U–Pb age data collected from zircon and monazite are used to draw fundamental inferences about tectonic processes in the Earth. Despite the emphasis placed on zircon and monazite ages, the understanding of how to relate the timing of growth of zircon and monazite to an evolving rock system remains in its infancy. In addition, few studies have presented large datasets of geochronological data from zircon and monazite occurring in the same metamorphic rock sample. Such information is crucial for understanding the growth of zircon relative to monazite in a systematic and predictive manner, as per this study. The data that exist support the generally held conception that zircon ages tend to be older than monazite ages within the same rock. Here experimental data for zircon and monazite saturation in melt-bearing rocks are integrated with phase diagram calculations. The calculations constrain the dissolution and growth behaviour of zircon and monazite with respect to evolving pressure, temperature and silicate mineral assemblages in high-grade, melt-bearing, metasedimentary rocks. Several key results emerge from this modelling: first, that in aluminous metapelitic rocks (i.e. garnet + cordierite + sillimanite assemblages), zircon ages are older than monazite ages in the same rock; second, that the growth rate of accessory minerals is nonlinear and much higher at and near saturation than at lower temperatures; and third, that the difference in zircon and monazite ages from the same rock may be ascribed to differences in the temperature(s) at which zircon and monazite grow rather than differences in closure temperature systematics. Using our methodology the cooling rate of granulites from the Reynolds Range, central Australia, have been constrained at ∼4 °C Myr−1. This study serves as a first-pass template on which further research in applying the technique to a field study can be based.

https://onlinelibrary.wiley.com/doi/pdf/10.1111/j.1525-1314.2007.00757.x

Thermobarometric modelling of zircon and monazite growth in melt-bearing systems: examples using model metapelitic and metapsammitic granulites

Assembling Australia: Proterozoic building of a continent

The distribution of REE minerals in metasedimentary rocks was investigated to gain insight into the stability of allanite, monazite and xenotime in metapelites. Samples were collected in the central Swiss Alps, along a well-established metamorphic field gradient that record conditions from very low grade metamorphism (250 C) to the lower amphibolite facies (600 C). In the Alpine metapelites
investigated, mass balance calculations show that LREE are mainly transferred between monazite and allanite during the course of prograde metamorphism. At very low grade metamorphism, detrital monazite grains (mostly Variscan in age) have two distinct populations in terms of LREE and MREE
compositions. Newly formed monazite crystallized during low-grade metamorphism (<440 C); these are enriched in La, but depleted in Th and Y, compared with inherited grains. Upon the appearance of chloritoid (440–450 C, thermometry based on chlorite–choritoid and carbonaceous material),
monazite is consumed, and MREE and LREE are taken up preferentially in two distinct zones of allanite distinguishable by EMPA and X-ray mapping. Prior to garnet growth, allanite acquires two growth zones of clinozoisite: a first one rich in HREE + Y and a second one containing low REE contents. Following garnet growth, close to the chloritoid–out zone boundary (556–580 C, based on phase equilibrium calculations), allanite and its rims are partially to totally replaced by monazite and xenotime, both associated with plagioclase (± biotite ± staurolite ± kyanite ± quartz). In these samples, epidote relics are located in the matrix or as inclusions in garnet, and these preserve their characteristic chemical and textural growth zoning, indicating that they did not experience reequilibration following their prograde formation. Hence, the partial breakdown of allanite to monazite offers the attractive possibility to obtain in situ ages, representing two distinct crystallization stages. In addition, the complex REE + Y and Th zoning pattern of allanite and monazite are essential monitors of crystallization conditions at relatively low metamorphic grade.

Prograde metamorphic sequence of REE minerals in pelitic rocks of the Central Alps: implications for allanite-monazite-xenotime phase relations from 250 to 610 C

The formation, age and trace element composition of zircon and monazite were investigated across the prograde, low-pressure metamorphic sequence at Mount Stafford (central Australia). Three pairs of inter-layered metapelites and metapsammites were sampled in migmatites from amphibolite-facies (T 600 C) to granulite-facies conditions (T 800 C). Sensitive high-resolution ion microprobe U–Pb dating on metamorphic zircon rims and on monazite indicates that granulite-facies metamorphism occurred between 1795 and 1805Ma. The intrusion of an associated granite was coeval with metamorphism at 1802 ± 3Ma and is unlikely to be the heat source for the prograde metamorphism. Metamorphic growth of zircon started at T 750 C, well above the pelite solidus. Zircon is more abundant in the metapelites, which experienced higher degrees of partial melting compared with the associated metapsammites. In contrast, monazite growth initiated under sub-solidus prograde conditions. At granulite-facies conditions two distinct metamorphic domains were observed in monazite. Textural observations, petrology and the trace element composition of monazite and garnet provide evidence that the first metamorphic monazite domain grew prior to garnet during prograde conditions and the second in equilibrium with garnet and zircon close to the metamorphic peak. Ages from sub-solidus, prograde and peak metamorphic monazite and zircon are not distinguishable within error, indicating that heating took place in less than 20 Myr.

/pdf/temperature-and-bulk-composition-control-on-the-growth-of-k6qxd267g3.pdf

Temperature and Bulk Composition Control on the Growth of Monazite and Zircon During Low-pressure Anatexis (Mount Stafford, Central Australia)

https://hal-insu.archives-ouvertes.fr/insu-00628119/document

Paleoproterozoic tectonic evolution of the Trans-North China Orogen: Toward a comprehensive model

Several petrographic studies have linked accessory monazite growth in pelitic schist to metamorphic reactions involving major rock-forming minerals, but little attention has been paid to the control that bulk composition might have on these reactions. In this study we use chemographic projections and pseudosections to argue that discrepant monazite ages from the Mount Barren Group of the Albany–Fraser Orogen, Western Australia, reflect differing bulk compositions. A new Sensitive High-mass Resolution Ion Microprobe (SHRIMP) U–Pb monazite age of 1027 ± 8 Ma for pelitic schist from the Mount Barren Group contrasts markedly with previously published SHRIMP U–Pb monazite and xenotime ages of c. 1200 Ma for the same area. All dated samples experienced identical metamorphic conditions, but preserve different mineral assemblages due to variable bulk composition. Monazite grains dated at c. 1200 Ma are from relatively magnesian rocks dominated by biotite, kyanite and/or staurolite, whilst c. 1027 Ma grains are from a ferroan rock dominated by garnet and staurolite. The latter monazite population is likely to have grown when staurolite was produced at the expense of garnet and chlorite, but this reaction was not intersected by more magnesian compositions, which are instead dominated by monazite that grew during an earlier, greenschist facies metamorphic event. These results imply that monazite ages from pelitic schist can vary depending on the bulk composition of the host rock. Samples containing both garnet and staurolite are the most likely to yield monazite ages that approximate the timing of peak metamorphism in amphibolite facies terranes. Samples too magnesian to ever grow garnet, or too iron-rich to undergo garnet breakdown, are likely to yield older monazite, and the age difference can be significant in terranes with a polymetamorphic history.

Bulk chemical control on metamorphic monazite growth in pelitic schists and implications for U–Pb age data

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Bulk chemical control on metamorphic monazite growth in pelitic schists and implications for U–Pb age data