Richard D. Adams
University of South Carolina
690 Papers
8.8K Citations
Richard D. Adams is an academic researcher from University of South Carolina. The author has contributed to research in topics: Ligand & Crystal structure. The author has an hindex of 45, co-authored 665 publications. Previous affiliations of Richard D. Adams include University at Buffalo & Texas A&M University.
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Papers
Catalytic Macrocyclization of 3,3-Dimethylthietane by Re2(CO)9(SCH2CMe2CH2)
TL;DR: In this article, a macrocyclization mechanism consisting of a metal-induced ring-opening cyclooligomerization of three, four, and five molecules of 3,3-DMT, respectively, is proposed.
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Nucleophilic ring opening transformations of bridging thietane ligands in metal carbonyl cluster complexers
TL;DR: In this paper, the nucleophilic ring opening reactions of bridging thietane ligands in metal cluster complexes are reviewed and a review of recent studies of nucleophilicity of the ring opening reaction is presented.
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An Extraordinary Example of Metalloselectivity. Extraction of Copper from the Mixed-Metal Cluster Cu2Ru6(CO)16(μ6-C)(NCMe)2 by 1,5,9-Trithiacyclododecane
TL;DR: In this article, the reaction of Cu2Ru6(CO)16(μ6-C) with the thiacrown ether 1,5,9-trithiacyclododecane (12S3) resulted in the extraction of both copper atoms from the ruthenium cluster complex by the thiarown and formation of the salt [Cu(η3-12S 3)(η1- 12S3)]2[Ru6
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The synthesis and structural analysis of the bis-Co2(CO)6 adduct of the cyclic tetrayne C20H8
TL;DR: In this paper, the reaction of the cyclic tetrayne 2 with Co2(CO)8 at 25°C has yielded the double addition product, C20H8[Co2(Co)6]2, 3 in a 39% yield.
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Ligand substitution reactons in electron-rich clusters. the synthesis, structures, and bonding of Os4(CO)12L(μ3-S)2 and Os4(CO)11L(μ3-S)2 (L = PMe2Ph and CN-t-Bu)
TL;DR: Etude RX des quatre complexes du titre as mentioned in this paper : 1) cristallise dans P2 1 /a avec Z=4; affinement jusqu'a R=0,041; 2) cristsallise Dans P 2 1 /n avec 0.
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