Richard H. Holm
Harvard University
580 Papers
13.5K Citations
Richard H. Holm is an academic researcher from Harvard University. The author has contributed to research in topics: Cubane & Chemistry. The author has an hindex of 87, co-authored 580 publications. Previous affiliations of Richard H. Holm include University of New Mexico & Stanford University.
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Papers
Electronic control of the "Bailar twist" in formally d0-d2 molybdenum tris(dithiolene) complexes: a sulfur K-edge X-ray absorption spectroscopy and density functional theory study.
Adam L. Tenderholt,Robert K. Szilagyi,Richard H. Holm,Keith O. Hodgson,Britt Hedman,Edward I. Solomon +5 more
TL;DR: Calculations reveal that the Bailar twist observed in some metal tris(dithiolene) complexes is the result of configuration interaction between metal and ligand orbitals and can be probed experimentally by S K-edge XAS.
On the molecular solid-state boundary. A cyclic iron-sulfur cluster of nuclearity eighteen: synthesis, structure, and properties
TL;DR: In this article, the structure of the black compound (Pr{sub 4}N{sup +} ions and two Na{sup+} ions weakly associated with the cluster (Na{sub 2}Fe{sub 18}S{sub 30}
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Synthesis and reactions of cubane-type iron-sulfur-phosphine clusters, including soluble clusters of nuclearities 8 and 16.
Hong-Cai Zhou,Richard H. Holm +1 more
TL;DR: A family of soluble, reduced iron-sulfur clusters with nuclearities 4, 8, and 16 having tertiary phosphine ligation and based on the Fe(4)S( 4) cubane-type structural motif has been synthesized.
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