Interpretation of impedance spectroscopy data requires both a description of the chemistry and physics that govern the system and an assessment of the error structure of the measurement. The approach presented here includes use of graphical methods to guide model development, use of a measurement model analysis to assess the presence of stochastic and bias errors, and a systematic development of interpretation models in terms of the proposed reaction mechanism and physical description. Application to corrosion, batteries, and biological systems is discussed, and emerging trends in interpretation and implementation of impedance spectroscopy are presented.

Impedance Analysis of Electrochemical Systems.

https://hal.science/hal-03719396/document

A new look on the corrosion mechanism of magnesium: an EIS investigation at different pH

Electrical impedance measurements for detecting artificial chemical additives in liquid food products

Titanium dioxide (TiO2) and aluminum oxide (Al2O3) coatings have been investigated in a wide range of bio-applications due to their biodegradation and biocompatibility properties, that are key parameters for their use in the food packaging and biomedical devices fields. The present study evaluates and compares the electrochemical behavior of the non-coated, commercial resin-coated, TiO2-coated and Al2O3-coated aluminum in commercial beer electrolyte. For this, TiO2 and Al2O3 thin films were deposited on aluminum (Al) substrates using atomic layer deposition (ALD). The evaluation of the corrosion barrier layer properties was performed by linear sweep voltammetry (LSV) during 10 min and electrochemical impedance spectroscopy (EIS). In addition, profilometry, grazing incidence X-ray diffractometry (GIXRD), scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FT-IR) analyses were performed to investigate the physical and chemical properties of the pristine and / or corroded samples. TiO2 and Al2O3 films presented an amorphous structure, a morphology that follows Al substrate surface, and a thickness of around 100 nm. Analysis of LSV data showed that ALD coatings promoted a considerable increase in corrosion barrier efficiency being 86.3% for TiO2-coated Al and 80% for Al2O3-coated Al in comparison with 7.1% of commercial resin-coated Al. This is mainly due to the lower electrochemical porosity, 11.4% for TiO2-coated Al and 20.4% for Al2O3-coated Al in comparison with 96% of the resin-coated Al, i.e. an increase of up to twofold in the protection of Al when coated with TiO2 compared to Al2O3. The EIS results allow us to complement the discussions about the reduced corrosion barrier efficiency of the Al2O3 film for beer electrolyte once SEM and FT-IR analyzes did not show drastic changes in both investigated ALD films after the corrosion assays. The above results indicate that ALD TiO2 and Al2O3 films may be a viable alternative to replace the synthetic resin coatings frequently used in aluminum cans of use in the food industry.

https://www.mdpi.com/1996-1944/12/4/682/pdf

Atomic Layer Deposited TiO2 and Al2O3 Thin Films as Coatings for Aluminum Food Packaging Application

The paper presents a coaxial-like sensor operating in the 20 Hz–2 MHz frequency range used to determine the electrical properties of selected liquids of low electrical conductivity. Examined materials included low-concentrated aqueous solutions of potassium chloride, sodium chloride and trisodium citrate, which are common food additives. Impedance spectra of the measurement cell filled with particular liquids were obtained and analyzed using the electrical equivalent circuit approach. The values of physical quantities and parameters describing the equivalent circuit components, including a constant phase element, were calculated for each sample. The applied sensor was also calibrated for electrical conductivity measurements up to 8 mS/m. The constant phase element parameters differed among the studied solutions and concentrations. This may provide a basis for a detection method of small amounts of compounds, such as food additives in low-concentrated aqueous solutions. To demonstrate the potential of the presented method, samples of purchased mineral water and a flavored drink containing various additives were tested.

Application of a coaxial-like sensor for impedance spectroscopy measurements of selected low-conductivity liquids.

Identification of reaction mechanism for anodic dissolution of metals using Electrochemical Impedance Spectroscopy

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Identification of reaction mechanism for anodic dissolution of metals using Electrochemical Impedance Spectroscopy