (TCO) nanocrystals.

504 citations

Journal Article•10.1039/C4CC02021A•
Ionic liquids for energy, materials, and medicine.

[...]

Marcin Smiglak1, Jennifer M. Pringle2, Xingmei Lu3, Lijun Han3, Suojiang Zhang3, Hongshuai Gao3, Douglas R. MacFarlane4, Robin D. Rogers5 •
Adam Mickiewicz University in Poznań1, Deakin University2, Chinese Academy of Sciences3, Monash University, Clayton campus4, University of Alabama5
22 Jul 2014-Chemical Communications
TL;DR: Current research trends in applications of ionic liquids to energy, materials, and medicines are discussed to provide some insight into the directions, motivations, challenges, and successes being achieved with ionic liquid research today.

478 citations

Journal Article•10.1039/C4CC00146J•
Nitrogen-doped carbon nanotubes and graphene composite structures for energy and catalytic applications

[...]

Won Jun Lee1, Uday Narayan Maiti1, Ju Min Lee1, Joonwon Lim1, Tae Hee Han2, Sang Ouk Kim1 •
KAIST1, Hanyang University2
03 Jun 2014-Chemical Communications
TL;DR: This invited feature article reviews the current research progress, emerging trends, and opening opportunities in N-doped carbon based composite structures.

465 citations

Journal Article•10.1039/C4CC06147K•
Limonene: a versatile chemical of the bioeconomy

[...]

Rosaria Ciriminna, Mónica Lomelí-Rodríguez1, Piera Demma Carà1, Jose Antonio Lopez-Sanchez1, Mario Pagliaro •
University of Liverpool1
11 Nov 2014-Chemical Communications
TL;DR: The expansion in uses for limonene will translate into increasing production and use of this relevant natural product, especially for advanced applications, according to this report.

452 citations

Journal Article•10.1039/C3CC49440C•
A p-type Ti(IV)-based metal–organic framework with visible-light photo-response

[...]

Junkuo Gao1, Jianwei Miao1, Pei-Zhou Li1, Wen Yuan Teng1, Ling Yang1, Yanli Zhao1, Bin Liu1, Qichun Zhang1 •
Nanyang Technological University1
13 Mar 2014-Chemical Communications
TL;DR: In this article, a new Ti(IV)-based porous metal-organic framework (MOF) (NTU-9), which displayed strong absorption in the visible region with a bandgap of 1.72 eV, was reported.
Journal Article•10.1039/C3CC47896C•
Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries

[...]

Robert Ellis Doe, Ruoban Han, Jaehee Hwang, Andrew J. Gmitter, Ivgeni Shterenberg1, Hyun Deog Yoo1, Nir Pour1, Doron Aurbach1 •
Bar-Ilan University1
07 Jan 2014-Chemical Communications
TL;DR: The first inorganic magnesium salt solution capable of highly reversible magnesium electrodeposition is presented, Synthesized by acid-base reaction of MgCl2 and Lewis acidic compounds such as AlCl3.
Journal Article•10.1039/C3CC47512C•
Engineering ultrasmall water-soluble gold and silver nanoclusters for biomedical applications

[...]

Zhentao Luo1, Kaiyuan Zheng1, Jianping Xie1•
National University of Singapore1
22 Apr 2014-Chemical Communications
TL;DR: It is believed that with continued efforts to understand the interactions of biomolecule-protected Au/ Ag NCs with the biological systems, scientists can largely realize the great potential of Au/Ag NCs for biomedical applications, which could finally pave their way towards clinical use.
Journal Article•10.1039/C4CC03312D•
Fluorescent probes for hydrogen sulfide detection and bioimaging

[...]

Fabiao Yu1, Xiaoyue Han1, Lingxin Chen1•
Chinese Academy of Sciences1
18 Sep 2014-Chemical Communications
TL;DR: This feature article addresses the synthesis and design strategies for the development of fluorescent probes for H2S based on the reaction type between H2 S and the probes, and highlights fluorescent probe for other reactive sulfur species, such as sulfane sulfurs and SO2 derivatives.
Journal Article•10.1039/C4CC02543A•
g-C3N4 quantum dots: direct synthesis, upconversion properties and photocatalytic application

[...]

Wanjun Wang1, Jimmy C. Yu1, Zhurui Shen1, Donald K.L. Chan1, Ting Gu1 •
The Chinese University of Hong Kong1
05 Aug 2014-Chemical Communications
TL;DR: The graphitic carbon nitride quantum dots show strong blue emission as well as upconversion behavior, which can be used as universal energy-transfer components in visible-light-driven metal-free photocatalytic systems.
Journal Article•10.1039/C4CC03170A•
Pillararene-based supramolecular polymers: from molecular recognition to polymeric aggregates

[...]

Chunju Li1•
Shanghai University1
23 Sep 2014-Chemical Communications
TL;DR: An overview of the construction of pillararene-based supramolecular polymers is provided and recent research endeavors of the marriage between pillararenes-based host-guest pairs and polymeric aggregates are covered.
Journal Article•10.1039/C4CC01086H•
A dye-sensitized Pt@UiO-66(Zr) metal–organic framework for visible-light photocatalytic hydrogen production

[...]

Jiao He1, Jiaqiang Wang1, Yongjuan Chen1, Jinping Zhang1, Deliang Duan1, Yao Wang1, Zhiying Yan1 •
Yunnan University1
03 Jun 2014-Chemical Communications
TL;DR: A stable photoactive metal-organic framework UiO-66(Zr) sensitized by adsorbed or directly added rhodamine B dye exhibited photocatalytic activity for hydrogen evolution under visible-light illumination using Pt as a co-catalyst.
Journal Article•10.1039/C4CC04133J•
Dihydrolevoglucosenone (Cyrene) as a bio-based alternative for dipolar aprotic solvents.

[...]

James Sherwood1, Mario De bruyn1, Andri Constantinou1, Laurianne Moity1, C. Robert McElroy1, Thomas J. Farmer1, Tony Duncan, Warwick Raverty, Andrew J. Hunt1, James H. Clark1 •
University of York1
29 Jul 2014-Chemical Communications
TL;DR: Dihydrolevoglucosenone demonstrates similar performance to NMP in a fluorination reaction and the Menschutkin reaction, which demonstrates significant promise as a dipolar aprotic solvent.
Journal Article•10.1039/C4CC05665E•
A 2D azine-linked covalent organic framework for gas storage applications

[...]

Zhongping Li1, Xiao Feng2, Yongcun Zou1, Yuwei Zhang1, Hong Xia1, Xiaoming Liu1, Ying Mu1 •
Jilin University1, Beijing Institute of Technology2
14 Oct 2014-Chemical Communications
TL;DR: A new azine-linked covalent organic framework, ACOF-1, was synthesized by condensation of hydrazine hydrate and 1,3,5-triformylbenzene under solvothermal conditions, with high selectivity towards CO2 over N2 and CH4.
Journal Article•10.1039/C3CC49856E•
P2-type Na2/3Ni1/3Mn2/3−xTixO2 as a new positive electrode for higher energy Na-ion batteries

[...]

Hiroaki Yoshida1, Naoaki Yabuuchi1, Kei Kubota1, Issei Ikeuchi1, Arnd Garsuch, Martin Schulz-Dobrick, Shinichi Komaba1 •
Tokyo University of Science1
11 Mar 2014-Chemical Communications
TL;DR: New electrode materials of layered oxides, Na2/3Ni1/3Mn2/ 3-xTixO2 (0 ≤ x ≤ 2/3), are successfully synthesized, and their electrochemical performance is examined in aprotic Na cells.
Journal Article•10.1039/C4CC01429D•
Smart drug delivery systems: from fundamentals to the clinic.

[...]

Carmen Alvarez-Lorenzo1, Angel Concheiro1•
University of Santiago de Compostela1
24 Jun 2014-Chemical Communications
TL;DR: A critical overview of therapeutically-interesting stimuli to trigger drug release and the evolution of responsive materials suitable as functional excipients is offered, illustrated with recent examples of formulations in clinical trials or already commercially available, which can provide a perspective on the current state of the art on smart drug delivery systems.
Journal Article•10.1039/C4CC05535G•
A lithium anode protection guided highly-stable lithium-sulfur battery

[...]

Guoqiang Ma1, Zhaoyin Wen1, Meifen Wu1, Chen Shen1, Qingsong Wang1, Jun Jin1, Xiangwei Wu1 •
Chinese Academy of Sciences1
21 Oct 2014-Chemical Communications
TL;DR: A Li3N protection layer is fabricated on the surface of a Li anode by an in situ method to suppress the shuttle effect on the basis of anode protection to retain the discharge capacity.
Journal Article•10.1039/C3CC49196J•
Carbon monoxide – physiology, detection and controlled release

[...]

Stefan H. Heinemann1, Toshinori Hoshi2, Matthias Westerhausen1, Alexander Schiller1•
University of Jena1, University of Pennsylvania2
11 Mar 2014-Chemical Communications
TL;DR: Recent progress in identifying new effector systems and elucidating the mechanisms of action of CO on ion channels is discussed, as well as the design of novel methods to monitor CO in cellular environments.
Journal Article•10.1039/C3CC48398C•
Water-stable metal–organic frameworks with intrinsic peroxidase-like catalytic activity as a colorimetric biosensing platform

[...]

Jian-Wei Zhang1, Hao-Tian Zhang1, Zi-Yi Du, Xueqing Wang1, Xueqing Wang2, Shu-Hong Yu1, Hai-Long Jiang1 •
University of Science and Technology of China1, University of British Columbia2
04 Feb 2014-Chemical Communications
TL;DR: Two iron(III)-based metal-organic frameworks are found to behave as efficient peroxidase mimics and catalyze the oxidation of different peroxIDase substrates by H2O2 accompanied with significant color change in the solution.
Journal Article•10.1039/C4CC02192D•
An achievement of over 12 percent efficiency in an organic dye-sensitized solar cell

[...]

Kenji Kakiage1, Yohei Aoyama, Toru Yano, Takahiro Otsuka, Toru Kyomen1, Masafumi Unno1, Minoru Hanaya1 •
Gunma University1
20 May 2014-Chemical Communications
TL;DR: Dye-sensitized solar cells fabricated by using a novel metal-free alkoxysilyl carbazole as a sensitizing dye and a Co(3+/2+)-complex redox electrolyte exhibited light-to-electric energy conversion efficiencies of over 12% with open-circuit photovoltages higher than 1 V by applying a hierarchical multi-capping treatment to the photoanode.
Journal Article•10.1039/C3CC47081D•
Aerobic oxidation catalysis with stable radicals

[...]

Qun Cao1, Laura M. Dornan1, Luke Rogan1, N. Louise Hughes1, Mark J. Muldoon1 •
Queen's University Belfast1
04 Apr 2014-Chemical Communications
TL;DR: This review will discuss the use of stable radicals (primarily nitroxyl radicals) in aerobic oxidation catalysis, highlighting the catalytic performance, mechanistic insights and the expanding synthetic utility of these catalytic systems.
Journal Article•10.1039/C4CC02401J•
Are Zr6-based MOFs water stable? Linker hydrolysis vs. capillary-force-driven channel collapse

[...]

Joseph E. Mondloch1, Michael J. Katz1, Nora Planas2, David Semrouni2, Laura Gagliardi2, Joseph T. Hupp1, Omar K. Farha3, Omar K. Farha1 •
Northwestern University1, University of Minnesota2, King Abdulaziz University3
15 Jul 2014-Chemical Communications
TL;DR: It is demonstrated that two Zr6-based frameworks, namely UiO-67 and NU-1000, are stable towards linker hydrolysis in H2O, but collapse during activation from H2 O, and can be overcome by utilizing solvent-exchange to solvents exhibiting lower capillary forces such as acetone.
Journal Article•10.1039/C3CC49176E•
Highly stable covalent organic framework–Au nanoparticles hybrids for enhanced activity for nitrophenol reduction

[...]

Pradip Pachfule1, Sharath Kandambeth1, David Díaz Díaz2, David Díaz Díaz3, Rahul Banerjee1 •
National Chemical Laboratory1, University of Regensburg2, Spanish National Research Council3
25 Feb 2014-Chemical Communications
TL;DR: Gold [Au(0)] nanoparticles immobilized into a stable covalent organic framework (COF) have been synthesized via the solution infiltration method and shows high recyclability and superior reactivity for nitrophenol reduction reaction than HAuCl4·3H2O.
Journal Article•10.1039/C4CC04381B•
Recent advances in the catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides

[...]

Javier Adrio1, Juan C. Carretero1•
Autonomous University of Madrid1
23 Sep 2014-Chemical Communications
TL;DR: This review will discuss important advances that have been reported in catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides since 2011 and investigates their application to enantioenriched pyrrolidines.
Journal Article•10.1039/C4CC00848K•
Lanthanide based tuning of luminescence in MOFs and dense frameworks--from mono- and multimetal systems to sensors and films.

[...]

Larissa V. Meyer1, Fabian Schönfeld1, Klaus Müller-Buschbaum1•
University of Würzburg1
02 Jul 2014-Chemical Communications
TL;DR: This feature article focuses on tuning options of photoluminescence properties of lanthanide containing Metal-Organic Frameworks (MOFs) and Dense Frameworks by selection of an appropriate set of metal ions together with suitable ligands.
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