Herein the design of broken gap heterojunction devices made of molybdenum trioxide and zinc phthalocyanine coated onto Al substrates are reported. The devices which are prepared by the thermal evaporation technique under vacuum pressure of 10−5 mbar are observed to exhibit a conduction and valence band offsets of 3.36 and 3.56 eV, respectively. The heterojunction devices are observed to form a subband gap of 0.66 eV between the valence bands edges of ${p-}$ ZnPc and conduction bands edges of ${p}$ -MoO3 leading to a ${p}^{+}{/}{n}^{+}$ heterojunction type. Analysis of the current- voltage characteristics of the devices has shown that it exhibits tunneling diode characteristics with maximum tunneling barriers of width of ~ 45 nm. The device displayed biasing dependent photosensitivity in response to 850 nm laser lights. In addition to its characteristics as MOS device, when it was imposed with ac signals in the frequency domain of 0.01-1.80 GHz, it displayed resonance-antiresonance phenomena accompanied with negative capacitance effect in the studied range of spectra. The analysis of the alternating current (ac) electrical conductivity has shown that the ac conduction is mostly governed by quantum mechanical tunneling assisted with correlated barriers hopping. The laser light photosensitivity, the negative capacitance effect, the capacitance switching within 100 ns and the bandpass characteristics with notch frequency of 1.24 GHz make the Al/MoO3/ZnPc/Al attractive for use as IR sensors, parasitic capacitance cancellers, fast capacitance switches and microwave bandpass filters.

Al/MoO 3 /ZnPc/Al Broken Gap Tunneling Hybrid Devices Design for IR Laser Sensing and Microwave Filtering

In this work, the effects of ytterbium substrates of thicknesses of 150 (Yb-150) and 1000 nm (Yb-1000) on the structural, optical and electrical properties of zinc phthalocyanine (ZnPc) are investigated. While the Yb-150/ZnPc exhibited strained monoclinic structure, the Yb-1000/ZnPc thin films are observed to exhibit phase transitions from monoclinic to triclinic structure. Analysis which targeted observatories of the effects of the Yb-150 substrate on the optical properties indicated that the transparent Yb-150 substrate enhanced the light absorbability by more than 11 times at 1.27 eV. On the other hand, the impedance spectroscopy measurements on the nontransparent Yb-1000/ZnPc/Ag sandwiched structures have shown that these devices could exhibit negative capacitance (NC) effect in the frequency domain of 0.244–1.800 GHz. The NC effect is associated with resonance-anti-resonance response at 0.235 and 0.244 GHz, respectively. The structural, optical and electrical properties of the Yb/ZnPc interfaces indicate its applicability as optoelectronic and/or radio/microwave components.

Ytterbium induced structural phase transitions and their effects on the optical and electrical properties of ZnPc thin films

Photoelectric properties of organic pigment zinc phthalocyanine Schottky diodes

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Photoelectric properties of organic pigment zinc phthalocyanine Schottky diodes