Froth flotation of fluorite: A review.

Flotation separation of fluorite from calcite by using psyllium seed gum as depressant

Studies on the selective flotation of pyrite from fine serpentine by using citric acid as depressant

Clean utilization of waste oil: Soap collectors prepared by alkaline hydrolysis for fluorite flotation

In industrial practice, hydrodynamic cavitation (HC) is commonly triggered by jetting either reagent solution or pulp. Although both methods can enhance mineral flotation, are their roles the same? There are few research studies in the field, which severely limits our understanding on mineral flotation combined with HC. Therefore, in this study, the flotation of ultrafine scheelite with HC pretreatments of reagent solution and pulp (abbreviated to be HCPS and HCPP, respectively) was studied and compared through flotation tests, zeta potential analysis, microscope tests, and shear yield stress measurements. The results of flotation tests show that both HCPS and HCPP can enhance the final flotation performance, but in general, HCPP leads to greater improvements on the final flotation recovery. The presence of (hydrophobized) scheelite particles brings extra gas nuclei for the cavitation–flotation system, suggesting that more NBs may be produced in the case of HCPP compared with HCPS. These tiny bubbles remarkably reduce the size distribution of bubbles in the flotation system, thus increasing the particle–bubbles collision probability. Increase in particle aggregation may be another reason why flotation with HCPP results in a higher flotation recovery. The adherence of NBs on hydrophobized particles decreases the (absolute) surface charge of the solids, resulting in a smaller repulsive force among particles and more significant particle aggregation, which is confirmed by the microscope tests and shear yield stress measurements.

https://www.mdpi.com/2075-163X/8/7/264/pdf

Different Flotation Performance of Ultrafine Scheelite under Two Hydrodynamic Cavitation Modes

Fluorite is the principal mineral of fluorine and usually coexists with quartz in deposits. The removal of fine quartz in fluorite concentrate is the main problem in fluorite flotation. In this study, the flotation tests on fluorite, quartz and a weight equivalent mixture (all less than 10 μm) using water glass (with different modulus) as depressants and sodium oleate as collector were conducted. The mechanism of fine quartz entering the fluorite concentrate was investigated through optional observations and rheology measurements on the flotation pulp. The particle interactions between fine fluorite and quartz under flotation-related conditions were analyzed through zeta potential measurements and DLVO calculations. The results revealed that there existed strong hetero-coagulation between fluorite and quartz particles in the flotation pulp, which could be the main reason for the quartz entering the fluorite concentrate in the flotation process. Water glass with higher modulus could eliminate the hetero-coagulation more totally but inevitably influences the flotability of fluorite.

https://www.mdpi.com/2075-163X/7/9/157/pdf

The Role of Water Glass in the Flotation Separation of Fine Fluorite from Fine Quartz

A novel method to limit the adverse effect of fine serpentine on the flotation of pyrite was investigated in this paper. The flotation results showed that coarser serpentine possessed a weaker depression effect on the pyrite flotation process, and the use of KAl(SO4)2·12H2O could efficiently limit the detrimental effect of fine serpentine on pyrite with a maximum increase of pyrite recovery from 14% to 86% at pH 9.0. The results of particle size measurements and rheological measurements exhibited that the addition of KAl(SO4)2·12H2O increased the particle size of serpentine buta hrdly affected the particle size of pyrite, then limited the formation of serpentine-pyrite aggregates. Adsorption test results showed that the adsorption density of potassium butyl xanthate (PBX) onto pyrite regained with the addition of KAl(SO4)2·12H2O, thereby achieving good flotation improvement. It can be concluded that KAl(SO4)2·12H2O is likely to be an effective pyrite flotation reagent, especially in the presence of fine serpentine.

A Novel Method to Limit the Adverse Effect of Fine Serpentine on the Flotation of Pyrite

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The Role of Water Glass in the Flotation Separation of Fine Fluorite from Fine Quartz

A Novel Method to Limit the Adverse Effect of Fine Serpentine on the Flotation of Pyrite