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  4. 2012
Showing papers in "Chemical Communications in 2012"
Journal Article•10.1039/C2CC00110A•
Graphene quantum dots: emergent nanolights for bioimaging, sensors, catalysis and photovoltaic devices

[...]

Jianhua Shen1, Yihua Zhu1, Xiaoling Yang1, Chunzhong Li1•
East China University of Science and Technology1
19 Mar 2012-Chemical Communications
TL;DR: Recent developments in preparation of GQDs are discussed, focusing on the main two approaches (top-down and bottom-down).

1,984 citations

Journal Article•10.1039/C2CC33796G•
Simple one-step synthesis of highly luminescent carbon dots from orange juice: application as excellent bio-imaging agents

[...]

Swagatika Sahu1, Birendra Behera2, Tapas K. Maiti2, Sasmita Mohapatra1•
National Institute of Technology, Rourkela1, Indian Institute of Technology Kharagpur2
06 Aug 2012-Chemical Communications
TL;DR: Highly photoluminescent carbon dots with a PL quantum yield of 26% have been prepared in one step by hydrothermal treatment of orange juice and demonstrated as excellent probes in cellular imaging.

1,451 citations

Journal Article•10.1039/C2CC31777J•
Prussian blue: a new framework of electrode materials for sodium batteries

[...]

Yuhao Lu1, Long Wang1, Jinguang Cheng1, John B. Goodenough1•
University of Texas at Austin1
06 Jun 2012-Chemical Communications
TL;DR: The data indicate that a Na-ion battery with a Prussian blue framework as a cathode will be feasible.

1,074 citations

Journal Article•10.1039/C2CC35862J•
A facile approach to synthesize novel oxygen-doped g-C3N4 with superior visible-light photoreactivity

[...]

Jianghua Li1, Biao Shen1, Zhenhua Hong1, Bizhou Lin1, Bifen Gao1, Yilin Chen1 •
Huaqiao University1
14 Nov 2012-Chemical Communications
TL;DR: The O-doping in the g-C(3)N(4) lattice could induce intrinsic electronic and band structure modulation, resulting in its absorbance edge up to 498 nm and enhanced visible-light photoactivity, consequently.

1,034 citations

Journal Article•10.1039/C1CC15678K•
One-step synthesis of amino-functionalized fluorescent carbon nanoparticles by hydrothermal carbonization of chitosan

[...]

Yunhua Yang1, Jianghu Cui1, Mingtao Zheng2, Chaofan Hu1, Shaozao Tan1, Yong Xiao1, Qu Yang1, Yingliang Liu1 •
Jinan University1, South China Agricultural University2
11 Jan 2012-Chemical Communications
TL;DR: Highly amino-functionalized fluorescent carbon nanoparticles were fabricated by hydrothermal carbonization of chitosan at a mild temperature and showed low cytotoxicity and excellent biocompatibility in human lung adenocarcinoma A549 cells.

975 citations

Journal Article•10.1039/C1CC14764A•
Enhancing the performances of Li-ion batteries by carbon-coating: present and future

[...]

Huiqiao Li1, Haoshen Zhou1•
National Institute of Advanced Industrial Science and Technology1
09 Jan 2012-Chemical Communications
TL;DR: The recent development of carbon coating techniques in lithium-ion batteries is discussed with detailed examples of typical cathode and anode materials and the limitation of current technology and future perspective of the new concept of "hybrid coating" are pointed out.

938 citations

Journal Article•10.1039/C2CC33869F•
Highly luminescent carbon nanodots by microwave-assisted pyrolysis

[...]

Xinyun Zhai1, Peng Zhang2, Peng Zhang1, Chang-jun Liu1, Chang-jun Liu3, Tao Bai1, Wenchen Li1, Liming Dai2, Wenguang Liu1 •
Tianjin University1, Case Western Reserve University2, Academy of Military Medical Sciences3
16 Jul 2012-Chemical Communications
TL;DR: Carbon nanodots with a low cytotoxicity have been synthesized by one-step microwave-assisted pyrolysis of citric acid in the presence of various amine molecules, confirmed to serve dual roles as N-doping precursors and surface passivation agents.

915 citations

Journal Article•10.1039/C2CC33945E•
A new approach to improve cycle performance of rechargeable lithium–sulfur batteries by inserting a free-standing MWCNT interlayer

[...]

Su Yu-Sheng1, Arumugam Manthiram1•
University of Texas at Austin1
06 Aug 2012-Chemical Communications
TL;DR: A conductive multiwalled carbon nanotube (MWCNT) interlayer acting as a pseudo-upper current collector not only reduces the charge transfer resistance of sulfur cathodes significantly, but also localizes and retains the dissolved active material during cycling.

762 citations

Journal Article•10.1039/C2CC32181E•
Carbon self-doping induced high electronic conductivity and photoreactivity of g-C3N4

[...]

Guohui Dong1, Kun Zhao1, Lizhi Zhang1•
Central China Normal University1
23 May 2012-Chemical Communications
TL;DR: It is theoretically and experimentally demonstrated that carbon self-doping could induce intrinsic electronic and band structure change of g-C(3)N(4)via the formation of delocalized big π bonds to increase visible light absorption and electrical conductivity as well as surface area and thus enhance both photooxidation and photoreduction activities.

741 citations

Journal Article•10.1039/C2CC17013B•
Intrinsic peroxidase-like activity and catalase-like activity of Co3O4 nanoparticles

[...]

Jianshuai Mu1, Yan Wang1, Min Zhao2, Li Zhang1•
Harbin Institute of Technology1, Northeast Forestry University2
06 Feb 2012-Chemical Communications
TL;DR: It is demonstrated that Co(3)O(4) nanoparticles (NPs) exhibit intrinsic peroxidase- like activity and catalase-like activity and their ability of electron transfer between reducing substrates and H(2]O(2), not from ˙OH radical generated.

731 citations

Journal Article•10.1039/C2CC33844K•
Bifunctional fluorescent carbon nanodots: green synthesis via soy milk and application as metal-free electrocatalysts for oxygen reduction.

[...]

Chengzhou Zhu1, Junfeng Zhai1, Shaojun Dong1•
Chinese Academy of Sciences1
22 Aug 2012-Chemical Communications
TL;DR: It is demonstrated a facile and green approach to synthesize bifunctional fluorescent carbon nanodots via soy milk, which not only showed favorable photoluminescent properties, but also exhibited good electrocatalytic activity towards oxygen reduction reaction.
Journal Article•10.1039/C2CC16791C•
Carbon nanodots as fluorescence probes for rapid, sensitive, and label-free detection of Hg2+ and biothiols in complex matrices

[...]

Li Zhou1, Youhui Lin1, Zhenzhen Huang1, Jinsong Ren1, Xiaogang Qu1 •
Chinese Academy of Sciences1
04 Jan 2012-Chemical Communications
TL;DR: In this work, unmodified carbon nanodots are demonstrated as novel and environmentally-friendly fluorescence probes for the sensing of Hg(2+) and biothiols with high sensitivity and selectivity.
Journal Article•10.1039/C2CC33433J•
Nanoporous carbons through direct carbonization of a zeolitic imidazolate framework for supercapacitor electrodes

[...]

Watcharop Chaikittisilp1, Ming Hu1, Hongjing Wang2, Hongjing Wang1, Hou-Sheng Huang3, Taketoshi Fujita1, Kevin C.-W. Wu3, Lin-Chi Chen3, Yusuke Yamauchi1, Yusuke Yamauchi2, Yusuke Yamauchi4, Katsuhiko Ariga4, Katsuhiko Ariga1 •
National Institute for Materials Science1, Waseda University2, National Taiwan University3, National Presto Industries4
25 Jun 2012-Chemical Communications
TL;DR: Nanoporous carbons with high surface area are achieved through direct carbonization of a commercially available zeolitic imidazolate framework (ZIF-8) without any additional carbon sources.
Journal Article•10.1039/C2CC32730A•
High capacity Na-storage and superior cyclability of nanocomposite Sb/C anode for Na-ion batteries.

[...]

Jiangfeng Qian1, Yao Chen1, Lin Wu1, Yuliang Cao1, Xinping Ai1, Hanxi Yang1 •
Wuhan University1
18 Jun 2012-Chemical Communications
TL;DR: A Sb/C nanocomposite was synthesized and found to deliver a reversible 3 Na storage capacity of 610 mA h g(-1), a strong rate capability at a very high current and long-term cycling stability with 94% capacity retention over 100 cycles.
Journal Article•10.1039/C2CC36237F•
Efficient green thermally activated delayed fluorescence (TADF) from a phenoxazine–triphenyltriazine (PXZ–TRZ) derivative

[...]

Hiroyuki Tanaka1, Katsuyuki Shizu1, Hiroshi Miyazaki1, Chihaya Adachi1•
Kyushu University1
29 Oct 2012-Chemical Communications
TL;DR: Efficient thermally activated delayed fluorescence (TADF) was developed in a material based on a phenoxazine electron donor unit and a TRZ electron acceptor unit and exhibited a maximum external quantum efficiency of 12.5% with green emission.
Journal Article•10.1039/C2CC17886A•
Diketopyrrolopyrrole (DPP)-based materials for organic photovoltaics

[...]

Sanyin Qu1, He Tian1•
East China University of Science and Technology1
27 Feb 2012-Chemical Communications
TL;DR: The application of DPP-based materials is described, highlighting the applications in optoelectrical fields.
Journal Article•10.1039/C2CC17129E•
High capacity, reversible alloying reactions in SnSb/C nanocomposites for Na-ion battery applications

[...]

Lifen Xiao1, Lifen Xiao2, Yuliang Cao3, Yuliang Cao2, Jie Xiao2, Wei Wang2, Libor Kovarik2, Zimin Nie2, Jun Liu2 •
Central China Normal University1, Pacific Northwest National Laboratory2, Wuhan University3
05 Mar 2012-Chemical Communications
TL;DR: A new SnSb/C nanocomposite based on Na alloying reactions is demonstrated as anode for Na-ion battery applications that can achieve an exceptionally high capacity, good rate capacity and cyclability and good level of capacity retention over 50 cycles.
Journal Article•10.1039/C2CC16434E•
Cost-effective large-scale synthesis of ZnO photocatalyst with excellent performance for dye photodegradation

[...]

Chungui Tian1, Qi Zhang1, Aiping Wu1, Meijia Jiang1, Zhenglan Liang1, Baojiang Jiang1, Honggang Fu1 •
Chinese Ministry of Education1
20 Feb 2012-Chemical Communications
TL;DR: Zinc oxide with excellent photocatalytic performance for the photodegradation of dyes (superior to Degussa P25 TiO(2)) could be easily prepared in large quantity by direct calcination of zinc acetate (Zn(Ac)(2·2H(2)O).
Journal Article•10.1039/C2CC33848C•
Carbon dioxide as a carbon source in organic transformation: carbon–carbon bond forming reactions by transition-metal catalysts

[...]

Yasushi Tsuji1, Tetsuaki Fujihara1•
Kyoto University1
12 Sep 2012-Chemical Communications
TL;DR: Recent carbon-carbon bond forming reactions of carbon dioxide with alkenes, alkynes, dienes, aryl zinc compounds, aRYl boronic esters, aryan halides, and arenes having acidic C-H bonds are reviewed in which transition-metal catalysts play an important role.
Journal Article•10.1039/C2CC35844A•
Superhydrophobic and superoleophilic hybrid foam of graphene and carbon nanotube for selective removal of oils or organic solvents from the surface of water

[...]

Xiaochen Dong1, Jun Chen2, Yanwen Ma2, Jing Wang1, Mary B. Chan-Park1, Xiangmei Liu2, Lianhui Wang2, Wei Huang2, Peng Chen1 •
Nanyang Technological University1, Nanjing University of Posts and Telecommunications2
03 Oct 2012-Chemical Communications
TL;DR: A monolithic 3D hybrid of graphene and carbon nanotube was synthesized by two-step chemical vapor deposition and can selectively remove oils and organic solvents from water with high absorption capacity and good recyclability.
Journal Article•10.1039/C2CC30188A•
Synthesis of high-quality carbon nanodots from hydrophilic compounds: role of functional groups

[...]

Pin-Che Hsu1, Huan-Tsung Chang1•
National Taiwan University1
26 Mar 2012-Chemical Communications
TL;DR: It is found that the compounds incorporating amino and carboxylic acid groups are suitable for the preparation of highly photoluminescent and water-soluble C-dots.
Journal Article•10.1039/C2CC17769B•
Facile access to versatile fluorescent carbon dots toward light-emitting diodes

[...]

Xin Guo1, Cai-Feng Wang1, Ziyi Yu1, Li Chen1, Su Chen1 •
Nanjing Tech University1
13 Feb 2012-Chemical Communications
TL;DR: The facile synthesis of carbon dots with tunable fluorescence from unzipping of photonic crystals and their application in LEDs is reported, which may provide an insight into the creation of multifunctional carbon dots adapted for various applications such as in optoelectronics, sensing, or bioimaging.
Journal Article•10.1039/C1CC15551B•
Self-assembling peptide scaffolds for regenerative medicine

[...]

John B. Matson1, Samuel I. Stupp•
Northwestern University1
04 Jan 2012-Chemical Communications
TL;DR: The future challenges of the field are discussed, including short-term goals such as integration with biopolymers and traditional implants, and long term goals, such as immune system programming, subcellular targeting, and the development of highly integrated scaffold systems.
Journal Article•10.1039/C2CC17061B•
Facile synthesis of silicon nanoparticles inserted into graphene sheets as improved anode materials for lithium-ion batteries

[...]

Xiaosi Zhou1, Ya-Xia Yin1, Li-Jun Wan1, Yu-Guo Guo1•
Chinese Academy of Sciences1
26 Jan 2012-Chemical Communications
TL;DR: The as-obtained Si/graphene nanocomposite exhibits remarkably enhanced cycling performance and rate performance compared with bare Si nanoparticles for lithium-ion batteries.
Journal Article•10.1039/C2CC31468A•
Electroluminescence based on thermally activated delayed fluorescence generated by a spirobifluorene donor–acceptor structure

[...]

Tetsuya Nakagawa1, Sung Yu Ku2, Ken-Tsung Wong2, Chihaya Adachi1•
Kyushu University1, National Taiwan University2
29 Aug 2012-Chemical Communications
TL;DR: An organic light emitting diode based on thermally activated delayed fluorescence (TADF) has been produced using a spirobifluorene derivative (Spiro-CN) having the donor-acceptor moieties as an emitter.
Journal Article•10.1039/C2CC34620F•
Amine-functionalized zirconium metal-organic framework as efficient visible-light photocatalyst for aerobic organic transformations.

[...]

Jinlin Long1, Jinlin Long2, Sibo Wang2, Zhengxin Ding2, Shuchao Wang1, Yangen Zhou2, Ling Huang1, Ling Huang3, Xuxu Wang2 •
Nanyang Technological University1, Fuzhou University2, Nanjing Tech University3
05 Nov 2012-Chemical Communications
TL;DR: An amine-functionalized zirconium metal-organic framework was used as a visible-light photocatalyst for selective aerobic oxygenation of various organic compounds including alcohols, olefins and cyclic alkanes, at high efficiency and high selectivity.
Journal Article•10.1039/C2CC35559K•
Creating high yield water soluble luminescent graphene quantum dots via exfoliating and disintegrating carbon nanotubes and graphite flakes

[...]

Liangxu Lin, Shaowei Zhang
19 Sep 2012-Chemical Communications
TL;DR: An effective method to exfoliate and disintegrate multi-walled carbon nanotubes and graphite flakes with high quantum yield and low oxidization can be developed.
Journal Article•10.1039/C2CC30730H•
Selective turn-on fluorescent probes for imaging hydrogen sulfide in living cells

[...]

Leticia A. Montoya1, Michael D. Pluth1•
University of Oregon1
18 Apr 2012-Chemical Communications
TL;DR: Two bright fluorescent probes are reported that are selective for H( 2)S over cysteine, glutathione and other reactive sulfur, nitrogen, and oxygen species and are demonstrated to detect H(2)S in live cells.
Journal Article•10.1039/C2CC34329K•
Commercial metal–organic frameworks as heterogeneous catalysts

[...]

Amarajothi Dhakshinamoorthy1, Mercedes Alvaro1, Hermenegildo Garcia1•
Spanish National Research Council1
24 Oct 2012-Chemical Communications
TL;DR: Organic transformations for which these commercial MOFs exhibit higher catalytic activity than the corresponding soluble metal salts or metal ion-exchanged zeolites are summarized.
Journal Article•10.1039/C2CC00001F•
Soft-templating synthesis of mesoporous graphitic carbon nitride with enhanced photocatalytic H2 evolution under visible light

[...]

Hongjian Yan1•
Sichuan University1
07 Mar 2012-Chemical Communications
TL;DR: The worm-like porous g-C(3)N(4) not only possesses high BET surface area but also redshifts its absorbance edge up to 800 nm, and shows photocatalytic activity even when the irradiation light λ > 700 nm.
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