Graphene nanoribbons: Current status and challenges as quasi-one-dimensional nanomaterials

The past one and a half decades have witnessed the tremendous progress of two-dimensional (2D) crystals, including graphene, transition-metal dichalcogenides, black phosphorus, MXenes, hexagonal boron nitride, etc., in a variety of fields. The key to their success is their unique structural, electrical, mechanical and optical properties. Herein, this paper gives a comprehensive summary on the recent advances in 2D materials for optoelectronic approaches with the emphasis on the morphology and structure, optical properties, synthesis methods, as well as detailed optoelectronic applications. Additionally, the challenges and perspectives in the current development of 2D materials are also summarized and indicated. Therefore, this review can provide a reference for further explorations and innovations of 2D material-based optoelectronics devices.

/pdf/advances-in-two-dimensional-materials-for-optoelectronics-139lymsc.pdf

Advances in Two-Dimensional Materials for Optoelectronics Applications

We examined the relationship between the intrinsic structure of a carbocatalyst and catalytic activity of peroxomonosulfate (PMS) activation for acetaminophen degradation. A series of nitrogen-doped carbon nanotubes with different degrees of oxidation was synthesized by the unzipping method. The linear regression analysis proposes that pyridinic N and graphitic N played a key role in the catalytic oxidation, rather than pyrrolic N and oxidized N. Pyridinic N reinforce the electron population in the graphitic framework and initiate the non-radical pathway via the formation of surface-bound radicals. Furthermore, graphitic N forms activated complexes (carbocatalyst-PMS*), facilitating the electron-transfer oxidative pathway. The correlation also affirms that -C=O was dominantly involved as a main active site, rather than -C-OH and -COOH. This study can be viewed as the first attempt to demonstrate the relationship between the fraction of N-groups and activity, and the quantity of O-groups and activity by active species (quenching studies) was established to reveal the role of N-groups and O-groups in the radical and non-radical pathways. 

/pdf/role-of-n-doping-and-o-groups-in-unzipped-n-doped-cnt-7fpcgrd5.pdf

Role of N-Doping and O-Groups in Unzipped N-Doped CNT Carbocatalyst for Peroxomonosulfate Activation: Quantitative Structure–Activity Relationship

Graphene nanoribbons grown in hBN stacks for high-performance electronics

In recent years, the emergence of low-dimensional carbon-based materials, such as carbon dots, carbon nanotubes, and graphene, together with the advances in materials science, have greatly enriched the variety of flexible and stretchable electronic devices. Compared with conventional rigid devices, these soft robotic sensors and actuators exhibit remarkable advantages in terms of their biocompatibility, portability, power efficiency, and wearability, thus creating myriad possibilities of novel wearable and implantable tactile sensors, as well as micro-/nano-soft actuation systems. Interestingly, not only are carbon-based materials ideal constituents for photodetectors, gas, thermal, triboelectric sensors due to their geometry and extraordinary sensitivity to various external stimuli, but they also provide significantly more precise manipulation of the actuators than conventional centimeter-scale pneumatic and hydraulic robotic actuators, at a molecular level. In this review, we summarize recent progress on state-of-the-art flexible and stretchable carbon-based sensors and actuators that have creatively added to the development of biomedicine, nanoscience, materials science, as well as soft robotics. In the end, we propose the future potential of carbon-based materials for biomedical and soft robotic applications.

/pdf/flexible-and-stretchable-carbon-based-sensors-and-actuators-1sdwjbyr.pdf

Flexible and Stretchable Carbon-Based Sensors and Actuators for Soft Robots

The lack of a sizeable band gap has so far prevented graphene from building effective electronic and optoelectronic devices despite its numerous exceptional properties. Intensive theoretical research reveals that a band gap larger than 1 eV can only be achieved in sub-3 nm wide graphene nanoribbons (GNRs), but real fabrication of such ultranarrow GNRs still remains a critical challenge. Herein, we demonstrate an approach for the synthesis of ultranarrow and photoluminescent semiconducting GNRs by longitudinally unzipping single-walled carbon nanotubes. Atomic force microscopy reveals the unzipping process, and the resulting 2.2 nm wide GNRs are found to emit strong and sharp photoluminescence at ∼685 nm, demonstrating a very desirable semiconducting nature. This band gap of 1.8 eV is further confirmed by follow-up photoconductivity measurements, where a considerable photocurrent is generated, as the excitation wavelength becomes shorter than 700 nm. More importantly, our fabricated GNR field-effect transistors (FETs), by employing the hexagonal boron nitride-encapsulated heterostructure to achieve edge-bonded contacts, demonstrate a high current on/off ratio beyond 105 and carrier mobility of 840 cm2/V s, approaching the theoretical scattering limit in semiconducting GNRs at room temperature. Especially, highly aligned GNR bundles with lengths up to a millimeter are also achieved by prepatterning a template, and the fabricated GNR bundle FETs show a high on/off ratio reaching 105, well-defined saturation currents, and strong light-emitting properties. Therefore, GNRs produced by this method open a door for promising applications in graphene-based electronics and optoelectronics.

Photoluminescent Semiconducting Graphene Nanoribbons via Longitudinally Unzipping Single-Walled Carbon Nanotubes.

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Photoluminescent Semiconducting Graphene Nanoribbons via Longitudinally Unzipping Single-Walled Carbon Nanotubes.