Tao Wang
Lanzhou University
4 Papers
101 Citations
Tao Wang is an academic researcher from Lanzhou University. The author has contributed to research in topics: Diastereomer & Cryptophane. The author has an hindex of 4, co-authored 4 publications.
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Papers
Tribenzotriquinacenes bearing six-fold benzofuran extensions: electron-rich C3v-symmetrical hosts for C60.
TL;DR: New tribenzotriquinacene hosts bearing six-fold peripheral benzofuran functionalization have been synthesized and were shown to operate optically independently and to generate deeply bowl-shaped C(3v)-symmetrical frameworks that act as relatively weak hosts toward C(60), as revealed by (1)H NMR spectroscopy.
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Tribenzotriquinacenes based on regioselective bis-formylation: optical resolution and absolute configuration of inherently chiral derivatives and synthesis of the first cyclophane-type tribenzotriquinacene dimers.
TL;DR: Enantiomers of TBTQs bearing two monofunctionalized aromatic nuclei were synthesized for the first time and their optical properties and absolute configuration determined and the usefulness of such thiacyclophanes as fluorescent chemosensors for different metal ions is demonstrated.
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Synthesis and optical resolution of inherently chiral difunctionalized tribenzotriquinacenes.
TL;DR: Efficient access to enantiopure, inherently chiral tribenzotriquinacenes may lay a foundation for studies of novel container compounds, supramolecular aggregation, chiral recognition, and asymmetric catalysis.
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C3-symmetrical tribenzotriquinacene derivatives: optical resolution through cryptophane synthesis and supramolecular self-assembly into nanotubes.
TL;DR: Based on a regioselective tris-formylation of a tribenzotriquinacene hydrocarbon, the racemic C(3)-symmetrical T BTQ-trialdehyde and the corresponding TBTQ-trimethanol were synthesized along with their C(1)-isomers.