The rare earths (REs) are a family of 17 elements that exhibit pronounced chemical similarities as a group, while individually expressing distinctive and varied electronic properties. These atomistic electronic properties are extraordinarily useful and motivate the application of REs in many technologies and devices. From their discovery to the present day, a major challenge faced by chemists has been the separation of RE elements, which has evolved from tedious crystallization to highly engineered solvent extraction schemes. The increasing incorporation and dependence of REs in technology have raised concerns about their sustainability and motivated recent studies for improved separations to achieve a circular RE economy.

Rare earth elements: Mendeleev's bane, modern marvels.

Rare earth elements (REE) are a homogenous group of 17 chemical elements in the periodic table that are key to many modern industries including chemicals, consumer electronics, clean energy, transportation, health care, aviation, and defense. Moreover, in recent years, they have been used in agriculture. One of the consequences of their worldwide use is the possible increase of their levels in various environmental compartments. This review addresses major topics concerning the study of REE in the soil environment, with special attention to the latest research findings. The main sources of REE to soils, the contents of REE in soils worldwide, and relevant information on the effects of REE to plants were explored. Ecological and human health risk issues related to the presence of REE in soils were also discussed. Although several findings reported positive effects of REE on plant growth, many questions about their biological role remain unanswered. Therefore, studies concerning the actual mechanism of action of these elements on cellular and physiological processes should be further refined. Even more urgent is to unveil their chemical behavior in soils and the ecological and human health risks that might be associated with the widespread use of REE in our modern society.

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Rare Earth Elements in the Soil Environment

Because of their remarkable and unmatched optical and magnetic properties, the lanthanides are under the limelight when it comes to high technology. These elements are used in strategic application...

Review: Lanthanide coordination chemistry: from old concepts to coordination polymers

Rare earth elements (REEs) or "technology metals" were coined by the U.S. Department of Energy, a group of seventeen elements found in the Earth's crust. These chemical elements are vital and irreplaceable to the world of technology owing to their unique physical, chemical, and light-emitting properties, all of which are beneficial in modern healthcare, telecommunication, and defense. Rare earth elements are relatively abundant in Earth's crust, with critical qualities to the device performance. The reuse and recycling of rare earth elements through different technologies can minimize impacts on the environment; however, there is insufficient data about their biological, bioaccumulation, and health effects. The increasing usage of rare earth elements has raised concern about environmental toxicity, which may further cause harmful effects on human health. The study aims to review the toxicity analysis of these rare earth elements concerning aquatic biota, considering it to be the sensitive indicator of the environment. Based on the limited reports of REE effects, the review highlights the need for more detailed studies on the hormetic effects of REEs. Aquatic biota is a cheap, robust, and efficient platform to study REEs' toxicity, mobility of REEs, and biomagnification in water bodies. REEs' diverse effects on aquatic life forms have been observed due to the lack of safety limits and extensive use in the various sectors. In accordance with the available data, we have put in efforts to compile all the relevant research results in this paper related to the topic "toxicity effect of REEs on aquatic life".

An Updated Review of Toxicity Effect of the Rare Earth Elements (REEs) on Aquatic Organisms

A POPULAR exposition of the doctrine of Relativity and what it implies: for this the world has been crying since the astronomers announced that the stars had proved it true. Here is an excellent translation of Einstein's own book; we hasten to it to know the whole truth and nothing but the truth. The reviewer on this occasion should be the man in the street, the man who, with thousands, has been asking, “What is Relativity?” “What is the matter with Euclid and with Newton?” “What is this message from the stars?” Whether it is possible for the prophet to make his message clear to the multitude, only history can prove. He must needs speak largely in parables, in incomplete similes; and he is subject, therefore, to inevitable misunderstanding.Relativity: The Special and the General Theory. A Popular Exposition.By Prof. Albert Einstein. Authorised translation by Dr. Robert W. Lawson. Pp. xiii + 138. (London: Methuen and Co., Ltd., 1920.) Price 5s. net.

Relativity : the special and the general theory, a popular exposition / by Albert Einstein ; authorised translation by Robert W. Lawson.

Synopsis Download full-size image This chapter gives an overview of the evolution of the position of the rare earths in the periodic table, from Mendeleev’s time to the present. Three fundamentally different accommodation methodologies have been proposed over the years. Mendeleev considered the rare-earth elements as homologues of the other elements. Other chemists looked upon the rare earths as forming a special intraperiodic group and they clustered the rare-earth elements in one of the groups of the periodic table. Still others adhered to the intergroup accommodation of the rare earths, according to which the rare earth elements do not show any relationship with the other elements, so that they had to be placed within the periodic table as a separate family of elements. The intergroup accommodation became the preferred one in the twentieth century. The advantages and disadvantages of the different representations of the modern periodic table are discussed.

Accommodation of the Rare Earths in the Periodic Table: A Historical Analysis

Shattered Symmetry: Group Theory From the Eightfold Way to the Periodic Table

The debate on the conventionality of simultaneity and the debate on the dimensionality of the world have been central in the philosophy of special relativity. The link between both debates however has rarely been explored. The purpose of this paper is to gauge what implications the former debate has for the latter. I show the situation to be much more subtle than was previously argued, and explain how the ontic versus epistemic distinction in the former debate impacts the latter. Despite claims to the contrary, I conclude that special relativity leaves the debate on the dimensionality of the world underdetermined.

/pdf/conventionality-and-reality-1jic1buqxs.pdf

Conventionality and Reality

To this day, a hundred and fifty years after Mendeleev’s discovery, the overal structure of the periodic system remains unaccounted for in quantum-mechanical terms. Given this dire situation, a handful of scientists in the 1970s embarked on a quest for the symmetries that lie hidden in the periodic table. Their goal was to explain the table’s structure in group-theoretical terms. We argue that this symmetry program required an important paradigm shift in the understanding of the nature of chemical elements. The idea, in essence, consisted of treating the chemical elements, not as particles, but as states of a superparticle. We show that the inspiration for this came from elementary particle physics, and in particular from Heisenberg’s suggestion to treat the proton and neutron as different states of the nucleon.We provide a careful study of Heisenberg’s last paper on the nature of elementary particles, and explain why the Democritean picture of matter no longer applied in modern physics and a Platonic symmetry-based picture was called for instead. We show how Heisenberg’s Platonic philosophy came to dominate the field of elementary particle physics, and how it found its culmination point in Gell-Mann’s classification of the hadrons in the eightfold way. We argue that it was the success of Heisenberg’s approach in elementary particle physics that sparked the group-theoretical approach to the periodic table. We explain how it was applied to the set of chemical elements via a critical examination of the work of the Russian mathematician Abram Ilyich Fet  the Turkish-American physicist Asim Orhan Barut, before giving some final reflections.

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Particular Symmetries: Group Theory of the Periodic System

Human freedom is in tension with nomological determinism and with statistical determinism. The goal of this paper is to answer both challenges. Four contributions are made to the free-will debate. First, we propose a classification of scientific theories based on how much freedom they allow. We take into account that indeterminism comes in different degrees and that both the laws and the auxiliary conditions can place constraints. A scientific worldview pulls towards one end of this classification, while libertarianism pulls towards the other end of the spectrum. Second, inspired by Hoefer, we argue that an interval of auxiliary conditions corresponds to a region in phase space, and to a bundle of possible block universes. We thus make room for a form of non-nomological indeterminism. Third, we combine crucial elements from the works of Hoefer and List; we attempt to give a libertarian reading of this combination. On our proposal, throughout spacetime, there is a certain amount of freedom (equivalent to setting the initial, intermediate, or final conditions) that can be interpreted as the result of agential choices. Fourth, we focus on the principle of alternative possibilities throughout and propose three ways of strengthening it.

Degrees of freedom

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