: The unpolarized absorption and circular dichroism spectra of the fundamental vibrational transitions of the chiral molecule, 4-methyl-2-oxetanone, are calculated ab initio. Harmonic force fields are obtained using Density Functional Theory (DFT), MP2, and SCF methodologies and a 5S4P2D/3S2P (TZ2P) basis set. DFT calculations use the Local Spin Density Approximation (LSDA), BLYP, and Becke3LYP (B3LYP) density functionals. Mid-IR spectra predicted using LSDA, BLYP, and B3LYP force fields are of significantly different quality, the B3LYP force field yielding spectra in clearly superior, and overall excellent, agreement with experiment. The MP2 force field yields spectra in slightly worse agreement with experiment than the B3LYP force field. The SCF force field yields spectra in poor agreement with experiment.The basis set dependence of B3LYP force fields is also explored: the 6-31G* and TZ2P basis sets give very similar results while the 3-21G basis set yields spectra in substantially worse agreements with experiment. jg

Ab initio calculation of vibrational absorption and circular dichroism spectra using density functional force fields

A fast-Fourier-transform method of topography and interferometry is proposed. By computer processing of a noncontour type of fringe pattern, automatic discrimination is achieved between elevation and depression of the object or wave-front form, which has not been possible by the fringe-contour-generation techniques. The method has advantages over moire topography and conventional fringe-contour interferometry in both accuracy and sensitivity. Unlike fringe-scanning techniques, the method is easy to apply because it uses no moving components.

Fourier-transform method of fringe-pattern analysis for computer-based topography and interferometry

Orbital angular momentum (OAM), which describes the “phase twist” (helical phase pattern) of light beams, has recently gained interest due to its potential applications in many diverse areas. Particularly promising is the use of OAM for optical communications since: (i) coaxially propagating OAM beams with different azimuthal OAM states are mutually orthogonal, (ii) inter-beam crosstalk can be minimized, and (iii) the beams can be efficiently multiplexed and demultiplexed. As a result, multiple OAM states could be used as different carriers for multiplexing and transmitting multiple data streams, thereby potentially increasing the system capacity. In this paper, we review recent progress in OAM beam generation/detection, multiplexing/demultiplexing, and its potential applications in different scenarios including free-space optical communications, fiber-optic communications, and RF communications. Technical challenges and perspectives of OAM beams are also discussed.

Optical communications using orbital angular momentum beams

Thirty years ago, Coullet et al. proposed that a special optical field exists in laser cavities bearing some analogy with the superfluid vortex. Since then, optical vortices have been widely studied, inspired by the hydrodynamics sharing similar mathematics. Akin to a fluid vortex with a central flow singularity, an optical vortex beam has a phase singularity with a certain topological charge, giving rise to a hollow intensity distribution. Such a beam with helical phase fronts and orbital angular momentum reveals a subtle connection between macroscopic physical optics and microscopic quantum optics. These amazing properties provide a new understanding of a wide range of optical and physical phenomena, including twisting photons, spin-orbital interactions, Bose-Einstein condensates, etc., while the associated technologies for manipulating optical vortices have become increasingly tunable and flexible. Hitherto, owing to these salient properties and optical manipulation technologies, tunable vortex beams have engendered tremendous advanced applications such as optical tweezers, high-order quantum entanglement, and nonlinear optics. This article reviews the recent progress in tunable vortex technologies along with their advanced applications.

/pdf/optical-vortices-30-years-on-oam-manipulation-from-2yknluuuga.pdf

Optical vortices 30 years on: OAM manipulation from topological charge to multiple singularities

Microneedles for drug and vaccine delivery.

Vector vortex beams, such as a radially or azimuthally polarized beam, have been widely investigated in many applications, including acceleration techniques [1] , high resolution microscopy [2] , materials processing [3] , [4] , and particle guiding or trapping [5] . The wavelength versatility of the vector vortex laser sources is strongly desired to explore these applications.

Radially polarized solid-state Raman laser

Ablation phenomena by intense terahertz vortex beam

High-Power, High-Quality Pico-Second Holographic Lasers Based on A Photorefractive Phase Conjugate Mirrors

Handedness control of the mid-infrared vortex output from a ZnGeP2 difference frequency generator pumped by a 1-μm vortex pumped KTiOPO4 optical parametric oscillator was demonstrated over a frequency range of 9–12 μm.

Handedness control of mid-infrared (9–12μm) vortex laser

Structured lights enable us to chiral nanostructures formed of a variety of materials, for instance, metal, silicon, and polymers. Such chiral nanostructures will provide us advanced chiral photonics devices, such as plasmonic metasurfaces for chiral chemical detection and reaction, and optical polarization rotators in the mid-IR or terahertz region.

Optical Angular Momentum Structures Chiral Materials and Devices

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