Systematical study on the roles of transition alloying substitutions on anti-disproportionation reaction of ZrCo during charging and releasing hydrogen

The photocatalytic conversion of carbon dioxide into fuels and valuable chemicals is a promising avenue to address the challenge of environmental change. Plasma treatment as a popular and effective method to prepare and modify materials based on its ultra-high energy and efficiency has attracted significant attention. In this study, abundant Bi quantum dots (Bi QDs) are reduced in situ on the surface of black Bi2WO6 nanosheets using an effective dielectric barrier discharge (DBD) plasma technology. The reduction of Bi QDs leads to the generation of a large number of unsaturated coordination atoms, which improves the light absorption performance of Bi2WO6. Benefiting from the unique interface design, black Bi2WO6 shows superior CO generation rate, roughly threefold higher than that of pristine Bi2WO6 nanosheets. Our work provides new insights and can be a reference in plasma modification engineering of catalyst surfaces and photoreduction of CO2.

Plasma-induced black bismuth tungstate as a photon harvester for photocatalytic carbon dioxide conversion

Tailoring the hydrogen transport properties of highly permeable Nb51W5Ti23Ni21 alloy membrane by Pd substitution

Reactive Magnetron Sputtering to Enhance the Hydrogen Permeation Performance of Nbc/V Composite Membranes

In this work, Pd-Ru-In membranes were prepared by electroless co-deposition and characterized by SEM, XRD, XPS, AES and hydrogen permeation test. The results show that defect-free 5–6 μm thick Pd-Ru-In membrane with homogeneous element distribution was successfully prepared. The composition of the membrane is Pd-Ru0.5at%-In1at% (M1) and Pd-Ru0.5at%-In2at% (M2), respectively. The hydrogen permeability of the membrane M2 reaches 1.32 × 10-8 mol·m−1·s−1·Pa−0.5 at 773 K, which is 1.6 times higher than that of a Pd-Ru0.5at% membrane prepared under the same conditions. The addition of the element In leads to a structural evolution of the membrane: the lattice parameters of the Pd-Ru-In membranes increase. This lattice expansion results in an improvement in the hydrogen permeability. Our study provides a useful reference for the fabrication of Pd-Ru-In ternary membranes with high hydrogen permeability. 

High hydrogen permeability of Pd-Ru-In membranes prepared by electroless co-deposition

Effects of doping with a third element (Pd, Ru, Ta) on the structure and hydrogen permeation properties of V–10Mo solid solutions

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Effects of doping with a third element (Pd, Ru, Ta) on the structure and hydrogen permeation properties of V–10Mo solid solutions