Advances in nanoscale science and engineering suggest that many of the current problems involving water quality could be resolved or greatly ameliorated using nanosorbents, nanocatalysts, bioactive nanoparticles, nanostructured catalytic membranes and nanoparticle enhanced filtration among other products and processes resulting from the development of nanotechnology. Innovations in the development of novel technologies to desalinate water are among the most exciting and promising. Additionally, nanotechnology-derived products that reduce the concentrations of toxic compounds to sub-ppb levels can assist in the attainment of water quality standards and health advisories. This article gives an overview of the use of nanomaterials in water purification. We highlight recent advances on the development of novel nanoscale materials and processes for treatment of surface water, groundwater and industrial wastewater contaminated by toxic metal ions, radionuclides, organic and inorganic solutes, bacteria and viruses. In addition, we discuss some challenges associated with the development of cost effective and environmentally acceptable functional nanomaterials for water purification.

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Nanomaterials and Water Purification: Opportunities and Challenges

The rapidly increasing population, depleting water resources, and climate change resulting in prolonged droughts and floods have rendered drinking water a competitive resource in many parts of the world. The development of cost-effective and stable materials and methods for providing the fresh water in adequate amounts is the need of the water industry. Traditional water/wastewater treatment technologies remain ineffective for providing adequate safe water due to increasing demand of water coupled with stringent health guidelines and emerging contaminants. Nanotechnology-based multifunctional and highly efficient processes are providing affordable solutions to water/wastewater treatments that do not rely on large infrastructures or centralized systems. The aim of the present study is to review the possible applications of the nanoparticles/fibers for the removal of pollutants from water/wastewater. The paper will briefly overview the availability and practice of different nanomaterials (particles or fibers) for removal of viruses, inorganic solutes, heavy metals, metal ions, complex organic compounds, natural organic matter, nitrate, and other pollutants present in surface water, ground water, and/or industrial water. Finally, recommendations are made based on the current practices of nanotechnology applications in water industry for a stand-alone water purification unit for removing all types of contaminants from wastewater.

/pdf/a-review-of-removal-of-pollutants-from-water-wastewater-p40ax32731.pdf

A Review of Removal of Pollutants from Water/Wastewater Using Different Types of Nanomaterials

Nanotechnology, the engineering and art of manipulating matter at the nanoscale (1-100 nm), offers the potential of novel nanomaterials for treatment of surface water, groundwater, and wastewater contaminated by toxic metal ions, organic and inorganic solutes, and microorganisms. Due to their unique activity toward recalcitrant contaminants and application flexibility, many nanomaterials are under active research and development. Accordingly, literature about current research on different nanomaterials (nanostructured catalytic membranes, nanosorbents, nanocatalysts, and bioactive nanoparticles) and their application in water treatment, purification and disinfection is reviewed in this article. Moreover, knowledge regarding toxicological effects of engineered nanomaterials on humans and the environment is presented.

Nanotechnology and Water Treatment: Applications and Emerging Opportunities

Novel types of microporous material are required for chemoselective adsorptions, separations and heterogeneous catalysis. This concept article describes recent research directed towards the synthesis of polymeric materials that possess microporosity that is intrinsic to their molecular structures. These polymers (PIMs) can exhibit analogous behaviour to that of conventional microporous materials, but, in addition, may be processed into convenient forms for use as membranes. The excellent performance of these membranes for gas separation and pervaporation illustrates the unique character of PIMs and suggests immediate technological applications.

Polymers of intrinsic microporosity (PIMs): bridging the void between microporous and polymeric materials.

Toxic aromatic pollutants, concentrated in industrial wastes and contaminated sites, can potentially be eliminated by low cost bioremediation systems. Most commonly, the goal of these treatment systems is directed at providing optimum environmental conditions for the mineralization of the pollutants by naturally occurring microflora. Electrophilic aromatic pollutants with multiple chloro, nitro and azo groups have proven to be persistent to biodegradation by aerobic bacteria. These compounds are readily reduced by anaerobic consortia to lower chlorinated aromatics or aromatic amines but are not mineralized further. The reduction increases the susceptibility of the aromatic molecule for oxygenolytic attack. Sequencing anaerobic and aerobic biotreatment steps provide enhanced mineralization of many electrophilic aromatic pollutants. The combined activity of anaerobic and aerobic bacteria can also be obtained in a single treatment step if the bacteria are immobilized in particulate matrices (e.g. biofilm, soil aggregate, etc.). Due to the rapid uptake of oxygen by aerobes and facultative bacteria compared to the slow diffusion of oxygen, oxygen penetration into active biofilms seldom exceeds several hundred micrometers. The anaerobic microniches established inside the biofilms can be applied to the reduction of electron withdrawing functional groups in order to prepare recalcitrant aromatic compounds for further mineralization in the aerobic outer layer of the biofilm. Aside from mineralization, polyhydroxylated and chlorinated phenols as well as nitroaromatics and aromatic amines are susceptible to polymerization in aerobic environments. Consequently, an alternative approach for bioremediation systems can be directed towards incorporating these aromatic pollutants into detoxified humic-like substances. The activation of aromatic pollutants for polymerization can potentially be encouraged by an anaerobic pretreatment step prior to oxidation. Anaerobic bacteria can modify aromatic pollutants by demethylating methoxy groups and reducing nitro groups. The resulting phenols and aromatic amines are readily polymerized in a subsequent aerobic step.

Enhanced biodegradation of aromatic pollutants in cocultures of anaerobic and aerobic bacterial consortia

A new, low-cost fiber glass supported activated carbon (FGAC) filter has been prepared that displays enhanced adsorption characteristics for the removal of BTEX (benzene, toluene, ethylbenzene, and p-xylene) from water to below maximum contaminant level (MCL) regulated by USEPA and two chemical warfare agent simulants (diisopropylmethyl phosphonate and 2-chloroethyl ethyl sulfide) to barely detectable levels. Breakthrough curves for both the FGAC filter and a commercially available granular activated carbon (GAC) filter containing equal weights of adsorbent show that the FGAC filter has greatly improved kinetics of adsorption over the GAC filter for all six chemical contaminants. Benzene breakthrough curves showed the FGAC filter effluent to contain less than one ppb as compared to several parts per million in the GAC filter effluent. This was 2 orders of magnitude better than the GAC and represents a major advance in generating good water quality for the military as well as the general public. The FGAC filter showed a much lower pressure drop and could be completely regenerated at least 6 times by heating to 190 degrees C under vacuum.

Removal of chemical contaminants from water to below USEPA MCL using fiber glass supported activated carbon filters.

Six activated carbon fibers (ACFs) with different chemical and physical properties were prepared by first curing a phenolic resin-coated glass fiber, followed by activation and post-treatment. Their adsorption properties were investigated to evaluate the removal of benzene, toluene, ethylbenzene, and p-xylene (BTEX) and the chemical warfare simulants dissopropylmethyl phosponate (DIMP) and half mustard (HM) from water. The adsorption isotherms showed that ACF SL-2 (activated with CO2/H2O at 800 °C) has a higher adsorption capacity for BTEX, DIMP, and HM than other ACFs. This suggests that the high adsorption affinity of SL-2 is related to its higher surface area, larger average micropore size of 11.6 A (especially effective for the adsorption of DIMP), and lower oxygen content of the surface. The adsorption isotherms are well represented by the Freundlich equation. For BTEX, the adsorption parameters based on carbon coating showed that, in all cases, ACFs have a higher K value than the best available data...

Adsorption of Organic Contaminants from Water Using Tailored ACFs

Enzymatic methods have shown promise for removing aromatic compounds from (high-strength) industrial wastewater. The removal of these compounds was studied at low levels that might be encountered in surface waters which receive some industrial discharge. The results indicate that enzymatic oxidative coupling using horseradish peroxidase and hydrogen perioxide may be useful in eliminating some aromatics that are not well-removed in biological or physical water treatment, but the nature of the byproducts must be determined to assure that the products are not more undesirable than the initial compounds. 21 references, 4 figures, 2 tables.

Transformation of trace organic compounds in drinking water by enzymic oxidative coupling.

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Removal of chemical contaminants from water to below USEPA MCL using fiber glass supported activated carbon filters.

Adsorption of Organic Contaminants from Water Using Tailored ACFs

Transformation of trace organic compounds in drinking water by enzymic oxidative coupling.