Zirconium and its stable isotopes in igneous systems

Copper and lead isotope records from an electroplating activity in sediments and biota from Sepetiba Bay (southeastern Brazil).

Gallium isotope constraints on the intense weathering of basalt

Anomalous mercury (Hg) contents recorded near the Permian-Triassic boundary (PTB) are often linked to Siberian Traps Large Igneous Province (STLIP) volcanism and the Permian-Triassic boundary mass extinction (PTBME). However, mounting evidence indicates that the relation between STLIP volcanism and Hg “anomalies” is not straightforward. This study focuses on the timing and provenance of volcanic fluxes around the PTBME in South China. We constrain carbon isotope (δ13C) and Hg concentration and isotope records by utilizing high-precision U-Pb zircon ages from two expanded deep-water marine sections spanning the Late Permian to Early Triassic in the Nanpanjiang Basin. Results reveal two episodes of Hg enrichment. The oldest episode predates the onset of a large negative δ13C excursion, which is documented to be older than 252.07 ± 0.130 Ma. The second episode occurred between 251.822 ± 0.060 and 251.589 ± 0.062 Ma, coinciding with the nadir of the δ13C excursion. Volcanic ash geochemistry and Hg isotope compositions suggest that mercury was mainly sourced from subduction-related volcanic arc magmatism in the Tethys region, which peaked between 251.668 ± 0.079 and 251.589 ± 0.052 Ma. These results are compatible with suggestions that regional arc volcanism contributed to the causes of the PTBME in South China and provide evidence that Hg anomalies close to the PTB are not a reliable stratigraphic marker for the PTB extinction event. This study demonstrates that relations between volcanism, environmental perturbations and mass extinction during the Permian-Triassic transition are better resolved with the aid of high-precision U-Pb zircon ages. 

https://onlinelibrary.wiley.com/doi/pdfdirect/10.1029/2023GC010912

Timing and Provenance of Volcanic Fluxes Around the Permian‐Triassic Boundary Mass Extinction in South China: U‐Pb Zircon Geochronology, Volcanic Ash Geochemistry and Mercury Isotopes

Anomalous mercury (Hg) contents recorded near the Permian‐Triassic boundary (PTB) are often linked to Siberian Traps Large Igneous Province (STLIP) volcanism and the Permian‐Triassic boundary mass extinction (PTBME). However, mounting evidence indicates that the relation between STLIP volcanism and Hg “anomalies” is not straightforward. This study focuses on the timing and provenance of volcanic fluxes around the PTBME in South China. We constrain carbon isotope (δ13C) and Hg concentration and isotope records by utilizing high‐precision U‐Pb zircon ages from two expanded deep‐water marine sections spanning the Late Permian to Early Triassic in the Nanpanjiang Basin. Results reveal two episodes of Hg enrichment. The oldest episode predates the onset of a large negative δ13C excursion, which is documented to be older than 252.07 ± 0.130 Ma. The second episode occurred between 251.822 ± 0.060 and 251.589 ± 0.062 Ma, coinciding with the nadir of the δ13C excursion. Volcanic ash geochemistry and Hg isotope compositions suggest that mercury was mainly sourced from subduction‐related volcanic arc magmatism in the Tethys region, which peaked between 251.668 ± 0.079 and 251.589 ± 0.052 Ma. These results are compatible with suggestions that regional arc volcanism contributed to the causes of the PTBME in South China and provide evidence that Hg anomalies close to the PTB are not a reliable stratigraphic marker for the PTB extinction event. This study demonstrates that relations between volcanism, environmental perturbations and mass extinction during the Permian‐Triassic transition are better resolved with the aid of high‐precision U‐Pb zircon ages.

Zirconium isotopes track volcanic inputs during the Permian-Triassic transition in South China

Copper and gallium isotopic behavior in highly weathered soils

A time-saving and high-efficient chemical separation procedure to isolate Zn and Mo from various geological samples is developed, which is based on a single pass of a double-stack column. The...

A fast double-stack column chemical separation of Zn and Mo from geological samples for isotopic analysis by MC-ICP-MS

First Determination of δ53CrSRM979 in Sixteen Geological Reference Materials Using Double Spike Thermal Ionisation Mass Spectrometry after a Two‐Column Matrix Separation

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Zirconium isotopes track volcanic inputs during the Permian-Triassic transition in South China

Copper and gallium isotopic behavior in highly weathered soils

A fast double-stack column chemical separation of Zn and Mo from geological samples for isotopic analysis by MC-ICP-MS

First Determination of δ53CrSRM979 in Sixteen Geological Reference Materials Using Double Spike Thermal Ionisation Mass Spectrometry after a Two‐Column Matrix Separation