Sharanappa Nembenna
National Institute of Science Education and Research
64 Papers
357 Citations
Sharanappa Nembenna is an academic researcher from National Institute of Science Education and Research. The author has contributed to research in topics: Chemistry & Catalysis. The author has an hindex of 19, co-authored 45 publications. Previous affiliations of Sharanappa Nembenna include University of Duisburg-Essen & Monash University.
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Papers
β-Diketiminate-Stabilized Magnesium(I) Dimers and Magnesium(II) Hydride Complexes: Synthesis, Characterization, Adduct Formation, and Reactivity Studies
Simon J. Bonyhady,Cameron Jones,Sharanappa Nembenna,Andreas Stasch,Alison J. Edwards,Garry J. McIntyre +5 more
TL;DR: The preparation and characterization of a series of magnesium(II) iodide complexes incorporating beta-diketiminate ligands of varying steric bulk and denticity, namely, [(ArNCMe)(2)CH](-) (Ar=phenyl), mesityl ((Mes)Nacnac), or 2,6-diisopropylphenyl (Dipp, ( Dipp)NACnac) are reported.
398
Aluminum Monohydride Catalyzed Selective Hydroboration of Carbonyl Compounds
TL;DR: The well-defined aluminum monohydride compound [{(2,4,6-Me3-C6H2)NC(Me)}2(Me)(H)]AlH·(NMe2Et) (1) catalyzes hydroboration of a wide range of aldehydes and ketones under mild reaction conditions.
165
A Dimeric Magnesium(I) Compound as a Facile Two-Center/Two-Electron Reductant
Simon J. Bonyhady,Shaun P. Green,Shaun P. Green,Cameron Jones,Sharanappa Nembenna,Andreas Stasch +5 more
TL;DR: The novel reduced or reductively coupled products obtained from these reductions suggest that magnesium(I) compounds may find wide use in organic and organometallic syntheses.
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Chemistry of soluble β-diketiminatoalkaline-earth metal complexes with M-X bonds (M=Mg, Ca, Sr; X=OH, Halides, H).
TL;DR: Some recent developments in alkaline earth metal complex chemistry, particularly of Mg, Ca, and Sr, are summarized through the utilization of β-diketiminate ligands, as well as the closely related chemistry of the Group 12 element Zn.
110
Aluminum-Catalyzed Selective Hydroboration of Nitriles and Alkynes: A Multifunctional Catalyst.
TL;DR: Aluminum dihydride catalyzed both intra- and intermolecular chemoselective hydroboration of nitriles and alkynes over other reducible functionalities for the first time and is expanded to more challenging substrates such as alkene, pyridine, imine, carbodiimide and isocyanides.
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