Light-Emitting Self-Assembled Materials Based on d(8) and d(10) Transition Metal Complexes.

Photoluminescence Properties of Multinuclear Copper(I) Compounds.

Relatively little attention has been paid to metal ions with the nd[sup 10] and nd[sup 10](n+1)s[sup 2] (i.e., [open quotes]s[sup 2][close quotes]) configurations. In combination with various anionic and neutral ligands, these metal ions form a wide variety of cluster compounds, some of which have been known to be luminescent when irradiated with ultraviolet light. Prominent examples of this family are cuprous iodide clusters such as Cu[sub 4]I[sub 4]-(py)[sub 4] (1, py = pyridine), which shows [open quotes]luminescence thermochromism[close quotes]; that is, they display bright emissions with colors markedly dependent on the temperature. Here the authors present an overview of recent studies carried out both independently and jointly in the authors' laboratories focusing upon the remarkably rich, but relatively unexplored, photochemical and photophysical properties of various tetra-and hexanuclear d[sup 10] and s[sup 2] metal ion clusters in solution. 74 refs., 4 figs., 2 tabs.

/pdf/photochemical-and-photophysical-properties-of-tetranuclear-vka15ses5b.pdf

Photochemical and photophysical properties of tetranuclear and hexanuclear clusters of metals with d10 and s2 electronic configurations

Lanthanide induced shifts and relaxation rate enhancements

Structures of high coordination complexes

/pdf/structural-studies-on-the-rare-earth-carboxylates-4-the-2py6dui94l.pdf

Structural Studies on the Rare Earth Carboxylates. 4. The Crystal and Molecular Structure of Orthorhombic Trisodium Tris(pyridine-2,6-dicarboxylato)ytterbiumate(III)-14-hydrate.

X-Ray Investigations of the Tin-Phosphorus System.

/pdf/the-crystal-and-molecular-structure-of-the-copper-i-8jq0k2gxh3.pdf

The Crystal and Molecular Structure of the Copper(I) Dipropylthiocarbamate Hexamer.

/pdf/the-crystal-structure-of-zirconium-cupferrate-zr-c6h5n2o2-4-34tl6pbbcc.pdf

The Crystal Structure of Zirconium Cupferrate, Zr(C6H5N2O2)4.

/pdf/enthalpies-of-mixing-in-liquid-mixtures-of-lithium-sulphate-3ig7x02m4g.pdf

Enthalpies of Mixing in Liquid Mixtures of Lithium Sulphate and Sodium Sulphate.

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