TEMPO was selected in 2012 by NASA as the first Earth Venture Instrument, for launch between 2018 and 2021. It will measure atmospheric pollution for greater North America from space using ultraviolet and visible spectroscopy. TEMPO observes from Mexico City, Cuba, and the Bahamas to the Canadian oil sands, and from the Atlantic to the Pacific, hourly and at high spatial resolution (~2.1 km N/S×4.4 km E/W at 36.5°N, 100°W). TEMPO provides a tropospheric measurement suite that includes the key elements of tropospheric air pollution chemistry, as well as contributing to carbon cycle knowledge. Measurements are made hourly from geostationary (GEO) orbit, to capture the high variability present in the diurnal cycle of emissions and chemistry that are unobservable from current low-Earth orbit (LEO) satellites that measure once per day. The small product spatial footprint resolves pollution sources at sub-urban scale. Together, this temporal and spatial resolution improves emission inventories, monitors population exposure, and enables effective emission-control strategies. TEMPO takes advantage of a commercial GEO host spacecraft to provide a modest cost mission that measures the spectra required to retrieve ozone (O3), nitrogen dioxide (NO2), sulfur dioxide (SO2), formaldehyde (H2CO), glyoxal (C2H2O2), bromine monoxide (BrO), IO (iodine monoxide),water vapor, aerosols, cloud parameters, ultraviolet radiation, and foliage properties. TEMPO thus measures the major elements, directly or by proxy, in the tropospheric O3 chemistry cycle. Multi-spectral observations provide sensitivity to O3 in the lowermost troposphere, substantially reducing uncertainty in air quality predictions. TEMPO quantifies and tracks the evolution of aerosol loading. It provides these near-real-time air quality products that will be made publicly available. TEMPO will launch at a prime time to be the North American component of the global geostationary constellation of pollution monitoring together with the European Sentinel-4 (S4) and Korean Geostationary Environment Monitoring Spectrometer (GEMS) instruments.

/pdf/tropospheric-emissions-monitoring-of-pollution-tempo-1d0f1osyxo.pdf

Tropospheric emissions: Monitoring of pollution (TEMPO)

. We present a new and improved version (V4.0) of the NASA standard nitrogen
dioxide (NO 2 ) product from the Ozone Monitoring Instrument (OMI) on the
Aura satellite. This version incorporates the most salient improvements for
OMI NO 2 products suggested by expert users and enhances the NO 2 
data quality in several ways through improvements to the air mass factors
(AMFs) used in the retrieval algorithm. The algorithm is based on
the geometry-dependent surface Lambertian equivalent reflectivity (GLER)
operational product that is available on an OMI pixel basis. GLER is
calculated using the vector linearized discrete ordinate radiative transfer
(VLIDORT) model, which uses as input high-resolution bidirectional
reflectance distribution function (BRDF) information from NASA's Aqua
Moderate Resolution Imaging Spectroradiometer (MODIS) instruments over land
and the wind-dependent Cox–Munk wave-facet slope distribution over water,
the latter with a contribution from the water-leaving radiance. The GLER
combined with consistently retrieved oxygen dimer (O 2 –O 2 )
absorption-based effective cloud fraction (ECF) and optical centroid
pressure (OCP) provide improved information to the new NO 2 AMF
calculations. The new AMFs increase the retrieved tropospheric NO 2 by
up to 50 % in highly polluted areas; these differences arise from both
cloud and surface BRDF effects as well as biases between the new MODIS-based
and previously used OMI-based climatological surface reflectance data sets.
We quantitatively evaluate the new NO 2 product using independent
observations from ground-based and airborne instruments. The new V4.0 data
and relevant explanatory documentation are publicly available from the NASA
Goddard Earth Sciences Data and Information Services Center ( https://disc.gsfc.nasa.gov/datasets/OMNO2_V003/summary/ , last access: 8 November 2020),
and we encourage their use over previous versions of OMI NO 2 products.

/pdf/ozone-monitoring-instrument-omi-aura-nitrogen-dioxide-4hwj0g9eqg.pdf

Ozone Monitoring Instrument (OMI) Aura nitrogen dioxide standard product version 4.0 with improved surface and cloud treatments

Tropospheric Emissions: Monitoring of Pollution (TEMPO)

Airborne and ground-based Pandora spectrometer NOspan classCombining double low line"inline-formula"2/span column measurements were collected during the 2018 Long Island Sound Tropospheric Ozone Study (LISTOS) in the New York City/Long Island Sound region, which coincided with early observations from the Sentinel-5P TROPOspheric Monitoring Instrument (TROPOMI) instrument. Both airborne- and ground-based measurements are used to evaluate the TROPOMI NOspan classCombining double low line"inline-formula"2/span Tropospheric Vertical Column (TrVC) product v1.2 in this region, which has high spatial and temporal heterogeneity in NOspan classCombining double low line"inline-formula"2/span. First, airborne and Pandora TrVCs are compared to evaluate the uncertainty of the airborne TrVC and establish the spatial representativeness of the Pandora observations. The 171 coincidences between Pandora and airborne TrVCs are found to be highly correlated (span classCombining double low line"inline-formula"ir/i2Combining double low line/spanthinsp;0.92 and slope of 1.03), with the largest individual differences being associated with high temporal and/or spatial variability. These reference measurements (Pandora and airborne) are complementary with respect to temporal coverage and spatial representativity. Pandora spectrometers can provide continuous long-term measurements but may lack areal representativity when operated in direct-sun mode. Airborne spectrometers are typically only deployed for short periods of time, but their observations are more spatially representative of the satellite measurements with the added capability of retrieving at subpixel resolutions of 250thinsp;mthinsp;span classCombining double low line"inline-formula"×/spanthinsp;250thinsp;m over the entire TROPOMI pixels they overfly. Thus, airborne data are more correlated with TROPOMI measurements (span classCombining double low line"inline-formula"ir/i2Combining double low line0.96/span) than Pandora measurements are with TROPOMI (span classCombining double low line"inline-formula"ir/i2Combining double low line0.84/span). The largest outliers between TROPOMI and the reference measurements appear to stem from too spatially coarse a priori surface reflectivity (0.5span classCombining double low line"inline-formula"g /span) over bright urban scenes. In this work, this results during cloud-free scenes that, at times, are affected by errors in the TROPOMI cloud pressure retrieval impacting the calculation of tropospheric air mass factors. This factor causes a high bias in TROPOMI TrVCs of 4thinsp;%-11thinsp;%. Excluding these cloud-impacted points, TROPOMI has an overall low bias of 19thinsp;%-33thinsp;% during the LISTOS timeframe of June-September 2018. Part of this low bias is caused by coarse a priori profile input from the TM5-MP model; replacing thesespan idCombining double low line"page6114"/ profiles with those from a 12thinsp;km North American Model-Community Multiscale Air Quality (NAMCMAQ) analysis results in a 12thinsp;%-14thinsp;% increase in the TrVCs. Even with this improvement, the TROPOMI-NAMCMAQ TrVCs have a 7thinsp;%-19thinsp;% low bias, indicating needed improvement in a priori assumptions in the air mass factor calculation. Future work should explore additional impacts of a priori inputs to further assess the remaining low biases in TROPOMI using these datasets./.

/pdf/evaluating-sentinel-5p-tropomi-tropospheric-no2-column-3hyck9e43y.pdf

Evaluating Sentinel-5P TROPOMI tropospheric NO2 column densities with airborne and Pandora spectrometers near New York City and Long Island Sound

Revisiting the effectiveness of HCHO/NO2 ratios for inferring ozone sensitivity to its precursors using high resolution airborne remote sensing observations in a high ozone episode during the KORUS-AQ campaign

. The Geostationary Trace gas and Aerosol Sensor Optimization (GeoTASO) airborne instrument is a test bed for upcoming air quality satellite instruments that will measure backscattered ultraviolet, visible and near-infrared light from geostationary orbit. GeoTASO flew on the NASA Falcon aircraft in its first intensive field measurement campaign during the Deriving Information on Surface Conditions from Column and Vertically Resolved Observations Relevant to Air Quality (DISCOVER-AQ) Earth Venture Mission over Houston, Texas, in September 2013. Measurements of backscattered solar radiation between 420 and 465 nm collected on 4 days during the campaign are used to determine slant column amounts of NO2 at 250 m  ×  250 m spatial resolution with a fitting precision of 2.2 × 1015 molecules cm−2. These slant columns are converted to tropospheric NO2 vertical columns using a radiative transfer model and trace gas profiles from the Community Multiscale Air Quality (CMAQ) model. Total column NO2 from GeoTASO is well correlated with ground-based Pandora observations (r = 0.90 on the most polluted and cloud-free day of measurements and r = 0.74 overall), with GeoTASO NO2 slightly higher for the most polluted observations. Surface NO2 mixing ratios inferred from GeoTASO using the CMAQ model show good correlation with NO2 measured in situ at the surface during the campaign (r = 0.85). NO2 slant columns from GeoTASO also agree well with preliminary retrievals from the GEO-CAPE Airborne Simulator (GCAS) which flew on the NASA King Air B200 (r = 0.81, slope = 0.91). Enhanced NO2 is resolvable over areas of traffic NOx emissions and near individual petrochemical facilities.

/pdf/nitrogen-dioxide-observations-from-the-geostationary-trace-3njoyn8vcq.pdf

Nitrogen dioxide observations from the Geostationary Trace gas and Aerosol Sensor Optimization (GeoTASO) airborne instrument: Retrieval algorithm and measurements during DISCOVER-AQ Texas 2013

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Nitrogen dioxide observations from the Geostationary Trace gas and Aerosol Sensor Optimization (GeoTASO) airborne instrument: Retrieval algorithm and measurements during DISCOVER-AQ Texas 2013