T. V. Demeshchik
A. N. Nesmeyanov Institute of Organoelement Compounds
8 Papers
22 Citations
T. V. Demeshchik is an academic researcher from A. N. Nesmeyanov Institute of Organoelement Compounds. The author has contributed to research in topics: Diastereomer & Palladium. The author has an hindex of 3, co-authored 8 publications.
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Papers
Optically active (2-aminomethylferrocenyl) phosphines with the phosphorus chiral center
TL;DR: In this paper, an enantiomeric planar-chiral palladium derivative of dimethyl-aminomethylferrocene with PhMePLi in THF at room temperature afforded a 1.5∶1.0 mixture of diastereomeric aminophosphines containing the phosphorus asymmetrical center along with a chiral plane.
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Synthetic approaches to trialkyl(ferrocenylmethyl)ammonium salts as cationic templates for the preparation of ferromagnets on the basis of bimetal oxalates
TL;DR: In this article, a trialkyl(ferrocenylmethyl)ammonium salts and their 2-substituted analogs designed for the preparation of molecular ferromagnetics based on bimetallic oxalates were synthesized using classical alkylation of dialkylaminomethylferrocenes by alkyl halides and nucleophilic substitution reaction of 2-saturated dimethylaminometric methiodides with trialkylamines.
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Synthesis and electrochemical properties of mono- and (±)-1,2-dialkylferrocenes and alkylferrocenium hexafluorophosphates in aqueous and micellar media
M. A. Bazhenova,S. S. Bogush,A. G. Herbst,T. V. Demeshchik,Yu. G. Komarovskaya,V. S. Kurova,Marina D. Reshetova,Marina D. Reshetova,Alexander D. Ryabov,Alexander D. Ryabov,Ekaterina S. Ryabova,Yu. N. Frrsova +11 more
TL;DR: In this article, simple methods have been developed for the preparation of a series of n-alkylferrocenes H(CH2)====== n====== Fc (n = 3, 5, 8, or 12) based on Friedel-Crafts acylation of ferrocenes followed by reduction of the corresponding ketones with Zn amalgam.
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Diatomic phenols as nucleophilic components in the carbonylation of the chelated C,N-palladacycle of the ferrocene series
TL;DR: The carbonylation of the chelated palladium derivative of dimethylaminoferrocene in the presence of diatomic phenols affords mixtures of the corresponding mono-and diacylated dihydroxybenzenes containing a 2-dimethylamine fragment in the acyl moiety.
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Stereochemical control in reactions of chiral ketone with 2-lithiated substituted ferrocene derivatives
L. L. Troitskaya,T. V. Demeshchik,S. T. Ovseenko,Zoya A. Starikova,Viatcheslav I. Sokolov,B. Malezieux,Michel Gruselle +6 more
TL;DR: The formation of a new chiral center in the reactions of ketone 4-MeOC6H4CH(Et)C(O)Et with planar-chiral 2-lithio-1-methyl- and 1-chloro-2-Lithioferrocenes was studied in this article.
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