Yang Yang
University of Melbourne
7 Papers
43 Citations
Yang Yang is an academic researcher from University of Melbourne. The author has contributed to research in topics: Organopalladium & Isopropyl. The author has an hindex of 4, co-authored 7 publications.
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Papers
Palladium-Mediated CO2 Extrusion Followed by Insertion of Isocyanates for the Synthesis of Benzamides: Translating Fundamental Mechanistic Studies To Develop a Catalytic Protocol
TL;DR: In this paper, a stoichiometric palladium-mediated ExIn (ExIn = extrusion-insertion) decarboxylative amidation of aromatic carboxylic acids is presented, providing gas-phase and condensed-phase spectroscopic data, as well as theoretical computational evidence for intermediates in a proposed stepwise process.
18
Tetraorganylargentate(III) Complexes: Key Intermediates in Silver-Mediated Cross-Coupling Reactions
TL;DR: In this paper, the use of silver as a catalyst in cross-coupling reactions remains underdeveloped, and it is shown by means of electrospray ionization mass spectrometry that the diorganylargentates LiAgR′2·Li(CN) (R′ = M...
17
Synthesis of Amidines by Palladium-Mediated CO2 Extrusion Followed by Insertion of Carbodiimides: Translating Mechanistic Studies to Develop a One-Pot Method
TL;DR: A palladium-mediated one-pot synthesis of amidines from aromatic carboxylic acids and carbodiimides (RNCNR) was reported as an isoelectronic adaption of CO2ExIn (ExIn = Extrusion-Insertion) reactions developed for the synthesis of thioamides from carboxyl acids and isothiocyanates as mentioned in this paper.
17
Desulfination versus decarboxylation as a means of generating three- and five-coordinate organopalladium complexes [(phen)nPd(C6H5)]+ (n = 1 and 2) to study their fundamental bimolecular reactivity
TL;DR: In this paper, a combination of low energy collision induced dissociation experiments in an ion trap mass spectrometer and DFT calculations was used to examine the route to the formation of 1,10-phenanthroline ligated organopalladium complexes.
7
Gas-phase studies of copper(I)-mediated CO2 extrusion followed by insertion of the heterocumulenes CS2 or phenylisocyanate
TL;DR: The mechanistic understanding obtained from these model studies encourages future development of a solution phase protocol for the synthesis of amides from carboxylic acids and isocyanates mediated by copper(I) complexes.