Lithium metal batteries (LMBs) are one of the most promising energy storage technologies that would overcome the limitations of current Li‐ion batteries, based on their low density (0.534 g cm−3), low reduction potential (−3.04 V vs Standard Hydrogen Electrode) as well as their high theoretical capacities (3860 mAh g−1 and 2061 mAh cm−3). The overall cell mass and volume would be reduced while both gravimetric and volumetric energy densities would be greatly improved. Their electrochemical performance, however, is hampered by the low efficiency at high current densities and continuous degradation, which are related, among other factors, to the properties of the lithium metal anode (LMA). Hence, the production and processing of LMAs is crucial to obtain the desired properties that would enable LMBs. Here, the conventional method used for the production of LMAs, which is the combination of extraction, electrowinning, extrusion, and rolling processes, is reviewed. Then, the advances in the different alternative methods that can be used to produce and improve the properties of LMAs are described, which are divided into vapor phase, liquid phase, and electrodeposition. Within this last method, the anode‐less concept, for which different approaches to the development of advanced current collectors are illustrated, is included.

https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/aenm.202203744

Current Status and Future Perspective on Lithium Metal Anode Production Methods

Abstract Current polyamide lithium extraction nanofiltration membranes are susceptible to chlorine degradation and/or low permeance, two problems that are hard to reconcile. Here we simultaneously circumvented these problems by designing a quaternized-spiro piperazine monomer and translating its beneficial properties into large-area membranes (1 × 2 m 2 ) via interfacial polymerization with trimesoyl chloride. The quaternary ammonium and spiral conformation of the monomer confer more positive charge and free volume to the membrane, leading to one of the highest permeance (~22 L m −2 h −1 bar −1 ) compared to the state-of-the-art Mg 2+ /Li + nanofiltration membranes. Meanwhile, membrane structures are chlorine resistant as the amine–acyl bonding contains no sensitive N-H group. Thus the high performance of membrane is stable versus 400-h immersion in sodium hypochlorite, while control membranes degraded readily. Molecular simulations show that the high permeance and chlorine resistance, which were reproducible at the membrane module level, arise from the spiral conformation and secondary amine structures of the monomer. 

pdf/quaternization-spiro-design-of-chlorine-resistant-and-high-23l5ldz2t7.pdf

Quaternization-spiro design of chlorine-resistant and high-permeance lithium separation membranes

Recent progress on key materials and technical approaches for electrochemical lithium extraction processes

Abstract The demand for lithium extraction from salt-lake brines is increasing to address the lithium supply shortage. Nanofiltration separation technology with high Mg 2+ /Li + separation efficiency has shown great potential for lithium extraction. However, it usually requires diluting the brine with a large quantity of freshwater and only yields Li + -enriched solution. Inspired by the process of selective ion uptake and salt secretion in mangroves, we report here the direct extraction of lithium from salt-lake brines by utilizing the synergistic effect of ion separation membrane and solar-driven evaporator. The ion separation membrane-based solar evaporator is a multilayer structure consisting of an upper photothermal layer to evaporate water, a hydrophilic porous membrane in the middle to generate capillary pressure as the driving force for water transport, and an ultrathin ion separation membrane at the bottom to allow Li + to pass through and block other multivalent ions. This process exhibits excellent lithium extraction capability. When treating artificial salt-lake brine with salt concentration as high as 348.4 g L −1 , the Mg 2+ /Li + ratio is reduced by 66 times (from 19.8 to 0.3). This research combines ion separation with solar-driven evaporation to directly obtain LiCl powder, providing an efficient and sustainable approach for lithium extraction. 

Solar-driven membrane separation for direct lithium extraction from artificial salt-lake brine

Doping engineering of lithium-aluminum layered double hydroxides for high-efficiency lithium extraction from salt lake brines

Abstract Microporous organic nanotubes (MONs) hold considerable promise for designing molecular-sieving membranes because of their high microporosity, customizable chemical functionalities, and favorable polymer affinity. Herein, we report the use of MONs derived from covalent organic frameworks to engineer 15-nm-thick microporous membranes via interfacial polymerization (IP). The incorporation of a highly porous and interpenetrated MON layer on the membrane before the IP reaction leads to the formation of polyamide membranes with Turing structure, enhanced microporosity, and reduced thickness. The MON-modified membranes achieve a remarkable water permeability of 41.7 L m −2 h −1 bar −1 and high retention of boron (78.0%) and phosphorus (96.8%) at alkaline conditions (pH 10), surpassing those of reported nanofiltration membranes. Molecular simulations reveal that introducing the MONs not only reduces the amine molecule diffusion toward the organic phase boundary but also increases membrane porosity and the density of water molecules around the membrane pores. This MON-regulated IP strategy provides guidelines for creating high-permeability membranes for precise nanofiltration. 

/pdf/microporous-organic-nanotube-assisted-design-of-high-23udezfh.pdf

Microporous organic nanotube assisted design of high performance nanofiltration membranes

Metal-based adsorbents for lithium recovery from aqueous resources

Membrane filtration has been widely adopted in various water treatment applications, but its use in selective solute separation for resource extraction and recovery is an emerging research area. When a membrane process is applied for solute–solute separation to extract solutes as the product, the performance metrics and process optimization strategies should differ from a membrane process for water production because the separation goals are fundamentally different. Here we used lithium (Li) magnesium (Mg) separation as a representative solute–solute separation to illustrate the deficiency of existing performance evaluation framework developed for water–solute separation using nanofiltration (NF). We performed coupon- and module-scale analyses of mass transfer to elucidate how membrane properties and operating conditions affect the performance of Li/Mg separation in NF. Notably, we identified an important operational trade-off between Li/Mg selectivity and Li recovery, which is critical for process optimization. We also established a new framework for evaluating membrane performance based on the success criteria of Li purity and recovery and further extended this framework to separation with the target ions in the brine. This analysis lays the theoretical foundation for performance evaluation and process optimization for NF-based selective solute separation. Membranes can be used not only for water filtration but also for solute–solute separation. Using the separation between lithium and magnesium, this analysis provides a platform for evaluating the performance of nanofiltration-based selective solute separation. 

/pdf/performance-metrics-for-nanofiltration-based-selective-147vr8wb.pdf

Performance metrics for nanofiltration-based selective separation for resource extraction and recovery

Field-scale fluorescence fingerprints of biochar-derived dissolved organic matter (DOM) provide an effective way to trace biochar migration and the downward co-migration of Pb, Cu and As in soil.

Stability of layer-by-layer nanofiltration membranes in highly saline streams

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