Shannon S. Stahl
University of Wisconsin-Madison
392 Papers
2.1K Citations
Shannon S. Stahl is an academic researcher from University of Wisconsin-Madison. The author has contributed to research in topics: Catalysis & Chemistry. The author has an hindex of 93, co-authored 345 publications. Previous affiliations of Shannon S. Stahl include Wisconsin Alumni Research Foundation & Great Lakes Bioenergy Research Center.
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Papers
Characterization of DMSO Coordination to Palladium(II) in Solution and Insights into the Aerobic Oxidation Catalyst, Pd(DMSO)2(TFA)2
TL;DR: New insights are provided into the coordination of DMSO to palladium(II) in both the solid state and in solution by studying the solid-state structure and crystal structure of Pd(DMSO)(2)(TFA)(2).
Electrochemical Functional-Group-Tolerant Shono-type Oxidation of Cyclic Carbamates Enabled by Aminoxyl Mediators.
TL;DR: This reaction represents the first α-functionalization of non-activated cyclic carbamates with oxoammonium oxidants and allows for functional-group compatibility that is inaccessible with conventional Shono oxidations, which proceed by direct electrochemical substrate oxidation.
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Bioinspired Aerobic Oxidation of Secondary Amines and Nitrogen Heterocycles with a Bifunctional Quinone Catalyst.
TL;DR: Efficient aerobic dehydrogenation of secondary amine substrates, including pharmaceutically relevant nitrogen heterocycles, including pharmacy relevant nitrogenheterocycles is studied.
116
Observation and mechanistic study of facile C-O bond formation between a well-defined aryl-copper(III) complex and oxygen nucleophiles.
Lauren M. Huffman,Alicia Casitas,Marc Font,Mercè Canta,Miquel Costas,Xavi Ribas,Shannon S. Stahl +6 more
TL;DR: In this article, a macrocyclic aryl-Cu(III)-Br species 2(Br) was observed as an intermediate in the catalytic reaction and the relationship between these reactions and catalytic C-O coupling methods was demonstrated by the reaction of 2 with acetic acid and pfluorophenol.
115
Molecular Cobalt Catalysts for O2 Reduction: Low-Overpotential Production of H2O2 and Comparison with Iron-Based Catalysts
TL;DR: The data show that the TOFs of the Co complexes exhibit a shallower dependence on E1/2(MIII/II) than the Fe complexes, which underlies the low overpotential, and is rationalized on the basis of the catalytic rate law.
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