Two step synthesis of ZnO/Ag and ZnO/Au core/shell nanocomposites: Structural, optical and electrical property analysis

Significant photocurrent enhancement of 0.4 mA/cm2 has been achieved for industrial textured multicrystalline silicon solar cells, due to the light trapping provided by aluminium nanoparticle enhanced antireflection coating. Aluminium nanoparticles support surface plasmon resonances, which can effectively scatter the light into the solar cells. By blue shifting the detrimental Fano resonances away from the important silicon absorption spectrum, aluminium nanoparticles can provide a broadband light absorption enhancement without a reduction at the short wavelengths. Combining the discovery with 75 nm silicon nitride antireflection coating, which can significantly enhance the absorption at the peak solar spectrum, we have achieved the strong broadband light absorption enhancement.

https://researchbank.swinburne.edu.au/file/0f00d9e1-1f9c-4536-81b8-af9e7d11c084/1/PDF (Published version).pdf

Improved multicrystalline Si solar cells by light trapping from Al nanoparticle enhanced antireflection coating

https://nanoenergy.kaust.edu.sa/Documents/1-s2.0-S2211285514000330-main.pdf

A broadband and omnidirectional light-harvesting scheme employing nanospheres on Si solar cells

Super absorption of ultra-thin organic photovoltaic films

Designing effective light-trapping structures for the insufficiently absorbed long-wavelength light in ultrathin silicon solar cells represents a key challenge to achieve low cost and highly efficient solar cells. We propose a hybrid structure based on the biomimetic silicon moth-eye structure combined with Ag nanoparticles to achieve advanced light trapping in 2 μm thick crystalline silicon solar cells approaching the Yablonovitch limit. By synergistically using the Mie resonances of the silicon moth-eye structure and the plasmonic resonances of the Ag nanoparticles, the integrated absorption enhancement achieved across the usable solar spectrum is 69% compared with the cells with the conventional light trapping design. This is significantly larger than both the silicon moth-eye structure (58%) and Ag nanoparticle (41%) individual light trapping. The generated photocurrent in the 2 μm thick silicon layer is as large as 33.4 mA/cm2, which is equivalent to that generated by a 30 μm single-pass absorption in the silicon. The research paves the way for designing highly efficient light trapping structures in ultrathin silicon solar cells.

Biomimetic and plasmonic hybrid light trapping for highly efficient ultrathin crystalline silicon solar cells

The effect of absorption enhancement with metallic nanoparticles on solar cell surfaces is often confused with various optical processes. In this work, the effective absorption rates in the active materials of solar cells are explicitly calculated including all possible factors. The results show that, although the total absorption is highly enhanced in general, the effective absorption in the active region is not much enhanced and even strongly reduced in the blue–violet regime. As the solar spectrum is considered, the integrated absorbed power in the solar cell materials is shown to be similar for structures with or without metallic nanoparticles.

Role of surface metal nanoparticles on the absorption in solar cells

Three novel corroles, 5,15-bis(phenyl)-10-(3-methoxy-4-hydroxylphenyl)- corrole PC, 5,15-bis(naphthyl)-10-(3-methoxy-4-hydroxylphenyl)-corrole NAPC and 5,15-bis(pyrenyl)-10-(3-methoxy-4-hydroxylphenyl)-corrole PYPC, were designed and synthesized. Their graphene oxide (GO) nanohybrids, PC-GO, NAPC-GO and PYPC-GO, were prepared by a covalent functionalization method and characterized by various spectroscopic techniques. The third order nonlinear optical (NLO) behavior of the corroles and their corresponding nanohybrids was investigated using open aperture Z-scan technique at 532 nm with 4 ns laser pulses. The nanohybrids showed enhanced NLO properties in comparison to the corresponding corroles. In addition, the NLO properties of nanohybrids increase in the order of NAPC-GO < PC-GO < PYPC-GO, while the corrole molecules exhibit NLO performance in the same order of NAPC < PC < PYPC, implying the NLO response originating from the corrole moiety play a more important role in the NLO properties of the nanohybrids than that arising from the photo-induced electron or energy transfer process between GO and corrole molecules. Importantly, at same transmission intensity, all the corroles showed typical nonlinear reverse saturation absorption (RSA) behavior, while all the nanohybrids exhibited a flip over behavior from saturation absorption (SA) to RSA. The different NLO response between the corrole molecules and their nanohybrids implies their promising applications as NLO materials. 

Preparation and third order nonlinear optical properties of corrole functionalized GO nanohybrids

Metallic nanoslit arrays usually demonstrate wide transmission bands for transverse-magnetic-polarized incidence light Here, we show that by introducing multi-dielectric layers underneath the metallic structure layer on the substrate, a narrow peak is formed, whose bandwidth can be down to a few nanometers Three types of resonance modes in the region under the metal layer are identified responsible for the formation of the peak, ie, a two-dimensional cavity resonance mode, which supports optical transmission, and two in-plane hybrid surface plasmon resonance modes locating on both sides of the peak that suppresses the transmission Such structures can be applied in advanced photonic devices

Narrow-band optical transmission of metallic nanoslit arrays

We propose a simple method, using the first singular value (FSV) of the spatial correlation of biphotons, to characterize topological phase transitions (TPTs) in one-dimensional (1D) topological photonic waveguide arrays (PWAs). After analyzing the spatial correlation of biphotons using the singular value decomposition, we found that the FSV of the spatial correlation of biphotons in real space can characterize TPTs and distinguish between the topological trivial and nontrivial phases in PWAs based on the Su-Schrieffer-Heeger model. The analytical simulation results were demonstrated by applying the coupled-mode theory to biphotons and were found to be in good agreement with those of the numerical simulation. Moreover, the numerical simulation of the FSV (of the spatial correlation of biphotons) successfully characterized the TPT in a PWA based on the Aubry-André-Harper and Rice-Mele models, demonstrating the universality of this method for 1D topological PWAs. Our method provides biphotons with the possibility of acquiring information regarding TPTs directly from the spatial correlation in real space, and their potential applications in quantum topological photonics and topological quantum computing as quantum simulators and information carriers.

Observation of the topological phase transition from the spatial correlation of a biphoton in a one-dimensional topological photonic waveguide array.

Tunable single-photon routing between two single-mode waveguides by a giant Λ-type three-level atom

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