Colored wide-bandgap semiconductor oxides with abundant mid-gap states have long been regarded as promising visible light responsive photocatalysts. However, their catalytic activities are hampered by charge recombination at deep level defects, which constitutes the critical challenge to practical applications of these oxide photocatalysts. To address the challenge, a strategy is proposed here that includes creating shallow-level defects above the deep-level defects and thermal activating the migration of trapped electrons out of the deep-level defects via these shallow defects. A simple and scalable solution plasma processing (SPP) technique is developed to process the presynthesized yellow TiO2 with numerous oxygen vacancies (Ov), which incorporates hydrogen dopants into the TiO2 lattice and creates shallow-level defects above deep level of Ov, meanwhile retaining the original visible absorption of the colored TiO2. At elevated temperature, the SPP-treated TiO2 exhibits a 300 times higher conversion rate for CO2 reduction under solar light irradiation and a 7.5 times higher removal rate of acetaldehyde under UV light irradiation, suggesting the effectiveness of the proposed strategy to enhance the photoactivity of colored wide-bandgap oxides for energy and environmental applications.

https://onlinelibrary.wiley.com/doi/pdf/10.1002/advs.202000204

Enhanced Solar Photothermal Catalysis over Solution Plasma Activated TiO2

With the development of society, energy shortage and environmental problems have become more and more outstanding. Solar energy is a clean and sustainable energy resource, potentially driving energy conversion and environmental remediation reactions. Thus, solar-driven chemistry is an attractive way to solve the two problems. Photothermal chemistry (PTC) is developed to achieve full-spectral utilization of the solar radiation and drive chemical reactions more efficiently under relatively mild conditions. In this review, the mechanisms of PTC are summarized from the aspects of thermal and non-thermal effects, and then the interaction and synergy between these two effects are sorted out. In this paper, distinguishing and quantifying these two effects is discussed to understand PTC processes better and to design PTC catalysts more methodically. However, PTC is still a little far away from practical. Herein, several key points, which must be considered when pushing ahead with the engineering application of PTC, are proposed, along with some workable suggestions on the practical application. This review provides a unique perspective on PTC, focusing on the synergistic effects and pointing out a possible direction for practical application.

Photothermal Chemistry Based on Solar Energy: From Synergistic Effects to Practical Applications.

Surface modification of nano-catalyst got significant attention due its outstanding photocatalytic performance with minimum secondary pollution. Photocatalytic oxidation (PCO) is a promising technology for removing volatile organic compounds (VOCs) due...

A critical review on surface modified nano-catalysts application for photocatalytic degradation of volatile organic compounds

Recent advances in VOCs and CO removal via photothermal synergistic catalysis

Although photocatalysis has been studied for many years as an attractive way to resolve energy and environmental problems, its principle still remains unclear. Some confusions and misunderstandings...

New Insights into the Fundamental Principle of Semiconductor Photocatalysis.

Revisiting cocatalyst/TiO2 photocatalyst in blue light photothermalcatalysis

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Revisiting cocatalyst/TiO2 photocatalyst in blue light photothermalcatalysis