Tom Nijbacker
VU University Amsterdam
15 Papers
153 Citations
Tom Nijbacker is an academic researcher from VU University Amsterdam. The author has contributed to research in topics: Phosphinidene & Dehydrohalogenation. The author has an hindex of 8, co-authored 14 publications. Previous affiliations of Tom Nijbacker include Utrecht University.
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Papers
Synthesis of Novel Terminal Iridium Phosphinidene Complexes
TL;DR: Stable, crystalline iridium-complexed phosphinidenes, Cp*(L)IrPR, are readily synthesized by using LiPHMes* and dehydrohalogenation of Cp(PH2R)IrCl2 (5, R = Mes*, Is, Mes) with in situ capturing of transient Cp*,Ir⋮PR (4) with phosphines, phosphites, arsines, isocyanides, and carbon monoxide as mentioned in this paper.
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Synthesis and Reactions of Terminal Osmium and Ruthenium Complexed Phosphinidenes [(η6-Ar)(L)MPMes*]
TL;DR: In this article, very stable ruthenium and osmium containing terminal phosphinidene complexes were obtained by dehydrohalogenation in the presence of a stabilizing ligand.
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The 2-Vinylphosphirane−3-Phospholene Rearrangement: Biradicaloid and Concerted Features
M. J. Van Eis,Tom Nijbacker,F. J. J. De Kanter,W. H. De Wolf,Koop Lammertsma,F.M. Bickelhaupt +5 more
TL;DR: In this paper, the 2-vinylphosphirane−3-phospholene rearrangement in the cycloheptane annellated series 7 → 8 was studied.
24
Introduction of Bulky Substituents at the Bridgehead Position of a 9-Silatriptycene: Pentacoordinate Hydridoorganylsilicates as Intermediates
TL;DR: The reaction of 10-phenyl-10-germa-9-silatriptycene (1b) with phenyllithium in THF/HMPA produced 9,10-diphenyl- 10-germma- 9-silatio-nictycenes (1a), which had hitherto not been accessible as discussed by the authors.
23
Generating and Dimerizing the Transient 16-Electron Phosphinidene Complex [Cp*Ir=PAr]: A Theoretical and Experimental Study
Arjan T. Termaten,Tom Nijbacker,Andreas W. Ehlers,Marius Schakel,Martin Lutz,Anthony L. Spek,Michael L. McKee,Koop Lammertsma +7 more
TL;DR: Density functional theory calculations show a preferred bent geometry for the model complex [CpIr=PH], in contrast to the linear structure of [C pIr=NH], which arises because of the large steric congestion in [[Cp*Ir=PAr]2], which forces it toward a more reactive planar structure that is apt to rearrange.