1182. Lunar and Planetary Institute, Houston (CD-

/pdf/the-nature-and-distribution-of-the-organic-material-in-3wpossorws.pdf

The Nature and Distribution of the Organic Material in Carbonaceous Chondrites and Interplanetary Dust Particles

Context. The inner regions of the envelopes surrounding young protostars are characterized by a complex chemistry, with prebiotic molecules present on the scales where protoplanetary disks eventually may form. The Atacama Large Millimeter/submillimeter Array (ALMA) provides an unprecedented view of these regions zooming in on solar system scales of nearby protostars and mapping the emission from rare species. Aims. The goal is to introduce a systematic survey, the Protostellar Interferometric Line Survey (PILS), of the chemical complexity of one of the nearby astrochemical templates, the Class 0 protostellar binary IRAS 16293 2422, using ALMA in order to understand the origin of the complex molecules formed in its vicinity. In addition to presenting the overall survey, the analysis in this paper focuses on new results for the prebiotic molecule glycolaldehyde, its isomers, and rarer isotopologues and other related molecules. Methods. An unbiased spectral survey of IRAS 16293 2422 covering the full frequency range from 329 to 363 GHz (0.8 mm) has been obtained with ALMA, in addition to a few targeted observations at 3.0 and 1.3 mm. The data consist of full maps of the protostellar binary system with an angular resolution of 0.5 '' (60 AU diameter), a spectral resolution of 0.2 km s(-1), and a sensitivity of 4-5 mJy beam(-1) km s(-1), which is approximately two orders of magnitude better than any previous studies. Results. More than 10 000 features are detected toward one component in the protostellar binary, corresponding to an average line density of approximately one line per 3 km s(-1). Glycolaldehyde; its isomers, methyl formate and acetic acid; and its reduced alcohol, ethylene glycol, are clearly detected and their emission well-modeled with an excitation temperature of 300 K. For ethylene glycol both lowest state conformers, aGg' and gGg', are detected, the latter for the first time in the interstellar medium (ISM). The abundance of glycolaldehyde is comparable to or slightly larger than that of ethylene glycol. In comparison to the Galactic Center these two species are over-abundant relative to methanol, possibly an indication of formation of the species at low temperatures in CO-rich ices during the infall of the material toward the central protostar. Both C-13 and the deuterated isotopologues of glycolaldehyde are detected, also for the first time ever in the ISM. For the deuterated species, a D/H ratio of approximate to 5% is found with no differences between the deuteration in the different functional groups of glycolaldehyde, in contrast to previous estimates for methanol and recent suggestions of significant equilibration between water and-OH functional groups at high temperatures. Measurements of the C-13-species lead to a C-12:C-13 ratio of approximate to 30, lower than the typical ISM value. This low ratio may reflect an enhancement of (CO)-C-13 in the ice due to either ion-molecule reactions in the gas before freeze-out or to differences in the temperatures where (CO)-C-12 and (CO)-C-13 ices sublimate. Conclusions. The results reinforce the importance of low-temperature grain surface chemistry for the formation of prebiotic molecules seen here in the gas after sublimation of the entire ice mantle. Systematic surveys of the molecules thought to be chemically related, as well as the accurate measurements of their isotopic composition, hold strong promise for understanding the origin of prebiotic molecules in the earliest stages of young stars.

/pdf/the-alma-protostellar-interferometric-line-survey-pils-first-1w0b4u0joy.pdf

The ALMA Protostellar Interferometric Line Survey (PILS): First results from an unbiased submillimeter wavelength line survey of the Class 0 protostellar binary IRAS 16293-2422 with ALMA

The search for evidence of extraterrestrial life in our Solar System is currently guided by our understanding of terrestrial biology and its associated biosignatures. The observed homochirality in all life on Earth, that is, the predominance of "left-handed" or l-amino acids and "right-handed" or d-sugars, is a unique property of life that is crucial for molecular recognition, enzymatic function, information storage and structure and is thought to be a prerequisite for the origin or early evolution of life. Therefore, the detection of l- or d-enantiomeric excesses (ee) of chiral amino acids and sugars could be a powerful indicator for extant or extinct life on another world. However, studies of primitive meteorites have revealed they contain extraterrestrial amino acids and sugar acids (aldonic acids) with large enantiomeric excesses of the same chirality as terrestrial biology resulting from nonbiological processes, complicating the use of chiral asymmetry by itself as a definitive biosignature. Here we review our current knowledge of the distributions and enantiomeric and isotopic compositions of amino acids and polyols found in meteorites compared to terrestrial biology and propose a set of criteria for future life detection missions that can be used to help establish the origin of chiral asymmetry.

The Search for Chiral Asymmetry as a Potential Biosignature in our Solar System.

We present the results of a 7 mm spectral survey of molecular absorption lines originating in the disk of a z=0.89 spiral galaxy located in front of the quasar PKS 1830-211. [...] A total of 28 different species, plus 8 isotopic variants, were detected toward the south-west absorption region, located about 2 kpc from the center of the z=0.89 galaxy, which therefore has the largest number of detected molecular species of any extragalactic object so far. The results of our rotation diagram analysis show that the rotation temperatures are close to the cosmic microwave background temperature of 5.14 K that we expect to measure at z=0.89, whereas the kinetic temperature is one order of magnitude higher, indicating that the gas is subthermally excited. The molecular fractional abundances are found to be in-between those in typical Galactic diffuse and translucent clouds, and clearly deviate from those observed in the dark cloud TMC 1 or in the Galactic center giant molecular cloud Sgr B2. The isotopic ratios of carbon, nitrogen, oxygen, and silicon deviate significantly from the solar values, which can be linked to the young age of the z=0.89 galaxy and a release of nucleosynthesis products dominated by massive stars. [...] We also report the discovery of several new absorption components, with velocities spanning between -300 and +170 km/s. Finally, the line centroids of several species (e.g., CH3OH, NH3) are found to be significantly offset from the average velocity. If caused by a variation in the proton-to-electron mass ratio mu with redshift, these offsets yield an upper limit |Delta_mu/mu|<4e-6, which takes into account the kinematical noise produced by the velocity dispersion measured from a large number of molecular species.

/pdf/molecules-at-z-0-89-a-4-mm-rest-frame-absorption-line-survey-4q6r14te2e.pdf

Molecules at z=0.89: A 4-mm-rest-frame absorption line survey toward PKS 1830-211

We investigate the gas-phase and grain-surface chemistry in the inner 30 AU of a typical protoplanetary disk (PPD) using a new model which calculates the gas temperature by solving the gas heating and cooling balance and which has an improved treatment of the UV radiation field. We discuss inner-disk chemistry in general, obtaining excellent agreement with recent observations which have probed the material in the inner regions of PPDs. We also apply our model to study the isotopic fractionation of carbon. Results show that the fractionation ratio, 12C/13C, of the system varies with radius and height in the disk. Different behavior is seen in the fractionation of different species. We compare our results with 12C/13C ratios in the solar system comets, and find a stark contrast, indicative of reprocessing.

http://iopscience.iop.org/article/10.1088/0004-637X/693/2/1360/pdf

Carbon isotope fractionation in protoplanetary disks

We propose a series of detailed observations that should allow current ideas concerning the important catalytic pathways to interstellar molecules on interstellar dust grains to be tested. The atoms and molecules that accrete on cold grains and take part in surface reactions will be selectively fractionated in 13C. Deeply embedded hot cores are surrounded by cold envelopes which still contain molecular ices that reflect the composition of the material evaporated into the hot gas. Recent Infrared Space Observatory observations of carbon dioxide ices towards embedded protostars have allowed the solid [12C/13C] ratio in CO2 to be measured for the first time. We therefore now have a means to test theories of grain chemistry by comparing the isotopic signature of abundant ice molecules with that of species derived from them and which are only detectable in the gas - isotopic labelling a posteriori.

/pdf/observational-tests-for-grain-chemistry-posterior-isotopic-4ysgr9lrzl.pdf

Observational Tests for Grain Chemistry: Posterior Isotopic Labelling

We have observed emission from both ortho and para spin states of ketene (CH2CO) towards several deeply-embedded protostars. The low CH2CO fractional abundances (∼10−10) and the rotation temperatures (∼20 K) are consistent with emission from the cooler envelope. We compare our results with previous studies and discuss possible production pathways to interstellar ketene. We suggest that, if low observed excitation temperatures of CH2CO, CH3CHO and H2CO are indicative of their absence from the hot core region, then this may be due to the extensive hydrogenation of pre-existing grain mantles prior to evaporation into the inner envelope, leading to lower abundances of these compounds and to mantles rich in alcohols.

Organic astrochemistry: observations of interstellar ketene

/pdf/observational-tests-for-grain-chemistry-posterior-isotopic-114xjz6trv.pdf

Observational tests for grain chemistry: posterior isotopic labelling

Handle everyday research tasks with reliable, citation-backed results

Your personal Research Agent to handle research tasks with citation-backed results

Popular Tasks used by Researchers

How can I help with your research?

Meet SciSpace

Get more enhanced response by uploading the PDFs you want me to reference.

No relevant PDFs in your library

SciSpace is the AI research assistant for academics. Run systematic literature reviews on 280M+ papers, and write papers with cited sources. Trusted by 1M+ students, PhDs & researchers.

SciSpace | AI for Research

Analyze PDFs

Code & Manuscripts

Funding & Grants

Literature & Patents

Medical & Clinical Data

Systematic Review

Visualize & Present

Web & Data

Build a Google Scholar-like website for your research.

Build a website

Create charts and images for your research

Create a Chart

Write a paper for submission to a journal

Draft a manuscript

Patent Search

Design eye-catching scientific posters in minutes.

Scientific Poster Generation

Systematic Literature Review

One task is running at the moment. Your messages will be shown right after.

Drag and drop or click here to browse

Loved by <highlight>1 million+</highlight> researchers

Extract a list of specific topics and their sources from unstructured text

Topics

Compare and analyze relevant papers that matches with your search

Papers

Get insights from PDFs and bookmarked papers from your library

My library

Recent searches

Try searching for:

Catch AI-generated content in scholarly and non-scholarly content

{ai} Detector

Ai Writer

Get PDF Summaries, highlighted text explanations 

Chat with PDF

Effortlessly create in-text citations and bibliographies in APA and 2,500 other formats

Citation generator

Get explanations, summaries, and answers on academic papers

Ease up your research workflow with {scispace}'s cohort of exciting AI tools

Elevate your academic writing skills and convey your ideas the way you want

Paraphraser

Explore our range of reading and writing tools

Your file is being prepared and should be ready in a few minutes. If it's a large file, it might take a bit longer. You can close this window, and we'll email you the file when it's done.

You have reached a maximum limit of <strong>{limit}</strong> columns in the table. Remove at least <strong>1</strong> column to add or create another one.

R. Ruiterkamp

Author Tools

Chat about Author

Papers

Observational Tests for Grain Chemistry: Posterior Isotopic Labelling

Organic astrochemistry: observations of interstellar ketene

Observational tests for grain chemistry: posterior isotopic labelling