Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency and selectivity. However, the structural complexity and vulnerability hamper the application potentials of enzymes. Driven by the practical demand for chemical conversion, there is a long-sought quest for bioinspired catalysts reproducing and even surpassing the functions of natural enzymes. As nanoporous materials with high surface areas and crystallinity, metal-organic frameworks (MOFs) represent an exquisite case of how natural enzymes and their active sites are integrated into porous solids, affording bioinspired heterogeneous catalysts with superior stability and customizable structures. In this review, we comprehensively summarize the advances of bioinspired MOFs for catalysis, discuss the design principle of various MOF-based catalysts, such as MOF-enzyme composites and MOFs embedded with active sites, and explore the utility of these catalysts in different reactions. The advantages of MOFs as enzyme mimetics are also highlighted, including confinement, templating effects, and functionality, in comparison with homogeneous supramolecular catalysts. A perspective is provided to discuss potential solutions addressing current challenges in MOF catalysis.

Bioinspired Framework Catalysts: From Enzyme Immobilization to Biomimetic Catalysis.

Luminescent Lanthanide Metal Organic Frameworks (LnMOFs): A Versatile Platform towards Organomolecule Sensing

Fluorophore molecule loaded in Tb-MOF for dual-channel fluorescence chemosensor for consecutive visual detection of bacterial spores and dichromate anion

• One-, two-, and three-dimensional luminescent lanthanide coordination polymers are focused for sensing applications. • Changeable luminescence come from the energy transfer between lanthanide(III) ions and aromatic organic ligands. • Their physical and chemical sensitive luminescence are useful for future sensing applications. The photophysical process of lanthanide(III) ion is based on the 4f-4f transition, which is the Laporte forbidden with narrow emission band and long emission lifetime. The 4f-4f emission process is affected by introducing aromatic organic ligands. In this review, recent progress of one-, two-, and three-dimensional polymer-typed lanthanide complexes, luminescent lanthanide coordination polymers, are focused for physical and chemical sensing applications. Their changeable luminescence depended on the physical and chemical environments come from the energy transfer between lanthanide(III) ions and aromatic organic ligands. The characteristic physical (temperature, pressure, pH and mechanical force) and chemical (adsorption of metal ions and molecules) sensitive luminescence of lanthanide coordination polymers are useful for future sensing applications. 

Luminescent lanthanide coordination polymers with transformative energy transfer processes for physical and chemical sensing applications

A new polydentate tetracarboxylic acid with a benzothiadiazole unit (4',4'''-(benzo[c][1,2,5]thiadiazole-4,7-diyl)bis([1,1'-biphenyl]-3,5-dicarboxylic acid), H4BTDBA) has been used to prepare a pH-stable three-dimensional TbIII-based metal-organic framework (MOF) with the formula {[(CH3)2NH2]0.7[Tb2(BTDBA)1.5(lac)0.7(H2O)2]·solvents}n (Hlac = lactic acid, JXUST-19). JXUST-19 exhibits a new (4,4,12)-connected topology based on tetranuclear [Tb4] clusters. JXUST-19 can remain stable when soaked in water for at least 1 week and in aqueous solutions with various pH values (2-12) for 24 h. Fluorescence study indicates JXUST-19 can be employed as a rare turn-on and blue-shift MOF sensor toward benzaldehyde (BZ) and salicylaldehyde (SA). To date, JXUST-19 represents the first TbIII-based turn-on MOF sensor toward salicylaldehyde in aqueous solution, and the fluorescence enhancement and naked-eye detection of BZ have been rarely reported. In addition, JXUST-19 based fluorescent test papers, light-emitting diode lamp beads, and portable composite films were developed to realize naked-eye detection of BZ and SA, which has great potential in practical applications.

A pH-Stable TbIII-Based Metal-Organic Framework as a Turn-On and Blue-Shift Fluorescence Sensor toward Benzaldehyde and Salicylaldehyde in Aqueous Solution.

From the perspective of efficient and economical utilization of materials, it is very meaningful to achieve multifunctional performance in its assembly process, and this is also the future developm...

Construction of Multifunctional Luminescent Lanthanide MOFs by Hydrogen Bond Functionalization for Picric Acid Detection and Fluorescent Dyes Encapsulation

In recent years, many researchers have leveraged various memristors to design many novel memristive chaotic systems with complex dynamics. Compared with other chaotic systems, applying these memristive chaotic systems to image encryption is expected to solve some key problems in this field. Therefore, exploiting a recently reported memristive chaotic system, this paper proposes a novel image encryption scheme based on the memristive chaotic system and combining bidirectional bit-level cyclic shift and dynamic DNA-level diffusion (IES-M-BD). First, a discrete memristive chaotic map is employed to generate chaotic sequences. Then, the plaintext image is shifted circularly on bit-level according to chaotic sequences and the hash value of the plaintext image. After that, the shifted matrix is recombined on the bit plane and encoded dynamically by DNA encoding rules. Next, dynamic DNA-level diffusion and DNA-level permutation are carried out in two rounds. Finally, the encrypted image is obtained after dynamic DNA decoding. Simulation tests and performance analyses are also carried out in this paper. The simulation results and the security analyses demonstrate that this encryption scheme has a high security level and can resist various attacks.

https://www.frontiersin.org/articles/10.3389/fphy.2022.963795/pdf

A novel image encryption scheme based on memristive chaotic system and combining bidirectional bit-level cyclic shift and dynamic DNA-level diffusion

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Construction of Multifunctional Luminescent Lanthanide MOFs by Hydrogen Bond Functionalization for Picric Acid Detection and Fluorescent Dyes Encapsulation

A novel image encryption scheme based on memristive chaotic system and combining bidirectional bit-level cyclic shift and dynamic DNA-level diffusion