Role of Structural Factors in the Nonlinear Optical Properties of Phthalocyanines and Related Compounds

The control of luminous radiation has extremely important implications for modern and future technologies as well as in medicine. In this Review, we detail chemical structures and their relevant photophysical features for various groups of materials, including organic dyes such as metalloporphyrins and metallophthalocyanines (and derivatives), other common organic materials, mixed metal complexes and clusters, fullerenes, dendrimeric nanocomposites, polymeric materials (organic and/or inorganic), inorganic semiconductors, and other nanoscopic materials, utilized or potentially useful for the realization of devices able to filter in a smart way an external radiation. The concept of smart is referred to the characteristic of those materials that are capable to filter the radiation in a dynamic way without the need of an ancillary system for the activation of the required transmission change. In particular, this Review gives emphasis to the nonlinear optical properties of photoactive materials for the functi...

Nonlinear Optical Materials for the Smart Filtering of Optical Radiation.

Double-layer nanoparticle-based coatings for efficient terrestrial radiative cooling

Double layer SiO2/Al2O3 high emissivity coatings on stainless steel substrates using simple spray deposition system

Enhanced infrared emissivity of CeO2 coatings by La doping

Carbon nanotubes doped SiO2/SiO2–PbO double layer high emissivity coating

Enhanced optical limiting properties in a novel metallophthalocyanine complex (C12H25O)8PcPb

Large nanosecond and picosecond optical limiting responses of novel planar transition-metal chalcogen cluster complex [WS4Cu4I2(py)6] were studied by using a double frequency nanosecond/picosecond Nd:YAG pulse laser system at wavelength of 532 nm. The experimental results demonstrated that the optical limiting behaviors of this metal cluster are better than fullerene-C60 under both nanosecond and picosecond laser pulse excitation.

Large Nanosecond and Picosecond Optical Limiting Response of Novel Transition-Metal Planar Chalcogen Cluster Complex [WS4Cu4I2(py)6]

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Carbon nanotubes doped SiO2/SiO2–PbO double layer high emissivity coating

Enhanced optical limiting properties in a novel metallophthalocyanine complex (C12H25O)8PcPb

Large Nanosecond and Picosecond Optical Limiting Response of Novel Transition-Metal Planar Chalcogen Cluster Complex [WS4Cu4I2(py)6]