Harvesting clean energy from fuel feedstocks is of paramount significance in the field of environmental science. In this dynamic area, desulfurization provides a valuable contribution by eliminating sulfur compounds from fuel feedstocks to ensure the utilization of fuels without the emission of toxic sulfur oxides (SOx gases). Nonetheless, the inadequacy of the current industrial technique (hydrodesulfurization, HDS) in the removal of refractory sulfur (RS) compounds and the stringent rules imposed on the fuel sulfur level have kindled research on other desulfurization methods like oxidative desulfurization (ODS). With the capacity of eliminating RS compounds under mild conditions, ODS is endorsed as a suitable replacement or complementary to HDS. ODS, in general, consists of two steps: (i) oxidation and (ii) extraction. The oxidation of sulfur compounds is carried out using a suitable catalyst (hereafter termed as an ODS catalyst) in the presence of an oxidant. Choosing a suitable ODS catalyst for industrial applications is still a quest among the various types of catalysts reported so far. With this outline, herein, all the types of ODS catalysts along with their synthetic methods, reactivity and mechanistic insights are reviewed. The activity of ODS catalysts could be influenced by factors like the type of RS compound, solvent, fuel, etc. and those factors are reviewed. The effects of ionic liquids, light, and ultrasound on the performance of ODS catalysts are also briefly summarized. The opportunities and challenges for ODS catalysts are comprehensively explicated in the end. Through this review, systematic information about the types of ODS catalysts including the basic definition, preparative methods, reactivity and mechanism can be comprehended. Furthermore, this review reveals the merits and demerits related to highlighting catalytic ODS as a replacement or complementary to HDS.

/pdf/a-comprehensive-review-on-oxidative-desulfurization-21shasgoao.pdf

A comprehensive review on oxidative desulfurization catalysts targeting clean energy and environment

Removal of sulfur- and nitrogen-containing compounds (SCCs and NCCs) from commercial fuel is very important since those impurities can cause various problems including catalyst deactivation and acid rain. Because of the limitations of the conventional refinery methods, development of a new method such as oxidative desulfurization (ODS) is highly desirable. Metal-organic frameworks (MOFs)-based and MOF-derived nanohybrid materials were suggested as a good catalyst for ODS of fuels. Moreover, removal of NCCs via oxidation with MOF-derived catalyst was also reported even though the technique is just emerging. Therefore, it is required to analyze the reported results; and more importantly to suggest a new research direction; and finally, to estimate the possibility of new desulfurization/denitrogenation technology that might replace/compensate studied technologies. This review might be quite beneficial not only to accumulate or understand the reported results but also to develop new efficient catalysts for the probable commercialization of the ODS/ODN technology.

Oxidative desulfurization and denitrogenation of fuels using metal-organic framework-based/-derived catalysts

The demand for clean fuels is increasing throughout the world, with more stringent environmental regulations for transportation fuels including marine fuels, particularly regarding their sulfur content. Moreover, the quality of crude oil and derived petroleum cuts is getting lower while fossil fuels are still in high demand. Heavy oils are characterized by high sulfur content where most sulfur is found in bulky thiophenic structures difficult to remove using conventional high pressure hydrodesulfurization process. However they appeared more reactive in oxidative desulfurization (ODS) process, carried out at mild conditions without hydrogen pressure. This review focuses for the first time on the heavy fuels initially containing more than 0.5 wt.%S and upgraded by the ODS process. Different attractive approaches of the literature towards ODS are reported using homogeneous and heterogeneous catalysis. Recent developments in ODS assisted with ultrasound technology and the use of ionic liquid to enhance ODS efficiency will be fully detailed and discussed to better understand their viability when applied to high sulfur content, high viscosity, and high boiling point feeds.

Oxidative Desulfurization of Heavy Oils with High Sulfur Content: A Review

Adsorptive removal of hazardous organics from water and fuel with functionalized metal-organic frameworks: Contribution of functional groups

Review on oxidative desulfurization of fuel by supported heteropolyacid catalysts

Ultra-deep desulfurization technologies are critical for cleaner oils and consequent better air quality. Earlier efforts in this field focused on specific catalysts and their catalytic efficiencies, while current interest has shifted to the differences between homogenous and heterogeneous catalysis systems applied in catalytic oxidation desulfurization (ODS) as well as their advantages and disadvantages. In this review, catalysts using various supports were described and their catalytic activities in total oxidation of sulfur compounds were evaluated and commented meanwhile, taking hydroperoxide as oxidant. Then, the effects of reaction parameters on catalyst activities and the kinetics and mechanisms that were used for ODS from oils were reviewed. Under the same conditions, heterogeneous catalysts performed better than homogeneous catalysts. Leaching of active components, existence of N-containing compounds and excessive reaction temperature would deactivate catalysts in ODS. Besides, power-law kinetics equations, Langmuir–Hinshelwood mechanism, and “nucleophilic attack” reaction mechanism” will provide in-depth analysis of desulfurization process and catalysts deactivation. Future research needs on ODS are proposed including the development of novel carrier materials, the optimization of acid sites distribution and the better understanding of deep reaction mechanisms.

Performances, kinetics and mechanisms of catalytic oxidative desulfurization from oils

Novel shear thickening gel/high‐performance fiber reinforced flexible composites: Multi‐velocity impact and functional properties

The invention discloses a biological nanomaterial with magnetism, a preparation method and an application thereof The biological nanomaterial adopts saccharomyces cerevisiae in saccharomyces as carriers, and is loaded with nano Fe3O4 and a crosslinking product of chitosan and epichlorohydrin; the surface of the saccharomyces cerevisiae is wrapped with calcium alginate The method comprises the following steps: firstly preparing the nano Fe3O4 and the crosslinking product of chitosan and epichlorohydrin, then mixing with saccharomyces cerevisiae spore liquid and a calcium alginate solution, dripping the mixed solution into a calcium chloride solution dropwise, and immobilizing to obtain nano Fe3O4-saccharomyces cerevisiae-calcium alginate microspheres, and culturing, thus obtaining a biological material with the magnetism The biological material with the magnetism has the magnetism of the Fe3O4 and the microbial performance of the saccharomyces cerevisiae, has the advantages of good removing effect, easiness in separation, no pollution and the like, and can be applied in treating atrazine in an aqueous solution

Biological nanomaterial with magnetism, preparation method and application thereof

Wearable flexible pressure sensors are a novel class of human activity detection device. However, the preparation of pressure sensors with high sensitivity and wide sensing range still faces great challenges. This study reveals an flexible heat-resistant variable density point pressure sensing array (PSA) with ultra-wide sensing range based on Ti3C2Tx-MXene. MXene containing polar oxygen-containing functional groups coated polyester fiber fabricated the pressure sensing layer while a stainless steel wire core is used as a flexible electrode for signal collection. The signal processing device rapidly converts the mechanical signal into electrical signal output to increase the transmission speed and range. Experimental results show that the PSA can effectively sense dynamic and static pressures with high sensitivity (0.14-0.87 kPa-1 over a pressure range of 7.2 Pa∼2000 kPa), a wide sensing range (0∼15000 kPa), fast response time (80 ms), 10,000 cycles (2000 kPa) stability and maintains a 81.25% current response. The noval fully woven structural flexible PSA exhibited larger area, of which the weave density is varied to control resolution and the pressure mapping is referenced to each pixel point to qualitatively and quantitatively analyze shape and pressure distribution. Variable density points pressure sensor with wide sensing range and spatial pressure mappinghas promising applications in healthcare. 

Variable Density Points Pressure Sensor with Wide Sensing Range and Spatial Pressure Mapping

With the rapid development of social economy, people’s living environment has undergone tremendous changes. At the same time as social development, it will also be accompanied by many problems, such as environmental degradation, air quality decline, and frequent diseases. Studies have found that due to the destruction of the ozone layer, the ultraviolet rays in the atmosphere cannot be effectively absorbed, which hinders the reduction, and the risk of skin cancer increases year by year. Environmental pollution is becoming more and more serious, bacteria multiply, and textiles are also polluted. Every year, a large number of textiles are discarded due to pollution, so people have new demands on the functionality of textiles. In recent years, with the breakthrough development of nanomaterials research enterprises, nanomaterials are increasingly used in textiles to meet people’s new needs for textiles. Nano-TiO2 has high antiultraviolet performance and self-cleaning performance and also has excellent performance in antibacterial and bacteriostatic issues. Toxicological experiments were carried out on nano-TiO2 materials. The results showed that the cytotoxicity of different cells in different concentrations of nano-TiO2 was very small, the cell viability was not less than 80%, and there was a certain concentration effect.

/pdf/application-and-safety-performance-of-nanomaterials-in-275z6oje.pdf

Application and Safety Performance of Nanomaterials in Clothing Design Engineering

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