'Bottom-up fabrication', which exploits the intrinsic properties of atoms and molecules to direct their self-organization, is widely used to make relatively simple nanostructures. A key goal for this approach is to create nanostructures of high complexity, matching that routinely achieved by 'top-down' methods. The self-assembly of DNA molecules provides an attractive route towards this goal. Here I describe a simple method for folding long, single-stranded DNA molecules into arbitrary two-dimensional shapes. The design for a desired shape is made by raster-filling the shape with a 7-kilobase single-stranded scaffold and by choosing over 200 short oligonucleotide 'staple strands' to hold the scaffold in place. Once synthesized and mixed, the staple and scaffold strands self-assemble in a single step. The resulting DNA structures are roughly 100 nm in diameter and approximate desired shapes such as squares, disks and five-pointed stars with a spatial resolution of 6 nm. Because each oligonucleotide can serve as a 6-nm pixel, the structures can be programmed to bear complex patterns such as words and images on their surfaces. Finally, individual DNA structures can be programmed to form larger assemblies, including extended periodic lattices and a hexamer of triangles (which constitutes a 30-megadalton molecular complex).

/pdf/folding-dna-to-create-nanoscale-shapes-and-patterns-1liv7u73y0.pdf

Folding DNA to create nanoscale shapes and patterns

There has been an intensive search for cost-effective photovoltaics since the development of the first solar cells in the 1950s. [1–3] Among all alternative technologies to silicon-based pn-junction solar cells, organic solar cells could lead the most significant cost reduction. [4] The field of organic photovoltaics (OPVs) comprises organic/inorganic nanostructures like dyesensitized solar cells, multilayers of small organic molecules, and phase-separated mixtures of organic materials (the bulkheterojunction solar cell). A review of several OPV technologies has been presented recently. [5] Light absorption in organic solar cells leads to the generation of excited, bound electron– hole pairs (often called excitons). To achieve substantial energy-conversion efficiencies, these excited electron–hole pairs need to be dissociated into free charge carriers with a high yield. Excitons can be dissociated at interfaces of materials with different electron affinities or by electric fields, or the dissociation can be trap or impurity assisted. Blending conjugated polymers with high-electron-affinity molecules like C60 (as in the bulk-heterojunction solar cell) has proven to be an efficient way for rapid exciton dissociation. Conjugated polymer–C60 interpenetrating networks exhibit ultrafast charge transfer (∼40 fs). [6,7] As there is no competing decay process of the optically excited electron–hole pair located on the polymer in this time regime, an optimized mixture with C60 converts absorbed photons to electrons with an efficiency close to 100%. [8] The associated bicontinuous interpenetrating network enables efficient collection of the separated charges at the electrodes. The bulk-heterojunction solar cell has attracted a lot of attention because of its potential to be a true low-cost photovoltaic technology. A simple coating or printing process would enable roll-to-roll manufacturing of flexible, low-weight PV modules, which should permit cost-efficient production and the development of products for new markets, e.g., in the field of portable electronics. One major obstacle for the commercialization of bulk-heterojunction solar cells is the relatively small device efficiencies that have been demonstrated up to now. [5] The best energy-conversion efficiencies published for small-area devices approach 5%. [9–11] A detailed analysis of state-of-the-art bulk-heterojunction solar cells [8] reveals that the efficiency is limited by the low opencircuit voltage (Voc) delivered by these devices under illumination. Typically, organic semiconductors with a bandgap of about 2 eV are applied as photoactive materials, but the observed open-circuit voltages are only in the range of 0.5–1 V. There has long been a controversy about the origin of the Voc in conjugated polymer–fullerene solar cells. Following the classical thin-film solar-cell concept, the metal–insulator–metal (MIM) model was applied to bulk-heterojunction devices. In the MIM picture, Voc is simply equal to the work-function difference of the two metal electrodes. The model had to be modified after the observation of the strong influence of the reduction potential of the fullerene on the open-circuit volt

Design Rules for Donors in Bulk‐Heterojunction Solar Cells—Towards 10 % Energy‐Conversion Efficiency

Brownian motors: noisy transport far from equilibrium

Dynamic atomic force microscopy methods

http://myweb.rz.uni-augsburg.de/~eckern/WEH-287/ABSTRACTS/ruitenbeek.pdf

Quantum properties of atomic-sized conductors

Growth of self-assembled InAs and InAsxP1−x dots on InP by metalorganic vapour phase epitaxy

We describe a technique for the fabrication of lateral nanometer-scale devices, in which individual metallic nanoparticles are imaged, selected and manipulated into a gap between two electrical leads with the tip of an atomic force microscope. In situ, real-time monitoring of the device characteristics is used to control the positions of the particles down to atomic accuracy and to tune the electrical properties of the device during fabrication. Using this technique we demonstrate a nanomechanical switch as well as atomic-scale contacts that are stable at quantized conductance levels on the time scale of hours at room temperature.

Fabrication of quantum devices by Ångström-level manipulation of nanoparticles with an atomic force microscope

A general problem in scanning probe microscopy (SPM) of small particles is that the probe itself moves and removes the particles as it tries to image them. This fact has strongly limited the use of SPM in the field of nm‐sized particles, and high‐resolution electron microscopy has been the only alternative for detailed imaging. Here, we take advantage of a moderate sintering at 350 °C to effectively stabilize nanometer‐sized metallic particles on a semiconductor surface, allowing characterization by SPM. Using this technique, we have been able to successfully image aerosol deposited Ag particles of sizes around 35 nm by contact mode atomic force microscopy (AFM). This new sample preparation technique for SPM overcomes the problems of probe‐induced particle movement during scanning and is proposed as a method to ‘‘freeze’’ artificial nanostructures produced by manipulation of particles with the AFM probe.

Contact mode atomic force microscopy imaging of nanometer‐sized particles

We have studied the formation of strained InAs and InP island structures on GaP surfaces grown by chemical beam epitaxy. InP grows pseudomorphically for 3 ML before island crystallization is observed by reflection high-energy electron diffraction, following a typical Stranski–Krastanov growth mode. For the growth of InAs on GaP, three-dimensional diffraction peaks are observed after 0.9 ML of InAs have been deposited, indicating a Volmer–Weber growth mode. Atomic force microscopy studies of these structures are presented and the optical properties are discussed.

A reflection high-energy electron diffraction and atomic force microscopy study of the chemical beam epitaxial growth of inas and inp islands on (001) gap

Single-electron devices via controlled assembly of designed nanoparticles

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