Chemorobust dye-encapsulated framework as dual-emission self-calibrating ratiometric sensor for intelligent detection of toluene exposure biomarker in urine.

By immobilizing the chiral center l-histidine (l-His) into a Zr-based metal-organic framework (MOF) through post-synthetic ligand exchange, a chiral compound MOF-His has been prepared. On this basis, MOF-His is hybridized with Eu3+ ions to obtain the final responsive compound Eu@MOF-His. It is worth noting that the bifunctional material exhibits enantioselective luminescence properties for tryptophan enantiomers. The experimental results demonstrate that tryptophan enantiomers can effectively quench the red-light emission of Eu3+ ions, and also, the quenching rates are various, which may originate from the differences in the interaction between analytes and chiral recognition sites. In addition, Eu@MOF-His can realize the sensing of tryptophan enantiomers in serum. Concurrently, the compound possesses reusability, high sensitivity, and fast response speed, which means that it has the potential to serve as an excellent fluorescent sensor for detecting and identifying tryptophan enantiomers.

Zirconium Metal Organic Framework-Based Hybrid Sensors with Chiral and Luminescent Centers Fabricated by Postsynthetic Modification for the Detection and Recognition of Tryptophan Enantiomers.

This work focuses on the design of multifunctional lanthanide MOFs platform for smart sensing of methylmalonic acid (MMA) and anti-counterfeiting applications. The platform enables intuitive detection of MMA in urine to further infer vitamin B12 levels.

Multifunctional lanthanide MOFs with active sites as new platforms for smart sensing of methylmalonic acid and anti-counterfeiting applications

In recent years, the irrational use of antibiotics has become very widespread. It is necessary to regulate this phenomenon through antibiotic detection. In this work, a series of isomorphic Ln-MOFs (Ln = Tb3+ and Eu3+) were synthesized from 1,3,5-tri(4-carboxyphenyl)benzene (H3L) and Ln3+ by the solvothermal method for the first time. A series of 1-EuxTb1-x with different luminescence were doped by changing the molar ratio of Tb3+ and Eu3+. Ln3+ forms a 4-connected 2D network structure through self-assembly with fully deprotonated L3-. It shows good chemical stability in water, and its luminescence is not affected by aqueous solutions with different pH values. 1-Eu demonstrates rapid and sensitive detection capabilities for MDZ and TET with good recyclability and low detection limits (10-5). In order to increase the practicability of 1-Eu, two portable sensors have been prepared, in which the fluorescent film (Film@1-Eu) has a detection limit of 10-4, and the sensitivity is only less than 10% of the titration results. A portable fluorescent test paper can reach the detection limit of 14.7 ppm. This study provides a new idea for the application of stable multifunctional materials in the field of fluorescence sensing.

Fabrication of the Antibiotic Sensor by the Multifunctional Stable Adjustable Luminescent Lanthanide Metal-Organic Frameworks.

Dyes-modified metal−organic frameworks composite as a sensitive, reversible and ratiometric fluorescent probe for the rapid detection of malachite green

Dye functionalized lanthanide metal-organic framework as a multifunctional luminescent hybrid material for visual sensing of biomarker 2-methoxyaceticacid and sulfide anion.

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Dye functionalized lanthanide metal-organic framework as a multifunctional luminescent hybrid material for visual sensing of biomarker 2-methoxyaceticacid and sulfide anion.