Abstract: Fifty-five fragments of Roman glass from Augusta Praetoria (Aosta, Italy) were analysed by inductively coupled plasma optical emission spectroscopy determining 15 elements (Si, Na, Ca, Al, Fe, Mg, Mn, Ti, Sr, Ba, Cr, Ni, Cu, Co and Pb) on dissolved samples; in addition, potassium was determined by flame atomic absorption spectroscopy. The analytical results indicate that all the fragments, with one exception, are silica-soda-lime glasses; (he exception is a potash glass. Cluster analysis was performed on the analytical data by accounting for either 14 (all the elements searched for but Ni and Pb) or eight elements (after further removal of Si, Fe, Mn, Cr, Cu and Co from the data set). The results obtained indicate that, once colouring and decolouring agents are removed, the classification of the glasses seems to be mainly determined by chronology; separate groups within coeval fragments may indicate different provenances.

Abstract: New evidence is reported here using transmission electron microscopy, scanning electron microscopy, and laser reflectance for the nature of the black glossy decoration layer present on the Attic black or red figure vases of the sixth to fourth century BC. The black layer, of total thickness about 20 μm, consists mainly of poly crystalline magnetite (Fe3O4) particles of dimensions from 0.2 μm down to extremely fine sizes embodied in an amorphous vitreous matrix. On the outer surface of the black paint we discovered for the first time a thin clear glassy film of approximate thickness 0.1 μm which is rich in Al and Fe and poor in Si. This film must be responsible for the characteristic sheen of the surface. This is verified with the reflection of laser light mostly in specular direction, a unique property compared with black paints of other areas and other periods.

Abstract: Res. d'A. : This paper reviews the ways in which assemblages of pottery have been quantified throughout the twentieth century, and the use to which such data have been put. The values of various ways of quantifying pottery are compared, and a theorical basis for the comparison of assemblages is described. Finally, the practical steps that need to be taken to make best use of the theory are set out

Abstract: The Nahal Mishmar hoard, found in a cave in the Judean Desert in 1961, is a key find for the study of Chalcolithic metallurgy in Israel and the Levant. Recent analyses of Chalcolithic metalwork from sites such as Shiqmim in Israel raised doubts about the validity of published analyses from the hoard. Accordingly a programme of re-analysis was established using atomic absorption spectrometry and electron probe microanalysis. The new analyses confirmed the doubts and showed that the metallurgy of Nahal Mishmar was the same as that at the other sites. The alloys used for the cast products in the hoard were generally ternary arsenic-antimony copper alloys with up to 20% alloy content; less common were compositions with arsenic and nickel. The unusual metallography of these alloys is described. Some suggestions are offered as to the mode of manufacture of the alloys.

Abstract: A non-destructive analytical method using both instrumental neutron activation and proton-induced gamma ray emission techniques was developed to study the provenance of obsidian artefacts from Turkey, Syria and Iraq

Abstract: Publication de la dix-septieme liste des datations radiocarbonne avec le systeme AMS Oxford. Origine geographique des echantillons, detail et commentaires.

Abstract: Res. d'A.: Magnetic susceptibility provides a rapid, cheap and non-destructive methode of in situ caracterization of archeological artefacts containing magnetic minerals, and can be used as an aid to geological provenancing. Three hundred and sixty-three Roman granite columns were mesured by this method and results show clear groupings similarities with potential granite sources in Italy, Turquey and Egypt. Magnetic susceptibility measurements must be made on representative, unweathered surfaces of rocks and artefacts, and corrected for object size and surface relief according to manufactures' recommendations. In addition, correction for column curvature have been derived for used with measurement made on columns.

Abstract: During the course of an investigation of fossil cave bear populations the uranium-series method for absolute age determination has been applied to bone material. The applicability of the method to bone samples from alpine caves could be demonstrated by the concordance of U/Th and U/Pa ages and cross-checks with the radiocarbon method. Stratigraphic agreement between bone ages and carbonate speleothetn ages also indicates the potential of the uranium-series method as a suitable tool for the age determination of fossil bones from alpine cave environments.

Abstract: Ancient copper coins from the Greek cities Nikopolis in Epirus and Thessaloniki in Macedonia, minted during Roman imperial times (31 BC to AD 268), were analysed non-destructively by proton induced X-ray emission, after removal of the patina. An intercompar-ison study using different analytical methods was also performed on five coins. Eleven elements were analysed quantitatively on all coins. Statistical analysis of the results was performed for their presentation in the form of dendrograms. Finally, the variations in the concentrations of some individual elements from emperor to emperor were examined.

Abstract: This study gathered and reported compositional and descriptive analyses of over 200 Italian Renaissance portrait medals in the collection of the National Gallery of Art, Washington A statistical model was developed for allocation of these medals into meaningful assemblages, using the surface alloy composition, and an expanded nomenclature was formulated. Copper, zinc, tin and lead were the primary elements found to combine to form a wide range of alloys, Common impurities were discovered to be significantly lower in the sixteenth-century medals when compared with those in the fifteenth-century medals. Renaissance medallists had an extensive knowledge of metallurgy and could produce a variety of alloys without the use of modern technology.

Abstract: This paper describes the use of electron spin resonance spectroscopy to estimate the degree of heating of quartzite cobbles from hearths on the floor of the archaeological remains of an eighteenth-century Dutch colonial slave lodge. A novel technique based on the comparison of line intensities for the E’and O-2 centres in quartz distinguished successfully between cobbles which had been heated to estimated temperatures ranging from 300 °C to 450° C and controls from an adjacent stream bed. This inexpensive and simple technique could be applied to a wide range of archaeological problems involving the thermal history of objects consisting of or containing quartz.

Abstract: The aim of this study is to achieve a better understanding of some of the factors that limit the thermoluminescence (TL) dating of glass. Using a‘model system’(lithium-disilicate samples having different levels of crystallinity from 0 to 100%), we show, first, that the TL of glass is reproducible only if the glass is not heated above its temperature glass transition and second, that there is a clear connection between the TL sensitivity and the degree of crvstallinity of the sample. We conclude that thermoluminescence is not a general dating method for archaeological glass, but it can be applied to particular glass samples that haue specified characteristics.

Abstract: In this paper we present the results of a chemical investigation by neutron activation analysis of sherds of different kinds of bird kotylai, bird bowls and related wares excavated in Kalabaktepe, a hill of the ancient city of Miletus. A new archaeological classification of this well-known group of Archaic ceramics of eastern Greece is presented. A number of kiln wasters of misfired vessels from Kalabaktepe revealed a characteristic local pattern. This pattern helped to clarify the provenance of some of the bird bowls classified archaeologically as of orientalizing type: they have been made in Miletus. But bird kotylai and bird bowls in the 'standard fabric’as well as other archaeologically related vessels show a different chemical pattern of unknown provenance.

Abstract: Fired ceramics containing zircon inclusions have been dated by allowing the zircons to regenerate their own thermoluminescence (TL) signal, hence auto-regenerative TL dating. The technique is conceptually straightforward. One first measures the TL accrued since the last heating of the material. The zircon grains are then stored for six months and the TL signal regenerated through self-irradiation is measured. Since the internal dose-rate for zircon is dominated by the internal component the age of the sample is simply given by the ratio of the natural to auto-regenerated signal times the laboratory storage period. The technique, however, requires the measurement of a very small auto-regenerated signal, which introduces a number of experimental and physical complications. The methods for overcoming these problems and successfully dating zircons by auto-regeneration are described.

Abstract: Archaeological exploration in the Taurus mountains at Goltepe in south-central Turkey has uncovered a site indicating the presence of extensive tin ore mining and smelling operations The most recent find of smelting crucible fragments allowed for a thermoluminescence-hased age determination spanning a late fifth to early third millennium BC date. This result is consistent with a number of radiocarbon dates derived for charcoal also found at the site. The importance of this site relates to the possible tin production and subsequent trade with southwestern Asia which would have provided this otherwise scarce ingredient to bronze technology in that area. This date is directly for crucible material and thus confirms the antiquity of tin smelting at Goltepe.

Abstract: There has been debate about whether standard principal components analysis is appropriate for the multivariate analysis of compositional data (eg oxide composition of glass), Loglinear transformation has been recommended by Aitchison as a prerequisite This paper argues that previous comparisons of methodological merits have tended to circularity of argument by making assumptions about the form of a good multivariate result To break the circularity of argument the authors have introduced randomized variables into five data sets A good result must recognize these randomized variables as noise and place them near the centroid of the principal components scattergram of variable loadings Standard principal components analysis is found to perform better than loglinear transformation in its ability to recognize the randomized variables It is concluded that loglinear transformation tends to introduce spurious structure into a table of compositional data This paper is followed by a comment by M J Baxter

Abstract: Jet has been widely used in the past for jewellery but was just one of a range of black lithic materials employed. When worked into small objects these materials can be visually indistinguishable, yet discrimination is important because of the restricted occurrence of jet. X-ray fluorescence (XRF) is a rapid non-destructive discriminatory technique, but not all samples are clearly classified, and inhomogeneity may pose problems. A reassessment of the use of XRF is reported. Other techniques considered include electron spin resonance, infrared spectroscopy, Raman spectroscopy, thermogravimetric analysis, scanning electron microscopy and X-radiography. These were tested on geological materials to define an effective methodology for archaeological material. The recommended approach is a combination of XRF and X-radiography, although preliminary Fourier transform infrared results showed promise. The X-ray techniques were tested on Romano-British assemblages from Catterick and Stanwick.

Abstract: A combination of micro-analytical techniques, including thin layer chromatography (TLC), gas chromatography (GC), and combined gas chromatography/mass spectrometry (GC/MS), was employed to study the lipid composition of an adhesive used to repair an Ecton ware jar, recovered from Roman sediments of the River Nene at West Cotton (Rounds, Northamptonshire, U.K.). GC of the total lipid extract of the adhesive showed a complex pattern which was difficult to interpret. TLC was used to fractionate the extract. The fractions were then trimethylsilylated and submitted to GC and GC/MS. Betulin, lupeol, lupenone, allobetul-2-ene, and several other pentacyclic triterpenoid compounds were shown to be present in the ancient material. The similarities between the lipid compositions of the adhesive and of contemporary birch bark tar and a birch bark total lipid extract led to the conclusion that the adhesive was derived largely from birch bark, thus providing the first firm evidence for the use of birch bark tar in ancient Britain.

Abstract: The levels of ten elements (phosphorus, calcium, magnesium, strontium, barium, potassium, sodium, zinc, iron, and aluminium) have been measured in the femurs and humeri of laboratory rats grown on test diets as a model for palaeodietary studies of excavated human skeletons. High levels of dietary fibre correlate with lower Ca and higher Sr and Ba in the bone. High values of the dietary Sr/Ca ratio correlate with high Sr levels in the bone. High levels of dietary protein correlate with lower Sr and higher Zn. High values of the ratio Ba/Ca and lower levels of Fe correlate with higher levels of Ba. Because bone levels typically are controlled by several dietary components, variation of the levels of a given element in the diet does not necessarily translate into analogous variations in bone. Only K and Fe in bone correlate highly with their levels in diet. The failure of bone Sr, Ba, and Zn to correlate positively with dietary levels is fully explicable in terms of their interdependence on other dietary components, such as Ca, P, Fe, protein, and fibre.