介绍了Kirk—Othmer Encyclopedia of Chemical Technology（化工技术百科全书）（第五版）电子图书网络版数据库，并对该数据库使用方法和检索途径作出了说明，且结合实例简单地介绍了该数据库的检索方法。

Kirk-Othmer Encyclopedia of Chemical Technology数据库介绍及实例

American Chemical Society to Honor Mohan

Experimental p–x data were measured for the (acetic acid + water) system at the temperatures (412.6, 443.2, and 483.2) K between the pressures 196 and 1902 kPa over the entire range of concentrations. Experiments were carried out in static-analytical equipment with quantitative analysis by GC. The experimental data were correlated with the Perturbed-Chain Statistical Associating Fluid Theory considering two association sites for acetic acid and four association sites for water.

/pdf/p-x-data-of-acetic-acid-water-at-t-412-6-443-2-483-2-k-4q4m36s2a3.pdf

p–x Data of (Acetic Acid + Water) at T = (412.6, 443.2, 483.2) K

Fractionation of dilute acetic acid aqueous mixtures was operated using a continuous countercurrent packed column with supercritical CO2. A generic procedure was developed to assess the feasibility of such an operation. Experiments were performed using a 2 m high and 17 mm inner diameter column, in the range (10−15 MPa) and (40 °C–60 °C). Thermodynamics of the mixture was described using the Soave-Redlich-Kwong equation modified by Boston Mathias with PSRK mixing rules and UNIQUAC activity coefficient model. Experimental results were compared to simulation using a software based on the concept of equilibrium stage. Conventional liquid-liquid extraction methods indicated that thermodynamics limits the separation performances. Therefore, an external extract reflux configuration was tested by simulation. It was shown that the limitation could be overridden and influence of design (number of stages, position of the feed) and operating conditions (reflux ratio, solvent-to-feed ratio) has been assessed.

https://hal.archives-ouvertes.fr/hal-02533378/document

Fractionation of a dilute acetic acid aqueous mixture in a continuous countercurrent packed column using supercritical CO2: Experiments and simulation of external extract reflux

An English translation of the highly successful German-language Lehrbuch der Organischem Chemie, first published in 1953 and revised through more than twenty subsequent editions.

Organic Chemistry: A Comprehensive Degree Text and Source Book, 22nd ed. (Beyer, Hans; Walter, Wolfgang)

Vapour – liquid equilibria were measured for the acetic acid + water and the propanoic acid + water systems, in the temperature range of 412.6 to 483.2 K and pressures of 1.87 to 19.38 bar, over the entire range of concentrations. An experimental apparatus based on the static-analytical method with sampling of both phases was used with quantitative analysis by GC. A new experimental technique comprising positron emission particle tracking (PEPT) was developed and applied for the determination phase compositions and molar volumes for the acetic acid + water system at 412.6 K. 
The Peng-Robinson (PR), the Cubic Plus Association (CPA), the Perturbed Chain Statistical Associating Fluid Theory (PC-SAFT) and the PC-polar-SAFT (PCP-SAFT) equations modelled the data. The 1A and 2B association schemes for propanoic acid and the 2B, 3B and 4C for water, were evaluated. In CPA, the ECR and CR1 combining rules were also tested. A single binary interaction parameter was used in all models. PCP-SAFT presented higher predictive and correlative capabilities when the organic acid was modelled as 1A and water as 2B. The best association combination among CPA and PC-SAFT was 2B and 4C for the acid and water, respectively. CR1 accounted for lower errors in predictive mode while ECR in correlative mode. CPA performance was intermediate between the PC-SAFT and PCP-SAFT models and the PR equation. PR predictions were rather poor but correlations were better than those of CPA, at the expense of a larger binary interaction parameter.

Vapour – liquid equilibria of acetic acid + water and propanoic acid + water: experimental measurement and thermodynamic modelling

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Vapour – liquid equilibria of acetic acid + water and propanoic acid + water: experimental measurement and thermodynamic modelling