Removal of organic compounds by nanoscale zero-valent iron and its composites.

Construction of a visible-light-driven magnetic dual Z-scheme BiVO4/g-C3N4/NiFe2O4 photocatalyst for effective removal of ofloxacin: Mechanisms and degradation pathway

Integration of nanoscale zero-valent iron and functional anaerobic bacteria for groundwater remediation: A review.

Recent advances in nanoscale zero-valent iron-based materials: Characteristics, environmental remediation and challenges

Spontaneous-emission lifetime of Wannier excitons in mesoscopic semiconductor quantum disks

Highly efficient photocatalytic removal of multiple refractory organic pollutants by BiVO4/CH3COO(BiO) heterostructured nanocomposite.

Novel approach for preparation of three-dimensional BiOBr/BiOI hybrid nanocomposites and their removal performance of antibiotics in water

Nanoscale zero-valent iron particles have large specific surface area and high reaction activity, and have been increasingly used for the degradation of environmental contaminants. However, rapid aggregation and deactivation hinder their wide applications. In this work, nanoscale zero-valent iron (NZVI) particles were prepared in vesicles, which were formed by self-assembly of amphiphilic block copolymer poly(1-vinylpyrrolidone-co-vinylacetate) (PVV) in aqueous tetrahydrofuran medium, and characterized with the aid of XRD, FTIR, SEM-EDX, TEM, XPS and DLS techniques. It was found that the NZVI particles were well encapsulated in the vesicles, and they could be stored directly in the air as solids, but the dried NZVI particles could be easily released from the vesicles once they were put in water. These NZVI particles showed some unique features, such as uniform nanometer size distribution (from 70 to 100 nm), vesicle-like morphology, and good dispersion. Activity and stability of the NZVI in vesicles were examined by using Cr(VI) and nitrobenzene as the model pollutants, and compared with the bare NZVI particles synthesized with the same procedures but without PVV. A dramatic difference in activity and stability was observed for the two different NZVI particles. The NZVI in vesicles showed a good chemical stability in the air, and still maintained its high reactivity in water. Such excellent performance might be attributed to the encapsulation of the NZVI by vesicles, which could impede well the strong agglomeration of metal particles in water and prevent metal particles from being oxidized in the air.

Highly reactive and stable nanoscale zero-valent iron prepared within vesicles and its high-performance removal of water pollutants

The synthesis of nanoscale zero-valent iron (NZVI) nanoclusters with dimensions ranging from 20 to 100 nm for the control of environmental pollutants has received substantial attention. However, due to the strong van der Waals and magnetic attraction forces of ZVI, synthesizing ZVI nanoclusters with a subnanometre size while retaining their surface activity and avoiding aggregation is challenging. Moreover, NZVI particles can be oxidized easily after the removal of contaminants even in anoxic environments, which makes the recovery and recycling of the particles very difficult. Here, for the first time, ultra-small zero-valent iron (ZVI) nanoclusters are successfully prepared in a micelle assisted method under mild conditions, and can be recycled simply. It is found that by encapsulating Fe3+ within the micelles, controlling the release of sulfur ions (S2-) from thiourea and forming the FeS nanoparticles as intermediates, the ZVI nanoclusters are produced with a precisely controlled size (<1 nm). A large number of zero-valent iron nanoclusters were assembled into quasi-spherical assemblages (with around 5 nm size), in which most of the nanoclusters exist discretely because of being coated by entangled hydrocarbon chains of the surfactant. The ZVI nanoclusters (with a diameter of <1 nm) exhibit excellent dispersibility and accessibility in solution, presenting significantly enhanced catalytic activity in the removal of p-nitrophenol from water. The as-prepared ZVI nanoclusters possess excellent stability and durability with the aid of NaBH4. Their catalytic activity/reusability can be comparable to those of the commonly used noble metal catalysts.

Ultra-small and recyclable zero-valent iron nanoclusters for rapid and highly efficient catalytic reduction of p-nitrophenol in water

2D/2D BiOIO3/Ti3C2 MXene nanocomposite with efficient charge separation for degradation of multiple pollutants

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