Abstract: Lipid residues from two Late Saxon/early medieval ceramic vessels recovered from excavations at West Cotton, Raunds, Northamptonshire, U.K., have been investigated by high-temperature gas chromatography (GC) and GC/mass spectrometry (GC/MS). The solvent extracts of sherds sampled from different points on each vessel (i.e., base, body and rim) were analysed quantitatively and qualitatively and compounds were identified which were characteristic of beeswax and animal fat. Furthermore, by determining the sites of accumulation of the specific lipid types and their concentrations in different parts of the vessels it can be inferred that the beeswax was added to the vessels prior to the addition of the fat. It was concluded that the two vessels performed different functions in antiquity.

Abstract: The question of the nature of social and economic life in the Chalcolithic southern Levant has recently been the subject of increasing interest. Several archaeological sites and features in Israel have been interpreted as elements of religion. These include the shrines at En-Gedi and Gilat and the Nahal Mishmar hoard. The results of petrographic analyses of the pottery assemblages of these three sites, as well as the ceramic cores of copper artefacts from Nahal Mishmar and additional sites, are presented. In light of these results some previous hypotheses are tested. Alternative suggestions are offered as to the role of these sites in the life of the inhabitants of the Chalcolithic southern Levant.

Abstract: Research into the dates of timber used for art-historical objects has provided a large data set on which to test standard dendrochronological techniques. Some 177 sets of tree-ring measurements, originally analysed by the late Dr J. M. Fletcher at Oxford University, have been re-examined independently in the tree-ring laboratories at the University of Sheffield and the Museum of London Archaeology Service. The results show a high level of agreement between the laboratories. In contrast, many of the dates produced by Dr Fletcher for the paintings are not confirmed. The two different approaches described here also resulted in remarkably similar internal groupings of the dated material. These groupings probably reflect the provenance of the timbers and suggest that two different areas of the eastern Baltic supplied the bulk of the material with smaller quantities of panels originating in Britain and central Europe.

Abstract: Archaeologists are increasingly becoming aware of an approach to data investigation known as Bayesian statistics. In this paper we outline both the philosophical and statistical background to the approach. We show that it provides a logical and coherent framework in which to make inferences on the basis of both data and a priori expert knowledge. We note that adoption of the Bayesian framework is particularly timely since there have been recent dramatic developments in numerical methods which mean that a number of previous implementation problems have now been solved. As a result, many questions of archaeological interest, which require the use of complex statistical models, are being investigated using this methodology. We use a variety of recently published examples from a range of archaeological areas to illustrate the type of questions that can be answered and the nature of the methodologies used, and we make comparisons with the results obtained using more traditional statistical techniques.

Abstract: Accelerator mass spectrometry radiocarbon ages have been taken for a test suite of small samples of material removed from some of the ‘beeswax’art figures found in rock shelters in northern Australia. The results indicate that we can reliably date this unique form of rock art with no noticeable damage. We had not expected to find figures of any great antiquity, and so we were surprised to find that the ages obtained spanned the time period from the recent past to about 4000 BP.

Abstract: Although documentary evidence provided by ethnographers makes reference to the source of adhesives, sealants, dyestuffs and medicines used by the communities of the Great Basin, much of it is sporadic and unspecified. However, observations of amorphous deposits surviving on stone tools, ceramics, basketry and wooden artefacts have prompted an investigation of their identity, procurement and use. The aim initially is to study samples from a number of archaeological and ethnographic contexts from the region. Comparative material includes higher plant and insect resins. The study provides a unique opportunity to document use patterns in plant and animal resources in the Great Basin region.

Abstract: Presentation des dates radiocarbone realisees par l'Universite d'Oxford depuis 1993. Elles couvrent le domaine europeen (Paleolithique, Neolithique et plus recent) et quelques sites oceaniens

Abstract: Blue glass trade beads from well-dated late seventeenth- to early twentieth-century sites and collections have been analysed non-destructively by instrumental neutron activation analysis. The beads display enough variations in their elemental contents to allow us to characterize the different chemistries. The implication of these results is that similar chemical analyses of blue beads from undated archaeological sites may be used to help date the sites, since each bead chemistry has a specific earliest period.

Abstract: Presentation de la 19e liste de datations par radiocarbone publiee par Archaeometry, contenant principalement le materiel date depuis le debut de l'annee 1993

Abstract: Late prehistoric pottery is found in abundance at archaeological sites around Southern Indian Lake. Black residues, found on the two dominant vessel forms, flat plates and round pots, are presumed to be the remains of prehistoric meals. 13C cross-polarization magic-angle-spinning nuclear magnetic resonance spectroscopy (CPMAS NMR) and13C and15 N isotopic ratios and C/N ratios are used to reconstruct prehistoric diet and to shed light on possible uses for the plates. Samples of foods were cooked in clay pots, on a wood fire, to simulate the conditions of burning that could have produced the residue. Decomposition of carbohydrates, protein, and fat during cooking is studied with 13C CPMAS NMR, and the effect of cooking on isotopic and C/N ratios documented. Predominantly fish and fat were cooked in the pots, whereas the residues from plates contain a greater proportion of fat and could have been used as frying pans or possibly as fat-burning lamps placed on the ashes of a wood fire.

Abstract: Analyses by inductively coupled plasma atomic emission spectrometry and atomic absorption spectrometry of 22 ceramic standards and sherds are compared. Further data from analyses of one of the ceramic standards analysed by both methods are also discussed. The results show that for most major elements, the methods are comparable, but that use of common standards would be advisable if data from the two methods are to be compared.

Abstract: The possibility of lead isotope fractionation in ancient lead production is examined. Kinetic theory relating to isotopic fractionation in non-equilibrium evaporation is considered and the feasibility of the alteration of lead isotope abundance ratios in ore roasting and smelting is assessed. Previous experimental work is shown to have been inconclusive and conclusions are drawn on the need for further research to quantify the possible extent of fractionation in practice.

Abstract: A statistical re-analysis is undertaken of 118 inductively coupled plasma spectrometry analyses of Romano-British glass specimens found in excavations at Colchester. There are four vessel types present, some of which are associated with chronologically distinct periods. Previous research has suggested little difference in the mean composition of different types. The present paper shows that there are interesting differences in the variation of compositions within types, with some showing much greater compositional stability then others. Some possible models to explain this phenomenon are discussed.

Abstract: Through K/Ar dating of basalt implements from two Mount Carmel late Epipalaeolithic sites and samples of locally occurring basalts, it was possible to demonstrate clearly that the prehistoric inhabitants of these sites did not utilize the locally available Upper Cretaceous (88–77 My) basalts. The dates of the basalt implements are of Tertiary-Quaternary age (3.7-<0.250 My) which suggests the exploitation of basalt exposures at least 60 km east of the sites. This is the first direct evidence for long-distance exchange/trade of an essential raw material in the Levant as early as 13000 BP.

Abstract: Cylinder seals, which were produced more or less continuously for about 3000 years in Western Asia, were worked with designs in intaglio. In this paper we report the results of an investigation into the techniques used to engrave seals composed of quartz. Our observations were made with a binocular microscope and supplemented by examination of impressions with a scanning electron microscope. A range of factors was considered, including shape in plan, topography, surface texture and orientation of features. In this way four basic techniques of engraving have been recognized. They have been tentatively interpreted as micro-chipping, filing, wheel-cutting and drilling.

Abstract: Fifty-six sherds of fine ware from Locri Epizephiri were analysed by inductively coupled plasma optical emission spectroscopy (ICPOES) and flame emission spectroscopy (FES). The sherds had been excavated on the archaeological areas of Marasa Sud, Centocamere and San Cono, and represent local and imported products from the seventh to the second century BC. The samples were dissolved by fusion with lithium metaborate and analysed for nine elements (Al, Fe, Ca, Mg, Ti, Mn, Sr, Ba and Cr) by ICPOES, while Na and K were determined by FES. The analytical data were subjected to hierarchical agglomerative clustering and principal components analysis to classify the sherds into compositional groups. The results obtained indicated that Corinthian, Attic and Ionian products or imitations may be classified in a few separate groups, while most local products are found in a unique, large group.

Abstract: Electron paramagnetic resonance spectroscopy is used to detect paramagnetic impurities in differently degraded antique sheets of unprinted paper. Impurities consist primarily of transition metal ions (Fe3+, Mn2+, Cu2+) present in different environments and symmetries. Organic radicals, common in modern, wood pulp paper, are absent in these antique samples made from rags. Fe3+ is the largest impurity (from 300 to 700 ppm). Mn2+ is also present but its concentration does not exceed 50ppm. Cu2+ has been detected in about one-third of the samples. Coupled with nuclear magnetic resonance data, these results describe degradation as an hydrolytic process leading to a net increase of amorphous cellulose and to a decrease of bound water. Copper and rhombic iron appear to act as efficient degradation catalysts, whereas the presence of octahedral iron is almost irrelevant.

Abstract: Five deposits of Santorini tephra have been found in the excavations currently under way at the site of Mochlos which lies on the north coast of Crete about 140 km to the south of Santorini. This paper provides refractive index and trace element analyses for the largest of these deposits, examines the stratigraphy of all five deposits, and notes the chronological implication of this stratigraphy for the Late Minoan IB period, the floruit of Minoan civilization.

Abstract: The nature of the large red stains exhibited on the Carrara marble elements of the Certosa of Pavia facade was investigated by means of spectroscopic techniques and scanning electron microscopy. Although previous microbiological analysis has demonstrated the presence on the stone of a bacterial strain identified as Micrococcus roseus that is capable of carotenoid production, it has been ascertained in the present study that an inorganic pigment, namely Pb3 O 4 , is responsible for the observed coloration. On small green spots, the presence of photosynthetic microorganisms has been demonstrated by microbiological analysis and confirmed by resonance Raman spectroscopy.

Abstract: A Roman archaeological site in northern Spain (La Maja, province of La Rioja) includes pottery workshops, part of an important ceramic industry that developed from about the first century BC to the first century AD. A geophysical study was planned to determine the extent of the industrial complex in the vicinity of an excavated kiln. Magnetic observations were done on a grid of 30 × 36m, with a sampling interval of 1m. Two dipolar-shaped anomalies were found: one in the north-east and the other in the south-west of the area. Low-pass and band-pass filters were used in the Fourier domain to enhance the characteristics of the magnetic data and to remove noise and undesirable shallow features. Three-dimensional polygonal prisms were used to model the magnetic anomalies based on palaeomagnetic measurements performed over an uncovered kiln that helped to constrain the induced and remanent parameters of the magnetizing fields.

Abstract: Inverse filtering and multiple source Werner deconvolution are tested on synthetic data produced by models which simulate features that occur commonly in archaeological exploration. Inverse filtering produces patterns which reflect the magnetization and lateral extent of the subterranean bodies and which are located at their centres. Multiple source Werner deconvolution locates the corners of the bodies with adequate accuracy. Both schemes can provide significant aid in interpreting magnetic data acquired for archaeological exploration.

Abstract: Eighty sherds from nine different kiln sites representing a wide geographic distribution and a long time span of Korean celadon culture are analysed for macroscopic and compositional characteristics. Additionally chemical and mineral compositions of six unglazed sherds are compared with those of some modern raw materials. Unusually high values of alumina in the earliest Kangjin pieces of the middle ninth and early tenth century (I1) could represent a significant technological innovation at the end of this period at this most important celadon production centre. Similarity in chemical and mineral compositions between unglazed sherds and some raw materials such as Kangjin clay and pottery stone show the possibility that many of the celadons were made from these types of raw materials as found in nature without additives and only after mechanical refining.

Abstract: Fifty-three copper-based metal fragments, recovered from the Robitaille site in southcentral Ontario, were analysed by neutron activation to establish their chemical make-up and to sort them by their trace elemental chemistries. Three different European copper samples, one brassy copper and 48 brass samples with five different chemistries were found. As few as eight trading actions may account for all of the recovered European metal fragments.

Abstract: The study addresses the chemical variations for Roman Samian wares manufactured during various periods at different workshops within the Lezoux production centre. Instrumental neutron activation analysis and inductively coupled plasma spectrometry were used to determine the chemical constituents of the pottery. The two techniques were evaluated based on the capacity of each to identify the same compositional groups for Lezoux Samian with the use of multivariate statistics. The compositional analysis redefines and clarifies how potters used the clay sources at the site to produce fine wares. The results indicate that the majority of potters from different workshops at Lezoux shared the same clay source during the second century AD.

Abstract: During the examination of the sculpture of Medea Rejuvenating Aeson attributed to Louis-Simon Boizot (1743–1809), X-ray fluorescence analysis revealed, surprisingly, that the outer surface of the brass cast was patinated with platinum. Research into the history of platinum coating methods revealed that chemical techniques for the deposition of platinum from solution were in use before the advent of electroplating. Some experimental work to replicate the patination technique of electrochemical replacement plating of platinum based on recipes from the nineteenth century is described. The technical evidence suggests that a late eighteenth-century date for the sculpture is reasonable.

Abstract: Several samples of geological stones from statuary pedestals found in various archaeological sites in Cyprus have been characterized using non-contact laser infrared photothermal radiometry. Thermal diffusivities and effective optical absorption coefficients were calculated using a one-dimensional thermal-wave model. The mean values and standard deviations were tabulated and comparisons were made with lithographic and petrographic studies of the samples. Good correlations were found, thus demonstrating that laser photothermal archaeometry is a promising methodology for the accurate, potentially non-destructive and convenient characterization of the origins of ancient stones in Cyprus and other geological and archaeological sites.

Abstract: The application of petrographic analysis to the problems of provenance attribution of ceramics made in the Islamic world is complicated by the presence of the highly quartzose ‘stonepaste’body. To facilitate the differentiation of different stonepaste groups, it has been necessary to develop specific criteria for distinguishing the characteristics of each centre, including the assessment of the degree of cloudiness of the quartz as rendered by fluid inclusions. This has enabled the successful application of petrographic analysis, and the solution of a number of provenance problems.

Abstract: Stable oxygen and carbon isotopic ratios in modern and archaeological estuarine mollusc shells, Polymesoda radiata, change in accordance with seasonal salinity fluctuations in the Acapetahua estuary located on the Pacific coast of southern Mexico. This region receives −3000 mm of precipitation annually, most during a wet season between April and October. The changing flux of fresh water and organic detritus into the estuary causes large changes in the oxygen and carbon isotopic composition of the estuarine waters and in the carbonate precipitated by P. radiata. Oxygen isotopic ratios in the shells of molluscs collected by late Archaic period populations (5000–4000 BP) in this region indicate that patterns of rainfall were similar to today. Modern shells, however, exhibit much more negative carbon isotopic values than observed in prehistoric shells. This change may be associated with the input of modern fertilizers into the estuary.

Abstract: Obsidian provenancing studies comprise one of the most productive and successful research programmes of archaeological science. Obsidian characterization has been successful because workable obsidian is homogeneous on a small scale, analysable by a large number of methods, and is restricted to a small number of mainly readily distinguishable geological sources. Analytical, dating, source, and trade studies within the western Mediterranean, central and eastern Europe, the Aegean, and Anatolia and the Near East during the last 30 years or so are reviewed. Research has shown that distributions are mainly separate in the four regions examined, and that obsidian was traded up to 900km in the prehistoric period. Publications on obsidian in the areas under review reached a peak of frequency in the later 1970s and 1980s, but have now decreased in number. This may reflect changing fashions in archaeometric studies, and a current lack of routine application of the provenancing methods developed.