Rise of silicene: A competitive 2D material

Two-dimensional crystals have emerged as a class of materials that may impact future electronic technologies. Experimentally identifying and characterizing new functional two-dimensional materials is challenging, but also potentially rewarding. Here, we fabricate field-effect transistors based on few-layer black phosphorus crystals with thickness down to a few nanometres. Reliable transistor performance is achieved at room temperature in samples thinner than 7.5 nm, with drain current modulation on the order of 10(5) and well-developed current saturation in the I-V characteristics. The charge-carrier mobility is found to be thickness-dependent, with the highest values up to ∼ 1,000 cm(2) V(-1) s(-1) obtained for a thickness of ∼ 10 nm. Our results demonstrate the potential of black phosphorus thin crystals as a new two-dimensional material for applications in nanoelectronic devices.

http://absimage.aps.org/image/MAR14/MWS_MAR14-2013-005031.pdf

Black Phosphorus Field-effect Transistors

Silicene is a two-dimensional allotrope of silicon with a puckered hexagonal structure closely related to the structure of graphene and that has been predicted to be stable. To date, it has been successfully grown in solution (functionalized) and on substrates. The goal of this review is to provide a summary of recent theoretical advances in the properties of both free-standing silicene as well as in interaction with molecules and substrates, and of proposed device applications.

/pdf/silicene-recent-theoretical-advances-32m3cr0kqn.pdf

Silicene: Recent theoretical advances

Structural, electronic, mechanical and thermodynamic properties of Cr–Si binary silicides from first-principles investigations

Chromium-based silicides (Cr–Si) are broadly used in thermoelectric devices, semiconductors, ultrahigh-temperature devices, and energy-storage systems. However, the structural feature and related p...

Structural Prediction and Overall Performances of CrSi2 Disilicides: DFT Investigations

Under external transverse electronic fields, the structure and electronic properties of the silicene nanoribbon with armchair edge (ASiNR) are studied. We find that the electric properties are modified by a transverse electric field. As affected by a transverse electric field, the band gap varies with increasing absolute value of the field strength. All the results can be explained using the Stark quadratic effect.

Band-gap modulations of armchair silicene nanoribbons by transverse electric fields

The search for and design of high-performance electrode materials is always an important topic in rechargeable batteries. Using a global structure prediction method together with first-principles calculations, a free-standing two-dimensional B2C3P monolayer with honeycomb structure was identified. The stability of the B2C3P monolayer was confirmed by cohesive energy, phonon curves, and ab initio molecular dynamics calculations. Of note, the B2C3P monolayer was demonstrated to be metallic, which shows excellent performance for Li-ion batteries. For example, the B2C3P monolayer also exhibited a metallic characteristic after Li adsorption, therefore the ability to keep good electrical conductivity during battery operation. Furthermore, when a B2C3P monolayer is used as a lithium-ion battery anode, it shows an ultra-high theoretical capacity of 3024 mAh/g, and a comparatively low diffusion barrier of 0.33 eV. All calculated results showed that the B2C3P monolayer is an appealing anode material, and has great potential in energy storage devices.

/pdf/metallic-b2c3p-monolayer-as-li-ion-battery-materials-a-first-2pfnqi81.pdf

Metallic B2C3P Monolayer as Li-Ion Battery Materials: A First-Principles Study

Phase transition and thermodynamic properties of YAg alloy from first-principles calculations

Carbon nanoparticle (CNP)-polymer sensors are good candidates for monitoring structural damage. A combined numerical-analytical approach with considering the stiffness degradation of composite is proposed to calculate the resistance variations with the cyclic loads. The electro-mechanical behavior of the sensor can be simulated through the finite element analysis of a random representative volume element model and the equivalent resistance calculation of microcircuit. Then, taking the glass fiber-reinforced composite coated with the CNP-epoxy resin as example, its electro-mechanical behavior under tension-tension cyclic loading is investigated experimentally and numerically. Furthermore, by microscopic analysis, the fatigue damage monitoring mechanism of the sensor is revealed. 

Investigation on carbon nanoparticle (CNP)-polymer sensors for fatigue monitoring of fiber-reinforced composites

Using the crystal-structure search technique and first-principles calculation, we report a new two-dimensional semiconductor, ZnSiP2, which was found to be stable by phonon, molecular-dynamic, and elastic-moduli simulations. ZnSiP2 has an indirect band gap of 1.79 eV and exhibits an anisotropic character mechanically. Here, we investigated the ZnSiP2 monolayer as an anode material for K-ion batteries and gas sensing for the adsorption of CO, CO2, SO2, NO, NO2, and NH3 gas molecules. Our calculations show that the ZnSiP2 monolayer possesses a theoretical capacity of 517 mAh/g for K ions and an ultralow diffusion barrier of 0.12 eV. Importantly, the ZnSiP2 monolayer exhibits metallic behavior after the adsorption of the K-atom layer, which provides better conductivity in a period of the battery cycle. In addition, the results show that the ZnSiP2 monolayer is highly sensitive and selective to NO2 gas molecules.

/pdf/a-novel-two-dimensional-znsip2-monolayer-as-an-anode-3fomtflc.pdf

A Novel Two-Dimensional ZnSiP2 Monolayer as an Anode Material for K-Ion Batteries and NO2 Gas Sensing

Handle everyday research tasks with reliable, citation-backed results

Your personal Research Agent to handle research tasks with citation-backed results

Popular Tasks used by Researchers

How can I help with your research?

Meet SciSpace

Get more enhanced response by uploading the PDFs you want me to reference.

No relevant PDFs in your library

SciSpace is the AI research assistant for academics. Run systematic literature reviews on 280M+ papers, and write papers with cited sources. Trusted by 1M+ students, PhDs & researchers.

SciSpace | AI for Research

Analyze PDFs

Code & Manuscripts

Funding & Grants

Literature & Patents

Medical & Clinical Data

Systematic Review

Visualize & Present

Web & Data

Build a Google Scholar-like website for your research.

Build a website

Create charts and images for your research

Create a Chart

Write a paper for submission to a journal

Draft a manuscript

Patent Search

Design eye-catching scientific posters in minutes.

Scientific Poster Generation

Systematic Literature Review

One task is running at the moment. Your messages will be shown right after.

Drag and drop or click here to browse

Loved by <highlight>1 million+</highlight> researchers

Extract a list of specific topics and their sources from unstructured text

Topics

Compare and analyze relevant papers that matches with your search

Papers

Get insights from PDFs and bookmarked papers from your library

My library

Recent searches

Try searching for:

Catch AI-generated content in scholarly and non-scholarly content

{ai} Detector

Ai Writer

Get PDF Summaries, highlighted text explanations 

Chat with PDF

Effortlessly create in-text citations and bibliographies in APA and 2,500 other formats

Citation generator

Get explanations, summaries, and answers on academic papers

Ease up your research workflow with {scispace}'s cohort of exciting AI tools

Elevate your academic writing skills and convey your ideas the way you want

Paraphraser

Explore our range of reading and writing tools

Your file is being prepared and should be ready in a few minutes. If it's a large file, it might take a bit longer. You can close this window, and we'll email you the file when it's done.

You have reached a maximum limit of <strong>{limit}</strong> columns in the table. Remove at least <strong>1</strong> column to add or create another one.

Zhuo Wang

Author Tools

Chat about Author