21 Papers
133 Citations
Yohan Macé is an academic researcher from Centre national de la recherche scientifique. The author has contributed to research in topics: Sulfoxide & Sulfilimine. The author has an hindex of 9, co-authored 21 publications. Previous affiliations of Yohan Macé include University of Paris-Sud.
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Papers
The New Age of Electrophilic Perfluoroalkylation Reactions†‡
Yohan Macé,Emmanuel Magnier +1 more
TL;DR: The introduction of a perfluoroalkyl group, with emphasis on the trifluoromethyl moiety, is a challenging topic as mentioned in this paper, however, a renaissance of this chemistry has happened thanks to reports both of numerous new reagents (stable, easy to handle and to prepare) and of easier preparation of older reagents.
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Octupolar derivatives functionalized with superacceptor peripheral groups: synthesis and evaluation of the electron-withdrawing ability of potent unusual groups.
Cédric Rouxel,Céline Le Droumaguet,Yohan Macé,Sophie Clift,Olivier Mongin,Emmanuel Magnier,Mireille Blanchard-Desce,Mireille Blanchard-Desce +7 more
TL;DR: Evidence of a linear correlation between the Hammett constant (σ(p)) values and the electronic gap between the ground and first excited state of the three-branched derivatives is provided, which was used to derive σ(p) values of fluorinated sulfoximinyl moieties.
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Sulfilimines and Sulfoximines by Reaction of Nitriles with Perfluoroalkyl Sulfoxides
Yohan Macé,Céline Urban,Charlotte Pradet,Jerome Marrot,Jean-Claude Blazejewski,Emmanuel Magnier +5 more
TL;DR: The species obtained by activation of perfluoroalkylated sulfoxides with trifluoromethanesulfonic anhydride behaves as highly electrophilic entities.
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Mechanistical insight into ‘electrophilic’ trifluoromethylation with S-(trifluoromethyl)dibenzothiophenium salts
TL;DR: In this article, it was shown that trifluoromethyl sulfonium salts are widely used for the introduction of a trifucloromethsyl group through reaction with a wide range of nucleophiles such as enol silyl ethers.
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Efficient copper-induced coupling between NH -fluoroalkylated sulfoximines and aryl iodides or bromides
Yohan Macé,Yohan Macé,Bruce Pégot,Régis Guillot,Chloée Bournaud,Martial Toffano,Giang Vo-Thanh,Emmanuel Magnier +7 more
TL;DR: In this paper, a copper-based system for N-arylation of fluorinated sulfoximines was proposed, and the best results were achieved using copper iodide in combination with DMEDA and Cs2CO3.
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