Azaindole derivatives with high affinity for the dopamine D4 receptor: synthesis, ligand binding studies and comparison of molecular electrostatic potential maps.

Rh(III)-Catalyzed Oxidative Annulation Leading to Substituted Indolizines by Cleavage of C(sp(2))-H/C(sp(3))-H Bonds.

The Cu-catalyzed three-component reaction between quinolines, diazo compounds, and alkenes has been established for direct construction of indolizine derivatives via quinolinium ylides. This methodology is distinguished by the use of a commercially inexpensive catalyst and readily available starting materials, wide substrate scope, and operational simplicity.

In Situ Generation of Quinolinium Ylides from Diazo Compounds: Copper-Catalyzed Synthesis of Indolizine.

Three COming together: The first carbonylative Heck coupling reaction of aryl bromides and vinyl ethers leading to 1-aryl-3-alkoxy-2-propen-1-ones has been established (see scheme). Based on this coupling methodology, a novel one-pot synthesis of aryl-substituted pyrazoles was also realized.

Palladium‐Catalyzed Carbonylative Heck Reaction of Aryl Bromides with Vinyl Ethers to 3‐Alkoxy Alkenones and Pyrazoles

Reactions of pyridinium n-ylides and their related pyridinium salts

Polarized ethylene. V. Synthesis of 1-substituted indolizine, pyrazolo[1,5-a]pyridine, and their related compounds using methoxyethylene derivatives

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Polarized ethylene. V. Synthesis of 1-substituted indolizine, pyrazolo[1,5-a]pyridine, and their related compounds using methoxyethylene derivatives